Aqueous adhesive compositions

Abstract

Novel aqueous adhesive and coating compositions composed of (1) an aqueous emulsion (latex) or dispersion of a polymer or interpolymer of one or more vinyl monomers such as an emulsion of a copolymer of vinyl acetate and butyl acrylate and (2) an aqueous emulsion or dispersion of a polyisocyanate which has at least partially reacted with an alcohol having the formula ROH wherein R is a hydrocarbon radical having .[.at least one carbon atom.]. .Iadd.from six to 30 carbon atoms .Iaddend.and wherein the dispersion or emulsion (2) is stabilized with a combined surfactant and alcohol having the formula R' wherein R' is a hydrocarbon radical having at least one carbon atom are described.

We claim: 
     
       1. A composition of matter comprising a mixture of an aqueous latex emulsion or dispersion of (a) a member selected from the group consisting of a homopolymer of a vinyl monomer and an interpolymer of two or more vinyl monomers, and   (b) a polyisocyanate which has undergone at least partial reaction of some of its isocyanate groups with a .[.alcohol.]..Iadd.C 6  -C 30  monohydroxy alkanol.Iaddend..   
     
     
       2. The composition of claim 1 wherein (b) is stabilized with an emulsion stabilizer composed of a surfactant and an alcohol having the structure R'OH wherein R' is a hydrocarbon radical having at least 1 carbon atom. 
     
     
       3. The composition of claim 1 wherein the monohydroxy alcohol in (b) is .[.one having the formula ROH wherein R is a hydrocarbon radical containing at least one carbon atom.]. .Iadd.selected from the group consisting of n-hexyl alcohol, n-heptyl alcohol, n-octyl alcohol, n-nonyl alcohol, n-decyl alcohol, lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, arachidyl alcohol, behenyl alcohol, isohexyl alcohol, 2-ethyl hexanol, 2-ethyl isohexanol, isooctyl alcohol, isononyl alcohol, isodecyl alcohol, isotridecyl alcohol, isocetyl alcohol, isostearyl alcohol, oleyl alcohol, and linoleyl alcohol. .Iaddend. 
     
     
       4. The composition of claim 1 wherein (a) is an aqueous latex of a homopolymer of an interpolymer of a monomer or monomers selected from the group consisting of vinyl acetate, vinyl chloride, vinylidene chloride, styrene, vinyl toluene, acrylonitrile, methacrylonitrile, acrylic esters, methacrylic esters, ethylene, isobutylene, butadiene and isoprene. 
     
     
       5. The composition of claim 4 wherein the polyisocyanate of .[.(2).]. .Iadd.(b) .Iaddend.is a member selected from the group consisting of ethylene diisocyanate, trimethylene, diisocyanate, dodecamethylene diisocyanate, hexamethylene diisocyanate, hexamethylene diisocyanate trimer, tetraethylene diisocyanate.Iadd., .Iaddend.pentamethylene diisocyanate, propylene-1,2-diisocyanate, 2,3-dimethyl tetramethylene diisocyanate, butylene-1,2-diisocyanate, butylene-1,3-diisocyanate, 1,4-diisocyanato cyclohexane, cyclopentene 1,3-diisocyanate, p-phenylene diisocyanate, 1-methyl phenylene-2,4-diisocyanate, naphthalene-1,4-diisocyanate, O,O,-toluene diisocyanate, diphenyl-4,4'-diisocyanate, benzene-1,2,4-triisocyanate, xylylene-1,4-diisocyanate, xylylene-1,3-diisocyanate, 4,4'-diphenylene methane diisocyanate, 4,4'-diphenylene propane diisocyanate, 1,2,3,4-tetraisocyanato butane, butane-1,2,3-triisocyanate, polymethylene polyphenyl isocyanate, and polymeric polyisocyanates. 
     
     
       6. A process comprising applying to at least one surface of a material a mixture of an aqueous latex, emulsion or dispersion of (a) a member selected from the group consisting of a homopolymer of a vinyl monomer and an interpolymer of two or more vinyl monomers, and   (b) a polyisocyanate which as undergone at least partial reaction of some of its isocyanate groups with a .Iadd.C 6  -C 30  monohydroxy .[.alcohol.]. .Iadd.alkanol. .Iaddend.   
     
     
       7. A process which comprises (1) treating at least one surface of a material with a mixture of an aqueous latex, emulsion or dispersion of (a) a member selected from the group consisting of a homopolymer of a vinyl monomer and an interpolymer of two or more vinyl monomers, and (b) a polyisocyanate which has undergone at least partial reaction of some of its isocyanate groups with a .Iadd.C 6  -C 30  .Iaddend. monohydroxy .[.alcohol.]. .Iadd.alkanol. .Iaddend.