Pitch pocket and sealant

Abstract

A one-part pourable sealant that is thermosetting, non-shrinking, and capable of quickly curing in a closed cavity to a depth of at least two inches includes a silyl-terminated polymer, a hygroscopic plasticizer present in an amount that is effective to promote rapid and deep curing, and a catalyst for promoting curing of the silyl-terminated polymer. The sealer composition is useful in a method of forming a seal around a roof penetration. The method includes dispensing the sealer composition into a pitch pocket formed around a roof penetration and allowing the sealer composition dispensed into the pitch pocket to cure by exposure to moisture in the air.

1. A one-part, moisture curable, pourable sealer composition, comprising:
 a silyl-terminated polymer, a hygroscopic plasticizer present in an amount that is effective to promote rapid and deep curing, and a catalyst for promoting curing of the silyl-terminated polymer.    
     
     
       2. The composition of  claim 1 , wherein the silyl-terminated polymer is selected from the group consisting of silylated polyurethanes, silylated polyethers, and silylated polyesters. 
     
     
       3. The composition of  claim 2 , wherein the silylated polymer is an alpha, omega-telechelic silyl-terminated polymer. 
     
     
       4. The composition of  claim 1 , wherein the silyl-terminated polymer is an oxyalkylene polymer having at least one reactive silyl group at each end of the polymer molecule. 
     
     
       5. The composition of  claim 4 , wherein the silyl-terminated polymer has a backbone selected from the group consisting of polypropylene oxide, polyethylene oxide, and copolyethylene oxide/polypropylene oxide. 
     
     
       6. A one-part, moisture curable, pourable sealer composition, comprising:
 a silyl-terminated polymer, a hygroscopic plasticizer present in an amount that is effective to promote rapid and deep curing, and a catalyst for promoting curing of the silyl-terminated polymer, wherein the silyl-terminated polymer is a silyl-terminated polyurethane.    
     
     
       7. The composition of  claim 6 , wherein the silyl-terminated polyurethane is the reaction product of an isocyanate-terminated polymer with an aminosilane, and wherein the isocyanate-terminated polymer is the reaction product of a hydroxyl-terminated polyether with a polyisocyanate compound. 
     
     
       8. The composition of  claim 7 , wherein the hydroxyl-terminated polyether is a hydroxyl-terminated polyoxyalkylene. 
     
     
       9. The composition of  claim 1 , wherein the silyl-terminated polymer has a weight average molecular weight of from about 500 to 50,000 Daltons. 
     
     
       10. The  A one- part, moisture - curable, pourable sealer  composition of  claim 1  , comprising:
   a silyl - terminated polymer, a hygroscopic plasticizer present in an amount that is effective to promote rapid and deep curing, and a catalyst for promoting curing of the silyl - terminated polymer,  wherein the hygroscopic plasticizer is a polyether polyol.  
 
     
     
       11. The composition of  claim 10 , wherein the polyether polyol is a hydroxyl-terminated polypropylene oxide. 
     
     
       12. The composition of  claim 10 , wherein the hygroscopic plasticizer is present in the one-part moisture curable pourable sealer composition in an amount of from about 5 to about 50 parts by weight per 100 parts by weight of the silyl-terminated polymer. 
     
     
       13. A method of forming a seal around a roof penetration, comprising:
 dispensing a one-part moisture curable, pourable sealer composition into a pitch pocket formed around the roof penetration, said one-part moisture curable pourable sealer composition containing a silyl-terminated polymer and a hygroscopic plasticizer present in an amount that is effective to promote rapid and deep curing.  
 
     
     
       14. The method of  claim 13 , wherein the silyl-terminated polymer is selected from the group consisting of silylated polyurethanes, silylated polyethers, and silylated polyesters. 
     
     
       15. The method of  claim 14 , wherein the silylated polymer is an alpha, omega-telechelic silyl-terminated polymer. 
     
     
       16. The method of  claim 13 , wherein the silyl-terminated polymer is an oxyalkylene polymer having at least one reactive silyl group at each end of the polymer molecule. 
     
     
       17. The method of  claim 16 , wherein the silyl-terminated polymer has a backbone selected from the group consisting of polypropylene oxide, polyethylene oxide, and copolyethylene oxide/polypropylene oxide. 
     
     
       18. A method of forming a seal around a roof penetration, comprising:
 dispensing a one-part moisture curable, pourable sealer composition into a pitch pocket formed around the roof penetration, said one-part moisture curable pourable sealer composition containing a silyl-terminated polymer and a hygroscopic plasticizer present in an amount that is effective to promote rapid and deep curing, wherein the silyl-terminated polymer is a silyl-terminated polyurethane.  
 
     
     
       19. The method of  claim 13 , wherein the hygroscopic plasticizer is a polyether polyol. 
     
     
       20. The method of  claim 19 , wherein the polyether polyol is a hydroxyl-terminated polypropylene oxide. 
     
     
       21. A method of forming a seal around a roof penetration, comprising:
   dispensing a one - part moisture curable, pourable sealer composition into a pitch pocket formed around the roof penetration, said one - part moisture curable pourable sealer composition containing a silyl - terminated polymer.     
     
     
       22. The method of  claim 21 , wherein the silyl- terminated polymer is selected from the group consisting of silylated polyurethanes, silylated polyethers, and silylated polyesters.   
     
     
       23. The method of  claim 22 , wherein the silylated polymer is an alpha, omega- telechelic silyl - terminated polymer.   
     
     
       24. The method of  claim 21 , wherein the silyl- terminated polymer is an oxyalkylene polymer having at least one reactive silyl group at each end of the polymer molecule.   
     
     
       25. The method of  claim 24 , wherein the silyl- terminated polymer has a backbone selected from the group consisting of polypropylene oxide, polyethylene oxide, and copolyethylene oxide/polypropylene oxide.