Method for applying a hot melt ink to a substrate

Abstract

The present invention provides a process for applying a thermoplastic image forming composition as a series of discrete droplets from a non-contact ink jet printing apparatus to form separate drops on a substrate moving relative to the apparatus, characterized in that the molten composition is thermally stable at the temperature of application and is applied at a temperature in excess of 100° C. The invention can be used to apply the molten composition to a variety of substrates using on-demand or continuous non-contact ink jet application techniques. However, the invention is of especial use in the application of thermoplastic inks to non-porous substrates using an on-demand ink jet printer.

I claim: 
     
       1. A process for applying a thermoplastic composition to a substrate, comprising the steps of: moving the substrate past an application station at which is located a non-contact jet printing apparatus;   operating the non-contact ink jet printing apparatus to apply the composition .Iadd.in the molten state .Iaddend.to the moving substrate as a series of discrete droplets, the composition being applied at a temperature in the range from 100° to 160° C., the .Iadd.molten .Iaddend.composition being characterized as .Iadd.having a softening point in excess of 60° C., as .Iaddend.being thermally stable at the temperature of application and having a viscosity of from 2 to 20 Centipoise at the temperature of application.   
     
     
       2. A process as claimed in claim 1 characterized in that the composition has a surface tension of less than 50 dynes per cm at 25° C. 
     
     
       3. A process as claimed in claim 1, further comprising the steps of: providing a reservoir as a part of the non-contact ink jet printing apparatus at the application station;   holding the composition in the reservoir at the application temperature so that the composition is maintained in a molten state;   feeding the composition from the reservoir under a pressure of from 0.5 to 20 psi gauge to a series of nozzles for discharging the composition onto the substrate as a series of droplets; and   controlling the discharge of the composition from the nozzles by providing valve means between the reservoir and nozzles.   
     
     
       4. A process as claimed in claim 3 characterised in that the valve has an operating cycle time of from 1 to 5 milliseconds, the nozzle has an orifice bore diameter of from 0.01 to 0.45 mms and an internal bore length to diameter ratio of from 3:1 to 1:2. 
     
     
       5. A process according to claim 1 characterised in that the thermoplastic composition comprises one or more oil miscible or soluble image forming components in a fusible carrier medium. 
     
     
       6. A process as claimed in claim 5 characterised in that the fusible carrier medium is thermally stable at temperatures of up to 160°0 C., has a viscosity .[.of less than 120 Cps.]. .Iadd.of from 2 to 20 Cps .Iaddend.at the temperature of application and has a surface tension of less than 40 dynes per cm at 25° C. 
     
     
       7. A process as claimed in claim 6 characterised in that the fusible carrier medium comprises at leat one component selected from a synthetic microcrystalline wax, an hydrocarbon resin and mixtures thereof. 
     
     
       8. A process as claimed in claim 7 characterised in that the microcrystalline wax is selected from polyolefin or paraffin waxes with molecular weights of from 300 to 1500 and softening points in the range 80° to 110° C. 
     
     
       9. A process as claimed in claim 7 characterised in that the hydrocarbon resin is selected from crystalline C 5  to C 9  chain length aliphatic resins and polyolefin resins with softening points greater than 90° C. and melting points greater than 110° C. 
     
     
       10. A process as claimed in claim .[.7.]. .Iadd.9 .Iaddend.characterized in that the polyolefin resin has a mean molecular weight of less than 1500 and an acid number of less than 1 (expressed as mg KOH/g). 
     
     
       11. A process as claimed in claim 6 characterized in that the molten composition has a viscosity of from 3 to 20 Cps at the .[.operating.]. .Iadd.application .Iaddend.temperature; and a surface tension of less than 40 dynes per cm at 25° C. 
     
     
       12. A process as claimed in claim 6 characterized in that the .Iadd.composition comprises .Iaddend.microcrystalline wax .[.is.]. present in from 40 to 99.5%.[.the.]. .Iadd.by weight.Iaddend.; hydrocarbon resin in from 25 to 55% .Iadd.weight .Iaddend.and .[.the.]. image forming material in from 0.1 to 2% .Iadd.by weight.Iaddend.; all percentages being .[.of the active material and.]. by weight .Iadd.based .Iaddend.on the weight of the total molten composition. 
     
     
       13. A process as claimed in claim 1 characterised in that the composition comprises from 40 to 99 parts by weight of a microcrystalline polyethylene wax; from 0 to 60 parts by weight of an hydrocarbon resin selected from C 5  -C 9  aliphatic resins, a polyethylene resin and a styrene resin said latter two resins having a molecular weight of from 500 to 1200; and from 0.1 to 1.5 parts by weight of an oil soluble dyestuff. 
     
     
       14. A process as claimed in claim 1 characterised in that the ink jet printing apparatus is operated at a fluid temperature of from 125° to 150° C. .[.15. A method according to claim 1 for applying a molten adhesive composition to a substrate characterised in that the adhesive composition is dispensed at a temperature in excess of 100° C. through a nozzle to form a series of discrete droplets which are applied to the substrate, the droplets being formed at a rate of more than 100 droplets per second..].