Lubricants for reciprocating air compressors

Abstract

Synthetic lubricants comprising 15 to 45 weight percent of an ester of a monohydric alcohol of 4 to 18 carbon atoms with one or more aromatic or alkane dicarboxylic acids having 4 to 18 carbon atoms blended with 85 to 55 weight percent of one or more polyether polyols having a number average molecular weight from about 400 to 5000. The blends are compounded with antioxidants, corrosion inhibitors, and metal deactivators to produce a superior lubricant for reciprocating air compressors which gives a long life to the compressors.

We claim: 
     
       1. A lubricant composition comprising, (A) about 15 to 45 weight percent of an ester of a monohydric alcohol having 4 to 18 carbon atoms with one or more aromatic .[.or alkane.]. dicarboxylic acids having 4 to 18 carbon atoms, and   (B) about 85 to 55 weight percent of one or more polyether polyols which have a flash point greater than 375° F. (191° C.) and which have the formula   Z--[(--R.sup.1 O).sub.n R.sup.2 ].sub.m        where   Z is the residue of a compound having 1-8 hydroxyl groups,   R 1  is an alkylene radical having 2 to 4 carbon atoms,   n is a number having an average value which will give a number average molecular weight range from about 400 to about 5000 for the final compound,   m is an integer having a value of from 1 to about 8,   R 2  is hydrogen or an alkyl group of 1 to 6 carbon atoms.   
     
     
       2. The lubricant composition of claim 1 wherein the weight percent of said ester ranges from 15 to 25 and the weight percent of said polyol ranges from 75 to 85. .[.3. A lubricant composition comprising, (A) about 15 to 45 weight percent of an ester of a monohydric alcohol having 4 to 18 carbon atoms with one or more alkandioic acids having 4 to 18 carbon atoms, and   (B) about 85 to 55 weight percent of one or more polyoxyalkylene glycols having a flash point greater than 375° F. (191° C.) and having a number average molecular weight range from about 400 to 5000. .[.4. The lubricant composition of claim 3 wherein said polyoxyalkylene glycols are homopolymers..]. .[.5. The lubricant composition of claim 3 wherein said polyoxyalkylene glycols are random copolymers..]. .[.6. The lubricant composition of claim 3 wherein said polyoxyalkylene glycols are   
     
     
        block copolymers..]. 7. A lubricant composition comprising, (A) about 15 to 45 weight percent of an ester of a monohydric alcohol with one or more aromatic dicarboxylic acids, and   (B) about 85 to 55 weight percent of one or more polyoxyalkylene glycols having a flash point greater than 375° F. and having a number   
     
     
        average molecular weight range from about 700 to 2500. 8. The lubricant composition of claim 7 wherein the weight percent of the ester ranges from 15 to 25 and the weight percent of the polyglycol ranges from 85 to 75. 
     
     
           The lubricant composition of claim 8 wherein the glycol is polypropylene glycol having a number average molecular weight of 1200. 
     
     
            The lubricant composition of claim 9 which comprises 20 weight percent 
     
     
        of said ester and 80 weight percent of said polypropylene glycol. 11. The composition of claim 1 which contains in addition (A) an effective amount of an antioxidant,   (B) an effective amount of an ashless metal corrosion inhibitor, and   
     
     
       (C) an effective amount of a cuprous deactivator. 12. The composition of claim 1 which contains in addition (A) about 0.1 to 5.0 weight percent of an aromatic amine antioxidant,   (B) about 0.1 to 2.0 weight percent of a ashless metal corrosion inhibitor, and   
     
     
       (C) about 0.001 to 0.5 weight percent of a cuprous metal deactivator. 13. The composition of claim 12 wherein said aromatic amine antioxidant is p,p'-dioctyl diphenyl amine, said ashless corrosion inhibitor is an amine salt of phosphoric acid monoester, and said cuprous metal deactivator is 
     
     
        tolutriazole. 14. A method of lubricating a reciprocating air compressor wherein said compressor is continuously run for long time intervals without downtime for valve maintenance which comprises using as the lubricant .[.the composition of claim 11.]. .Iadd.a composition comprising (A) about 15 to 45 weight percent of an ester of an monohydric alcohol having 4 to 18 carbon atoms with one or more aromatic or alkane dicarboxylic acids having 4 to 18 carbon atoms,   (B) about 85 to 55 weight percent of one or more polyether polyols which have a flash point greater than 375° F. (191° C.) and which have the formula   Z--[(--R.sup.1 O).sub.n R.sup.2 ].sub.m        where Z is the residue of a compound having 1-8 hydroxyl groups, R 1  is an alkylene radical having 2 to 4 carbon atoms, n is a number having an average value which will give a number average molecular weight range from about 400 to about 5000 for the final compound, m is an integer having a value of from 1 to about 8, R 2  is hydrogen or an alkyl group of 1 to 6 carbon atoms,   (C) an effective amount of an antioxidant,   (D) an effective amount of an ashless metal corrosion inhibitor, and   
     
     
       (E) an effective amount of a cuprous deactivator.Iaddend.. 15. A method of lubricating a reciprocating air compressor wherein said compressor is continuously run for long time intervals without downtime for valve maintenance which comprises using as the lubricant .[.the composition of claim 12.]. .Iadd.a composition comprising (A) about 15 to 45 weight percent of an ester of an monohydric alcohol having 4 to 18 carbon atoms with one or more aromatic or alkane dicarboxylic acids having 4 to 18 carbon atoms,   (B) about 85 to 55 weight percent of one or more polyether polyols which have a flash point greater than 375° F. (191° C.) and which have the formula   Z--[(--R.sup.1 O).sub.n R.sup.2 ].sub.m        where Z is the residue of a compound having 1-8 hydroxyl groups, R 1  is an alkylene radical having 2 to 4 carbon atoms, n is a number having an average value which will give a number average molecular weight range from about 400 to about 5000 for the final compound, m is an integer having a value of from 1 to about 8, R 2  is hydrogen or an alkyl group of 1 to 6 carbon atoms,   (C) about 0.1 to 5.0 weight percent of an aromatic amine antioxidant,   (D) about 0.1 to 2.0 weight percent of a ashless metal corrosion inhibitor, and   (E) about 0.001 to 0.5 weight percent of a cuprous metal   
     
     
        deactivator.Iaddend.. 16. A method of lubricating a reciprocating air compressor wherein said compressor is continuously run for long time intervals without downtime for valve maintenance which comprises using as the lubricant .[.the composition of claim 13.]. .Iadd.a composition comprising (A) about 15 to 45 weight percent of an ester of an monohydric alcohol having 4 to 18 carbon atoms with one or more aromatic or alkane dicarboxylic acids having 4 to 18 carbon atoms,   (B) about 85 to 55 weight percent of one or more polyether polyols which have a flash point greater than 375° F. (191° C.) and which have the formula   Z--[(--R.sup.1 O).sub.n R.sup.2 ].sub.m        where Z is the residue of a compound having 1-8 hydroxyl groups, R 1  is an alkylene radical having 2 to 4 carbon atoms, n is a number having an average value which will give a number average molecular weight range from about 400 to about 5000 for the final compound, m is an integer having a value of from 1 to about 8, R 2  is hydrogen or an alkyl group of 1 to 6 carbon atoms,   (C) an effective amount of p,p'-dioctyl diphenyl amine,   (D) an effective amount of an amine salt of phosphoric acid monoester, and   (E) an effective amount of tolutriazole.Iaddend..