Feed-water heater comprising low C-Cr-Mo steel components used under wet steam

Abstract

A novel low C-Cr-Mo steel having an excellent weldability and a high erosion-corrosion resistance under wet steam, which consists of, in % by weight, 0.02-0.14% of C, not more than 0.90% of Si, 0.30-0.80% of Mn, 0.70-1.60% of Cr, 0.40-0.70% of Mo and the remainder being susbtantially Fe. This novel steel is a very excellent material for fabricating the portions in the feed-water heater, for example, for a nuclear power generation plant, the portions being used under wet steam condition. The above described weldability and erosion-corrosion resistance can be improved, by additionally adding the second components of Cu, N, or B, the third components of Nb or V or the fourth components of Al, Ti or Zr in the respectively defined amounts.

What is claimed is: 
     
       1. In a feed-water heater comprising a water chamber provided with an inlet and an outlet for the feed-water flowing through the heater, heat exchanging tubes in which the feed-water exchanged and flowed to the outlet of the heater, support plates supporting the heat exchanging tubes at a proper distance and a shell into which heating fluids for heating the feed-water flowing in the heat exchanging tubes are introduced, the improvement comprising at least one of the heat exchanging tubes, the support plates and the shell is composed of a low C-Cr-Mo steel subjected to normalizing and tempering treatment and consisting of, in % by weight, 0.02-0.14% of C, not more than 0.90% of Si, 0.30-0.80% of Mn, 0.70-1.60% of Cr, 0.40-0.70% of Mo and the remainder being substantially Fe, and having a ferrite-pearlite microstructure. 
     
     
       2. In a feed-water heater comprising a water chamber provided with an inlet and an outlet for the feed-water flowing through the heater, heat exchanging tubes in which the feed-water charged into the heater through the inlet is heat exchanged and flowed to the outlet of the heater, support plates supporting the heat exchanging tubes at a proper distance and a shell in which heating fluids for heating the feed-water flowing in the heater exchanging tubes are introduced, the improvement comprising at least one of the heat exchanging tubes, the support plates and the shell is composed of a low C-Cr-Mo steel subjected to normalizing and tempering treatment and consisting of, in % by weight, 0.02-0.14% of C, not more than 0.90% of Si, 0.30-0.80% of Mn, 0.70-1.60% of Cr, 0.40-0.70% of Mo, at least one of Al, Ti and Zr in an amount of 0.005-0.08% in each element, and the remainder being substantially Fe, and having a ferrite-pearlite microstructure. 
     
     
       3. In a feed-water heater comprising a water chamber provided with an inlet and an outlet for the feed-water flowing through the heater, heat exchanging tubes in which the feed-water charged into the heater through the inlet is heat exchanged and flowed to the outlet of the heater, support plates supporting the heat exchanging tubes at a proper distance and a shell into which heating fluids for heating the feed-water flowing in the heat exchanging tubes are introduced, the improvement comprising at least one of the heat exchanging tubes, the support plates and the shell is composed of a low C-Cr-Mo steel subjected to normalizing and tempering treatment and consisting of, in % by weight, 0.02-0.14% of C, not more than 0.90% of Si, 0.30-0.80% of Mn, 0.70-1.60% of Cr, 0.40-0.70% of Mo, at least one of not more than 0.005% of B, at least one of Al, Ti and Zr in an amount of 0.005-0.08% in each element, and the remainder being substantially Fe, and having a ferrite-pearlite microstructure. 
     
     
       4. In a feed-water heater comprising a water chamber provided with an inlet and an outlet for the feed-water flowing through the heater, heat exchanging tubes in which the feed-water charged into the heater through the inlet is heat exchanged and flowed to the outlet of the heater, support plates supporting the heat exchanging tubes at a proper distance and a shell into which heating fluids for heating the feed-water flowing in the heat exchanging tubes are introduced, the improvement comprising at least one of the heat exchanging tubes, the support plates and the shell is composed of a low C-Cr-Mo steel subjected to normalizing and tempering treatment and consisting of, in % by weight, 0.02-0.14% of C, not more than 0.90% of Si, 0.30-0.80% of Mn, 0.70-1.60% of Cr, 0.40-0.70% of Mo, at least one of not more than 0.5% of Cu, not more than 0.5% of Ni and not more than 0.005% of B, at least one of not more than 0.05% of Nb and not more than 0.08% of V, at least one of Al, Ti and Zr in an amount of 0.005-0.08% in each element, and the remainder being substantially Fe, and having a ferrite-pearlite microstructure. 
     
     
       5. In a feed-water heater comprising a water chamber provided with an inlet and an outlet for the feed-water flowing through the heater, heat exchanging tubes in which the feed-water charged into the heater through the inlet is heat exchanged and flowed to the outlet of the heater, support plates supporting the heat exchanging tubes at a proper distance and a shell into which heating fluids for heating the feed-water flowing in the heat exchanging tubes are introduced, the improvement comprising at least one of the heat exchanging tubes, the support plates and the shell is composed of a low C-Cr-Mo steel subjected to normalizing and tempering treatment and consisting of, in % by weight, 0.02-0.14% of C, not more than 0.45% of Si, 0.30-0.80% of Mn, 0.70-1.60% of Cr, 0.40-0.70% of Mo, at least one of Al, Ti and Zr in an amount of 0.005-0.08% in each element, and the remainder being substantially Fe, and having a ferrite-pearlite microstructure. 
     
     
       6. In a feed-water heater comprising a water chamber provided with an inlet and an outlet for the feed-water flowing through the heater, heat exchanging tubes in which the feed-water charged into the heater through the inlet is heat exchanged and flowed to the outlet of the heater, support plates supporting the heat exchanging tubes at a proper distance and a shell into which heating exchanging tubes are introduced, the improvement comprising at least one of the heat exchanging tubes, the support plates and the shell is composed of a low C-Cr-Mo steel subjected to normalizing and tempering treatment and consisting of, in % by weight, 0.02-0.14% of C, not more than 0.45% of Si, 0.30-0.80% of Mn, 0.70-1.60% of Cr, 0.40-0.70% of Mo, at least one of not more than 0.5% of Cu, not more than 0.5% of Ni and not more than 0.005% of B, at least one of Al, Ti and Zr in an amount of 0.005-0.08% in each element, and the remainder being substantially Fe, and having a ferrite-pearlite microstructure. 
     
     
       7. The feed-water heater as claimed in claim 3, 4 or 6, wherein C is not more than 0.13%, Cu and Ni are 0.16-0.30%, in % by weight. .Iadd. 
     
     
       8.  In a feed-water heater comprising a water chamber provided with an inlet and an outlet for the feed-water flowing through the heater, heat exchanging tubes in which the feed-water charged into the heater through the inlet is heat exchanged and flowed to the outlet of the heater, support plates supporting the heat exchanging tubes at a proper distance and a shell into which heating fluids for heating the feed-water flowing in the heat exchanging tubes are introduced, the improvement comprising at least one of the heat exchanging tubes, the support plates and the shell is composed of a low C-Cr-Mo steel subjected to annealing treatment and consisting of in % by weight, 0.02-0.14% of C, not more than 0.90% of Si, 0.30-0.80% of Mn, 0.70-1.60% of Cr, 0.40-0.70% of Mo and the remainder being substantially Fe, and having a ferrite-pearlite microstructure. .Iaddend. .Iadd.9. In a feed-water heater comprising a water chamber provided with an inlet and an outlet for the feed-water flowing through the heater, heat exchanging tubes in which the feed-water charged into the heater through the inlet is heat exchanged and flowed to the outlet of the heater, support plates supporting the heat exchanging tubes at a proper distance and a shell in which heating fluids for heating the feed-water flowing in the heat exchanging tubes are introduced, the improvement comprising at least one of the heat exchanging tubes, the support plates and the shell is composed of a low C-Cr-Mo steel subjected to annealing treatment and consisting of, in % by weight, 0.02-0.14% of C, not more than 0.90% of Si, 0.30-0.80% of Mn, 0.70-1.60% of Cr, 0.40-0.70% of Mo, at least one of Al, Ti and Zr in an amount of 0.005-0.08% in each element, and the remainder being substantially Fe, and having a ferrite-pearlite microstructure. .Iaddend. .Iadd.10. In a feed-water heater comprising a water chamber provided with an inlet and an outlet for the feed-water flowing through the heater, heat exchanging tubes in which the feed-water charged into the heater through the inlet is heat exchanged and flowed to the outlet of the heater, support plates supporting the heat exchanging tubes at a proper distance and a shell into which heating fluids for heating the feed-water flowing in the heat exchanging tubes are introduced, the improvement comprising at least one of the heat exchanging tubes, the support plates and the shell is composed of a low C-Cr-Mo steel having been subjected to annealing treatment and consisting of, in % by weight, 0.02-0.14% of C, not more than 0.90% of Si, 0.30-0.80% of Mn, 0.70-1.60% of Cr, 0.40-0.70% of Mo, at least one of not more than 0.5% of Cu, not more than 0.5% of Ni and not more than 0.005% of B, at least one of Al, Ti and Zr in an amount of 0.005-0.08% in each element, and the remainder being substantially Fe, and having a ferrite-pearlite 
     
     
        microstructure. .Iaddend. .Iadd.11.  In a feed-water heater comprising a water chamber provided with an inlet and an outlet for the feed-water flowing through the heater, heat exchanging tubes in which the feed-water charged into the heater through the inlet is heat exchanged and flowed to the outlet of the heater, support plates supporting the heat exchanging tubes at a proper distance and a shell into which heating fluids for heating the feed-water flowing in the heat exchanging tubes are introduced, the improvement comprising at least one of the heat exchanging tubes, the support plates and the shell is composed of a low C-Cr-Mo steel subjected to annealing treatment and consisting of, in % by weight, 0.02-0.14% of C, not more than 0.90% of Si, 0.30-0.80% of Mn, 0.70-1.60% of Cr, 0.40-0.70% of Mo, at least one of not more than 0.5% of Cu, not more than 0.5% of Ni and not more than 0.005% of B, at least one of not more than 0.05% of Nb and not moe than 0.08% of V, at least one of Al, Ti and Zr in an amount of 0.005-0.08% in each element, and the remainder being substantially Fe, and having a ferrite-pearlite microstructure. .Iaddend. .Iadd.12. In a feed-water comprising a water chamber provided with an inlet and an outlet for the feed-water flowing through the heater, heat exchanging tubes in which the feed-water charged into the heater through the inlet is heat exchanged and flowed to the outlet of the heater, support plates supporting the heat exchanging tubes at a proper distance and a shell into which heating fluids for heating the feedwater flowing in the heat exchanging tubes are introduced, the improvement comprising at least one of the heat-exchanging tubes, the support plates and the shell is composed of a low C-Cr-Mo steel subjected to annealing treatment and consisting of, in % by weight, 0.02-0.14% of C, not more than 0.45% of Si, 0.30-0.80% of Mn, 0.70-1.60% of Cr, 0.40-0.70% of Mo, at least one of Al, Ti and Zr in an amount of 0.005-0.08% in each element, and the remainder being substantially Fe, and having a ferrite-pearlite microstructure. .Iaddend. .Iadd.13. In a feed-water heater comprising a water chamber provided with an inlet and an outlet for the feed-water flowing through the heater, heat exchanging tubes in which the feed-water charged into the heater through the inlet is heat exchanged and flowed to the outlet of the heater, support plates supporting the heat exchanging tubes at a proper distance and a shell into which heating exchanging tubes are introduced, the improvement comprising at least one of the heat exchanging tubes, the support plates and the shell is composed of a low C-Cr-Mo steel subjected to annealing treatment and consisting of, in % by weight, 0.02-0.14% of C, not more than 0.45% of Si, 0.30-0.80% of Mn, 0.70-1.60% of Cr, 0.40-0.70% of Mo, at least one of not not more than 0.5% of Cu, not more than 0.5% of Ni and not more than 0.005% of B, at least one of Al, Ti and Zr in an amount of 0.005-0.08% in each element, and the remainder being substantially Fe, and having a ferrite-pearlite microstructure. .Iaddend. .Iadd.14. The feed-water heater as claimed in claim 10, 11 or 13, wherein C is not more than 0.13%, Cu and Ni are 0.16-0.30%, in % by weight. .Iaddend.