Automotive additives and sealants containing waste powder prime

Abstract

The present invention is directed to compositions for use as additives in the automotive industry, which compositions contain waste powder prime and a plasticizer selected from the group consisting of 2-ethylhexyl diphenyl phosphate, diisoheptyl phthalate, a linear phthalate based upon C 7 -C 9 alcohols, a mixture of esters containing a minimum of 55 percent of diesters and a maximum of 20 percent dibenzoate, a mixture of esters containing a minimum of 60 percent of diesters and a maximum of 30 percent dibenzoate and dipropylene glycol dibenzoate and automotive sealants which contain waste powder prime, a plasticizer selected from the group consisting of 2-ethylhexyl diphenyl phosphate, diisoheptyl phthalate, a linear phthalate based upon C 7 -C 9 alcohols, a mixture of esters containing a minimum of 55 percent of diesters and a maximum of 20 percent dibenzoate, a mixture of esters containing a minimum of 60 percent of diesters and a maximum of 30 percent dibenzoate and dipropylene glycol dibenzoate and automotive sealants; and a polymeric resin.

What is claimed is:  
     
       1. A composition, comprising: 
       waste powder prime; and  
       a plasticizer selected from the group consisting of 2-ethylhexyl diphenyl phosphate, diisoheptyl phthalate, a linear phthalate based upon C 7 -C 9  alcohols, a mixture of esters containing from about 50 to about 85 percent of 2-methyl-3-(benzoyloxy)-2,2,4-trimethylpentyl ester  propanoic acid,-   2   - methyl -   3   -( benzoyloxy )-   2 , 2 , 4   - trimethylpentyl ester  (CAS #22527-63-5), from about 10 to 30 1 percent of 2,2,3-trimethyl-1,3-pentanediol dibenzoate   2 , 2 , 4 - trimethyl -   1 , 3   - pentanediol dibenzoate  (CAS #68052-23-3) and from about 5 to about 10 percent of 2-methyl-2,2-dimethyl-1-(1-methylethyl)-1,3-propanediyl ester and  propanoic acid,-   2   - methyl -   2 , 2   - dimethyl -   1   -(   1   - methylethyl )-   1 , 3   - propanediyl ester  ( CAS # 6846   -   50   -   0   ) dipropylene glycol dibenzoate and mixtures thereof, wherein the waste powder prime and the plasticizer are present in amounts effective to provide a viscosity-stable dispersion of the waste powder prime in the plasticizer.  
     
     
       2. The composition of  claim 1  wherein the waste powder prime and the plasticizer are present at a weight ration  ratio of about 1:10 to about 10:1. 
     
     
       3. The composition of  claim 1  wherein the plasticizer is selected from the group consisting of 2-ethylhexyl diphenyl phosphate, diisoheptyl phthalate, a linear phthalate based upon C 7 -C 9  alcohols, and dipropylene glycol dibenzoate. 
     
     
       4. The composition of  claim 1  wherein the plasticizer is selected from the group consisting of 2-ethylhexyl diphenyl phosphate and diisoheptyl phthalate. 
     
     
       5. The composition of  claim 1  further comprising a polymeric resin of the type used to prepare conventional automotive sealants, in amounts effective to provide film-forming properties to the automotive sealant. 
     
     
       6. The composition of  claim 5  comprising from about 0.1 to about 50 percent of the waste powder prime, from about 0.1 to about 50 percent of the plasticizer and from about 10 to about 50 percent of the polymeric resin. 
     
     
       7. The composition of  claim 6  wherein the polymeric resin is selected from the group consisting of poly(vinyl chloride), poly(vinyl acetate), copolymers of vinyl chloride and copolymers of vinyl acetate. 
     
     
       8. The composition of  claim 1  further comprising a component selected from the group consisting of an adhesion promoter, a filler, a solvent and a rheology modifier, in amounts effective to perform the specific function for which the component is used. 
     
     
       9. The composition of  claim 1  wherein said composition is free of adhesion promoters. 
     
     
       10. A composition comprising waste powder prime and a plasticizer, wherein the plasticizer is selected and is present in an amount relative to the waste powder prime effective to provide a viscosity- stable dispersion of the waste powder prime in the plasticizer, wherein the plasticizer is selected from the group consisting of mixed isobutyrates, benzoate esters of trimethylpentanediols, and mixtures thereof.   
     
     
       11. The composition of  claim 10  wherein the waste powder prime and the plasticizer are present at a weight ratio of about  1 : 10  to about  10 : 1 . 
     
     
       12. The composition of  claim 11  further comprising a polymeric resin used to prepare an automotive sealant in an amount effective to provide film- forming properties to the automotive sealant.   
     
     
       13. The composition of  claim 12  comprising from about  0 . 1  to about  50  percent of the waste powder prime, from about  0 . 1  to about  50  percent of the plasticizer and from about  10  to about  50  percent of the polymeric resin. 
     
     
       14. The composition of  claim 12  wherein the polymeric resin is selected from the group consisting of poly ( vinyl chloride ) , poly  ( vinyl acetate ) , copolymers of vinyl chloride and copolymers of vinyl acetate.   
     
     
       15. The composition of  claim 12  further comprising an effective amount of a component selected from a group consisting of an adhesion promoter, a filler, a solvent and a rheology modifier. 
     
     
       16. The composition of  claim 10  wherein said composition is free of adhesion promoters. 
     
     
       17. The composition of  claim 10  wherein said plasticizer comprises a mixture of esters containing propanoic acid-   2   - methyl -   3   -( benzoyloxy )-   2 , 2 , 4   - trimethylpentyl ester,  2 , 2 , 4   - trimethyl -   1 , 3   - pentanediol dibenzoate and propanoic acid -   2   - methyl -   2 , 2   - dimethyl -   1   -(   1   - methylethyl )-   1 , 3   - propanediyl ester.   
     
     
       18. A composition comprising waste powder prime and a plasticizer, wherein the plasticizer is selected and is present in an amount relative to the waste powder prime effective to provide a viscosity- stable dispersion of the waste powder prime in the plasticizer, wherein said plasticizer is selected from the group consisting of  2   - ethylhexyl diphenyl phosphate, diisoheptyl phthalate, a linear phthalate based upon C   7   -C   9    alcohols, and dipropylene glycol dibenzoate.