Method for preparing carboxy functional silicones

Abstract

A novel method is provided for preparing carboxy functional silicones, comprising the steps of: (1) addition reacting a mixture of ingredients containing (A) an olefin-terminated organoacyloxysilane; (B) an organohydrogenpolysiloxane, and (C) a precious metal or a precious metal-containing catalyst, and (2) hydrolyzing the addition reaction product prepared in step (1).

What is claimed is: 
     
       1. A method of preparing carboxy functional silicones, comprising the steps of: (1) addition reacting a mixture of ingredients comprising: (A) an organoacyloxysilane having the general formula:   (I) R.sub.3 SiOOC(R.sup.1).sub.x CH═CH.sub.2     wherein R .[.and R 1  are.]. .Iadd.is a .Iaddend.monovalent hydrocarbon .[.radicals.]. .Iadd.radical .Iaddend.free of aliphatic unsaturation, .Iadd.R 1  is a divalent hydrocarbon free of aliphatic unsaturation .Iaddend.and "x" is a number from about 0 to about 30.     (B) an organohydrogenpolysiloxane having a hydride concentration of 0.01 to about 100 mole percent and a viscosity of about 2 to about 1 million centipoise at 25° C.; and   (C) an amount of a precious metal or a precious metal-containing catalyst effective for promoting an addition reaction between components (1) and (2);   wherein components are present in a molar ratio of about 1:1; and     (2) hydrolyzing the addition reaction product formed in step (1).   
     
     
       2. A method according to claim 1 wherein R .[.and R 1  are each.]. .Iadd.is .Iaddend.methyl or phenyl, .Iadd.R 1  is methylene or phenylene .Iaddend.and x is a number from about 0 to about 15. 
     
     
       3. A method according to claim 2 wherein R .[.and R 1  are.]. is methyl, R 1  is methylene and x is a number from about 1 to about 8. 
     
     
       4. A method according to claim 1 wherein the catalyst is a platinum or platinum-containing catalyst. 
     
     
       5. A method according to claim 1 wherein component (C) is present in an amount within the range of from about 1 to about 100 parts per million of the total composition of components A and B. 
     
     
       6. A method according to claim 5 wherein component (C) is present in an amount within the range of from about 1 to about 80. 
     
     
       7. A method according to claim 6 wherein component (C) is present in an amount within the range of from about 1 to about 20. 
     
     
       8. A method according to claim 1 wherein in step (B), the amount of water is in the range of from about 1 to about 10 moles of water per mole of component (A).