Polyphenylene ether-polyamide compositions from aryloxytriazine-capped polyphenylene ethers

Abstract

Aryloxytriazine-capped polyphenylene ethers are prepared by reaction of a polyphenylene ether with an aryloxychlorotriazine such as diphenyl chlorocyanurate. The products undergo reaction with amine-terminated polymers such as polyamides, to form compositions which have excellent properties and which find utility as molding compositions and as compatibilizers for blends of similar polymers.

What is claimed is: 
     
       1. A composition comprising at least one polyamide and at least one aryloxytriazine-capped polyphenylene ether having end groups of the formula ##STR8## wherein: each Q 1  is independently halogen, primary or secondary lower alkyl, phenyl, haloalkyl, aminoalkyl, hydrocarbonoxy, or halohydrocarbonoxy wherein at least two carbon atoms separate the halogen and oxygen atoms; each Q 2  is independently hydrogen, halogen, primary or secondary lower alkyl, phenyl, haloalkyl, hydrocarbonoxy or halohydrocarbonoxy as defined for .[.Qhu 1.]. .Iadd.Q 1  .Iaddend.;   A is an unsubstituted or substituted aromatic radical; and   X is an alkyl or cycloalkyl radical or an unsubstituted or substituted aromatic radical.   
     
     
       2. A composition according to claim 1 wherein the polyphenylene ether comprises a plurality of structural units having the formula ##STR9## 
     
     
       3. A composition according to claim 2 wherein the polyphenylene ether is a poly(2,6-dimethyl-1,4-phenylene ether). 
     
     
       4. A composition according to claim 3 wherein X is an aromatic radical. 
     
     
       5. A composition according to claim 3 wherein the polyamide is a polyamide-6 or a polyamide-66. 
     
     
       6. A composition according to claim 5 which also contains an elastomeric impact modifier. 
     
     
       7. A composition according to claim 6 wherein the impact modifier is a triblock copolymer wherein the end blocks are derived from styrene and the midblock is derived from at least one of isoprene and butadiene. 
     
     
       8. A composition according to claim 7 wherein the aliphatic unsaturation in the midblock has been removed by selective hydrogenation. 
     
     
       9. A composition comprising polyphenylene etherpolyamide copolymer molecules containing at least one polyphenylene ether-polyamide linkage of the formula ##STR10## wherein: each Q 1  is indepedently halogen, primary or secondary lower alkyl, phenyl, haloalkyl, aminoalkyl, hydrocarbonoxy, or halohydrocarbonoxy wherein at least two carbon atoms separate the halogen and oxygen atoms; each Q 2  is independently hydrogen, halogen, primary or secondary lower alkyl, phenyl, haloalkyl, hydrocarbonoxy or halohydrocarbonoxy as defined for Q 1  ; and   Z is an .[.alkyl or cycloalkyl or.]. .Iadd.alkoxy, cycloalkoxy, .Iaddend.unsubstituted .[.or.]. .Iadd.aryloxy, .Iaddend.substituted .[.aromatic radical.]. .Iadd.aryloxy .Iaddend.or --NH--.   
     
     
       10. A composition according to claim 9 wherein the polyphenylene ether comprises a plurality of structural units having the formula ##STR11## 
     
     
       11. A composition according to claim 10 wherein the polyphenylene ether is a poly(2,6-dimethyl-1,4-phenylene ether). 
     
     
       12. A composition according to claim 11 wherein Z is an .[.aromatic.]. .Iadd.aryloxy .Iaddend.radical. 
     
     
       13. A composition according to claim 11 wherein Z is --NH--. 
     
     
       14. A composition according to claim 11 wherein the polyamide is a polyamide-6 or a polyamide-66. 
     
     
       15. A composition according to claim 14 which also contains an elastomeric impact modifier. 
     
     
       16. A composition according to claim 15 wherein the impact modifier is a triblock copolymer wherein the end blocks are derived from styrene and the midblock is derived from at least one of isoprene and butadiene. 
     
     
       17. A composition according to claim 16 wherein the aliphatic unsaturation in the midblock has been removed by selective hydrogenation. .Iadd.18. A composition comprising at least one polyamide, at least one aryloxytriazine-capped polyphenylene ether and reaction products thereof prepared upon blending at a temperature in the range of about 175°-350° C., said capped polyphenylene ether being prepared by contacting under reactive conditions, in the presence of a basic reagent, at least one polyphenylene ether with an aryloxychlorotriazine of the formula ##STR12##.Iaddend. wherein A is an unsubstituted or substituted aromatic radical and X is alkyl, an unsubstituted aromatic radical or substituted aromatic 
     
     
        radical.  .Iadd.19.  A composition according to claim 18 wherein the polyphenylene ether comprises a plurality of structural units having the formula ##STR13## 
     
     
       .Iaddend.  .Iadd.20.  A composition according to claim 19 wherein the polyphenylene ether is a poly(2,6-dimethyl-1,4-phenylene ether). .Iaddend. .Iadd.21. A composition according to claim 20 wherein each of A and X is an aromatic radical. .Iaddend. .Iadd.22. A composition according to claim 20 wherein the polyamide is a polyamide-6 or a polyamide-66. .Iaddend. .Iadd.23. A composition according to claim 22 which also contains an elastomeric impact modifier. .Iaddend. .Iadd.24. A composition according to claim 23 wherein the impact modifier is a triblock copolymer wherein the end blocks are derived from styrene and the midblock is derived from 
     
     
        at least one of isoprene and butadiene. .Iaddend. .Iadd.25.  A composition according to claim 24 wherein the aliphatic unsaturation in the midblock has been removed by selective hydrogenation. .Iaddend. .Iadd.26. A composition according to claim 25 wherein A and X are each phenyl. .Iaddend.