Negative thermal expansion glass ceramic

Abstract

A negative thermal expansion glass ceramic having a negative coefficient of thermal expansion, which is a sufficiently large absolute value in a temperature range of −40° C. to +160° C. and a method for producing the same are provided. The negative thermal expansion glass ceramic has a coefficient of thermal expansion of −25 to −100×10 −7 /° C. in the temperature range of −40° C. to +160° C., and comprises main crystalline phases which are one or more types selected from a group consisting of β-eucryptite solid solution (β-Li 2 O•Al 2 O 3 •2SiO 2 solid solution), β-eucryptite (β-Li 2 O•Al 2 O 3 •2SiO 2 ), β-quartz solid solution (β-SiO 2 ) solid solution), and β-quartz (β-SiO 2 ), wherein a total amount of crystals of the main crystalline phases can be 70 to 100% in mass percent.

1. A negative thermal expansion glass ceramic, comprising:
 5.5-15 mass percent of Li 2 O; and  
 0.5-4 mass percent of BaO;  
 wherein the negative thermal expansion glass ceramic has a coefficient of thermal expansion of −25 to −100×10 −7 /° C. in a temperature range of −40° C. to +160° C.  
 
     
     
       2. The negative thermal expansion glass ceramic of  claim 1 , comprising 40-65 mass percent of SiO 2 . 
     
     
       3. The negative thermal expansion glass ceramic of  claim 1 , comprising 25-45 mass percent of Al 2 O 3 . 
     
     
       4. The negative thermal expansion glass ceramic of  claim 1 , comprising a main crystalline phase which is at least one crystalline phase selected from the group consisting of β-eucryptite solid solution, β-eucryptite, β-quartz solid solution, and β-quartz. 
     
     
       5. The negative thermal expansion glass ceramic of  claim 4 , wherein a total amount of crystals of the main crystalline phase is 70 to 100% in mass percent. 
     
     
       6. The negative thermal expansion glass ceramic of  claim 1 , wherein the glass ceramic is a material that is essentially free of anisotropy. 
     
     
       7. The negative thermal expansion glass ceramic of  claim 1 , wherein the glass ceramic is applied to a temperature compensating member, the glass ceramic being combined with a material having a positive coefficient of thermal expansion. 
     
     
       8. The negative thermal expansion glass ceramic of  claim 1 , wherein the glass ceramic is applied to a device securing an optical fiber. 
     
     
       9. The negative thermal expansion glass ceramic, comprising:
 40-65 mass percent Of SiO 2 ;  
 25-45 mass percent of Al 2 O 3 ;  
 5.5-15 mass percent of Li 2 O; and  
 0.5-4 mass percent of BaO;  
 wherein the negative thermal expansion glass ceramic has a coefficient of thermal expansion of −25 to −100×10 −7 /° C. in a temperature range of −40° C. to +160° C.  
 
     
     
       10. The negative thermal expansion glass ceramic, comprising:
 34-45 mass percent of Al 2 O 3 ; and  
 0.5-4 mass percent of BaO;  
 wherein the negative thermal expansion glass ceramic has a coefficient of thermal expansion of −25 to −100×10 −7 /° C. in a temperature range of −40° C. to +160° C.  
 
     
     
       11. A temperature compensating member comprising:
   a negative thermal expansion glass ceramic which comprises:  5 . 5 - 15  mass percent of Li   2   O; and  0 . 5 - 4  mass percent of BaO; wherein the negative thermal expansion glass ceramic has a coefficient of thermal expansion of − 25  to − 100 × 10     −7   /° C. in a temperature range of − 40 ° C. to + 160 ° C.     
     
     
       12. A temperature compensating member comprising:
   a negative thermal expansion glass ceramic which comprises:  34 - 35  mass percent of Al   2   O   3   ; and  0 . 5 - 4  mass percent of BaO; wherein the negative thermal expansion glass ceramic has a coefficient of thermal expansion of − 25  to − 100 × 10     −7   /° C. in a temperature range of − 40 ° C. to + 160 ° C.     
     
     
       13. A negative thermal expansion glass ceramic comprising:
     34 - 45  mass percent of Al   2   O   3   ;          0 . 5 - 4  mass percent of BaO; and          40 - 65  mass percent of SiO   2   ;        wherein the negative thermal expansion glass ceramic has a coefficient of thermal expansion of − 25  to − 100 × 10     −7   /° C. in a temperature of − 40 ° C. to + 160 ° C.     
     
     
       14. The negative thermal expansion glass ceramic of  claim 13 , comprising a main crystalline phase which is at least one crystalline phase selected from the group consisting of β-eucryptite solid solution, β-eucryptite, β-quartz solid solution, and β-quartz. 
     
     
       15. The negative thermal expansion glass ceramic of  claim 14 , wherein a total amount of crystals of the main crystalline phase is  70  to  100 %  in mass percent.   
     
     
       16. The negative thermal expansion glass ceramic of  claim 13 , wherein the glass ceramic is a material that is essentially free of anisotropy. 
     
     
       17. The negative thermal expansion glass ceramic of  claim 13 , wherein the glass ceramic is applied to a temperature compensating member, the glass ceramic being combined with a material having a positive coefficient of thermal expansion. 
     
     
       18. The negative thermal expansion glass ceramic of  claim 13 , wherein the glass ceramic is applied to a device securing an optical fiber.