Fragrance-releasing pull apart sheet

Abstract

Microencapsulated materials are released by rupturing of an adhesive layer on a substrate containing the capsules.

We claim: .[.1. A device for exposing a liquid, said device comprising 
     
        C. and less than 1% relative humidity for seventy-two hours..]. 2. The device of claim .[.1.]. .Iadd.28 .Iaddend.wherein said adhesive 
     
     
        composition comprises said microcapsules and a viscofier. 3. The device of claim 2 wherein said surfaces are on flexible sheets of coated paper and said viscofier comprise from 0.25 to 12% by dry weight of said adhesive 
     
     
        composition layer. 4. The device of claim 3 wherein said microcapsules 
     
     
        have an average diameter between 14 and 26 micrometers. 5. The device of claim 4 wherein said microcapsules comprise between 50 and 85% by volume 
     
     
        of said adhesive composition. 6. The device of claim 3 wherein said liquid 
     
     
        is an odor releasing material. 7. The device of claim 2 wherein said 
     
     
        microcapsules have an average diameter between 12 and 30 micrometers. 8. The device of claim 7 wherein said liquid is an odor releasing 
     
     
        material. 9. The device of claim 2 wherein said microcapsules comprise gelatin and are between 21 and 100% by weight of said adhesive composition, said binder comprises between 0 and 78.75% by weight and said 
     
     
        viscofier comprises between 0.25 and 12% by weight. 10. The device of 
     
     
        claim 9 wherein said liquid is an odor releasing material. 11. The device 
     
     
        of claim 2 wherein said liquid is an odor releasing material. 12. The device of claim 2 wherein said adhesive is a water-remoistenable adhesive. 
     
     
        3. The device of claim .[.1.]. .Iadd.28 .Iaddend.wherein said 
     
     
        microcapsules have an average diameter between 8 and 30 micrometers. 14. The device of claim 13 wherein said microcapsules comprise between 50 
     
     
        and 85% by volume of adhesive composition. 15. The device of claim .[.1.]. .Iadd.28 .Iaddend.wherein said microcapsules comprise between 50 and 85% 
     
     
        by volume of said adhesive composition. 16. The device of claim .[.1.]. .Iadd.28 .Iaddend.wherein said liquid is an odor releasing material and 
     
     
        the shell of said microcapsule comprises a urea-formaldehyde resin. 17. The device of claim .[.1.]. .Iadd.28 .Iaddend.wherein said liquid is 
     
     
        an odor releasing material. 18. The device of claim .[.1.]. .Iadd.28 .Iaddend.wherein a polymeric coating is present over said coated paper surface which is not dissolved by or chemically bonded to said adhesive 
     
     
        composition. 19. The device of claim .[.1.]. .Iadd.28 .Iaddend.wherein said adhesive composition contains said microcapsule and a non-viscosity 
     
     
        enhancing particulate filler. 20. A device for exposing a liquid, said device consisting essentially of (1) two surfaces of paper, at least one of which surfaces is a surface of coated paper, said surfaces being bound by an adhesive composition layer, said coated paper comprising paper which is coated with a resinous binder and white, bone or ivory pigment, and said at least one surface a coated paper having a printed image thereon,   (2) said adhesive composition layer containing microcapsules with said liquid within the shell of the microcapsules, and   (3) said microcapsules having an average diameter between 4 and 80 micrometers, the cohesive strength of the adhesive composition layer being less than the strength of the bond between said adhesive composition and a coated face of said sheets, the tensile rupture strength of said microcapsules being such that the cohesive failure of the adhesive results in breakage of the microcapsules, and the tensile rupture strength between said two surfaces being at least 4.0 g/cm and less than 90 g/cm at 20° C. and 50% relative humidity. .[.21. A device for exposing a liquid, said device comprising     (1) at least two surfaces of coated paper bound by an adhesive composition layer,   (2) said adhesive composition layer containing microcapsules with said liquid within the shell of the microcapsules, and   (3) said microcapsules having an average diameter between 4 and 80 micrometers, the cohesive strength of the adhesive composition layer being less than the strength of the bond between said adhesive composition and a coated face of said sheets, the tensile rupture strength of said microcapsules being such that the cohesive failure of the adhesive results in breakage of the microcapsules, and the tensile rupture strength between said two surfaces being at least 8.0 g/cm and less than 90 g/cm at 20° C. and 50% relative humidity and greater than 4.0 g/m after storage for seventy-two     
     
     
        hours at 120° C. and less than 1% relative humidity..]. .[.22.  The device of claim 21 wherein said tensile rupture strength between said two surfaces is at least 16.0 g/cm and less than 90 g/cm at 20° C. and 50% relative humidity..]. .[.23. The device of claim 22 wherein said liquid is an odor releasing material..]. .[.24. The device of claim 22 wherein said tensile rupture strength is at least 8.0 g after storage for seventy-two hours at 1% relative humidity and 120° C..]. .[.25. The device of claim 21 wherein said liquid is an odor releasing material..]. .[.26. The device of claim 25 wherein said tensile rupture strength is at least 8.0 g after storage for seventy-two hours at 1% relative humidity and 120° C..]. .[.27. The device of claim 21 wherein said tensile rupture strength is at least 8.0 g after storage for seventy-two hours at 
     
     
        1% relative humidity and 120° C..]. .Iadd.28.  A device for exposing a liquid, said device consisting essentially of (1) two surfaces of paper, both of said surfaces being surfaces of coated paper, said surfaces being bound by an adhesive composition layer, said coated paper comprising paper which is coated with a resinous binder and white, bone or ivory pigment, and at least one of said surfaces of coated paper having a printed image thereon,   (2) said adhesive composition layer containing microcapsules with said liquid within the shell of the microcapsules, and   (3) said microcapsules having an average diameter between 4 and 80 micrometers, the cohesive strength of the adhesive composition layer being less than the strength of the bond between said adhesive composition and a coated face of said sheets, the tensile rupture strength of said microcapsules being such that the cohesive failure of the adhesive results in breakage of the microcapsules, and the tensile rupture strength between said two surfaces being at least 4.0 g/cm and less than 90 g/cm at 20° C. and 50%     
     
     
        relative humidity..Iaddend. .Iadd.29.  A device for exposing a liquid, said device consisting essentially of (1) two surfaces of coated paper bound by an adhesive composition layer, said coated paper comprising paper which is coated with a resinous binder and white, bone, or ivory pigment, and at least one of said surfaces having a high quality printed image thereon,   (2) said adhesive composition layer containing microcapsules with said liquid within the shell of said microcapsules, and   (3) said microcapsules having an average diameter between 4 and 80 micrometers, the cohesive strength of the adhesive composition layer being less than the strength of the bond between said adhesive composition and said surfaces of coated paper, the tensile rupture strength of said microcapsules being such that the cohesive failure of the adhesive results in breakage of the microcapsules, and the tensile rupture strength between said two surfaces being at least 4.0 g/cm and less than 90 g/cm at 20° C. and 50% relative humidity and greater than 4.0 g/cm after storage at 120° F. and low humidity for seventy-two hours..Iaddend.   
     
     
        .Iadd.30.  A device for exposing a liquid, said device consisting essentially of (1) two surfaces of high quality coated paper as conventionally used in the advertising trade, said surfaces being bound by an adhesive composition layer, said coated paper comprising paper which is coated with a resinous binder and white, bone, or ivory pigment, and at least one of said surfaces of coated paper having a high quality printed image thereon,   (2) said adhesive composition layer containing microcapsules within the shell of the microcapsules, and   (3) said microcapsules having an average diameter between 4 and 80 micrometers, the cohesive strength of the adhesive composition layer being less than the strength of the bond between said adhesive composition and said surfaces of coated paper, the tensile rupture strength of said microcapsule being such that the cohesive failure of the adhesive results in breakage of the microcapsules, and the tensile rupture strength between said two surfaces being at least 4.0 g/cm and less than 90 g/cm at 20° C. and 50% relative humidity.