Terpolymer compositions for aqueous drilling fluids

Abstract

A method of improving high temperature fluid loss and rheology stabilization of high calcium brine clay-containing oil well drilling fluids which comprises adding thereto a stabilizing amount of a water-soluble terpolymer composition comprising: ______________________________________ Ingredients % by weight ______________________________________ NaAMPS 72-3.8 N,N-dimethylacrylamide 13.5-0.7 Acrylonitrile 9.5-0.5 ______________________________________ said composition containing lignin, modified lignin, brown coal or modified brown coal in an amount ranging between 5-95% with the lignin, modified lignin, brown cell or modified brown coal having been present during the polymerization of the water-soluble polymer.

Having thus described our invention it is claimed as follows: 
     
       1. A method of improving high temperature fluid loss and rheology stabilization of high calcium brine clay-containing aqueous oil well drilling fluids which comprises adding thereto a stabilizing amount of a water-soluble terpolymer composition comprising: a polymer prepared by polymerizing the following monomer ingredients:   ______________________________________                                    
Ingredients          % by Weight                                          
______________________________________                                    
[NaAMPS] 2-acrylamido-2-methyl-                                           
                      72-3.8                                              
propane sulfonic acid, sodium salt                                        
N,N-dimethylacrylamide                                                    
                     13.5-0.7                                             
Acrylonitrile        9.5-0.5                                              
______________________________________                                    
     said composition containing lignin, modified lignin, brown coal or modified brown coal in an amount ranging between 5-95% with the .Iadd.lignin, modified lignin, .Iaddend.brown coal or modified brown coal having been present during the polymerization of the water-soluble polymer, where the lignin, modified lignin, brown coal or modified brown coal is from the group consisting of lignites, sulphonated lignites, lignins, leonardites, lignosulfonates, alkali metal humic acid salts, humic acids, and sulphonated humic acids. .[.2. The method of claim 1 where the lignin, modified lignin, brown coal or modified brown coal is present in an amount   
     
     
        ranging between 5-95% by weight..]. 3. The method of claim 1 where the lignin, modified lignin, brown coal or modified brown coal is present in an amount ranging between 20-35% by weight.