Magnesium oxide-carboxlate complexes, method for their preparation, and compositions containing same

Abstract

Magnesium-containing complexes are prepared by heating a mixture of magnesium hydroxide, magnesium oxide, hydrated magnesium oxide or a magnesium alkoxide; a carboxylic acid, a sulfonic acid, a pentavalent phosphorus acid, or an ester or salt of any of these; water; and an organic solubilizing agent (which may be liquid or solid at ambient temperature) for the acid or ester. The amount of magnesium is such as to provide a basic composition. The resulting complexes may be obtained in liquid (which may be thickened) or solid form, and are useful as additives for lubricants and fuels and as protective coating compositions for metal surfaces (such as automotive undercoats and frame coatings). .[.This application is a continuation-in-part of copending application Ser. No. 681,627, filed Apr. 29, 1976 and now abandoned..].

What is claimed is: 
     
       1. A method for preparing a non-carbonated magnesium-containing complex which comprises heating, at a temperature above about 30° C., a mixture .[.comprising:.]. .Iadd.consisting essentially of:.Iaddend. (A) At least one of magnesium hydroxide, magnesium oxide, hydrated magnesium oxide .[.,.]. or a magnesium alkoxide;   (B) At least one oleophilic organic reagent .[.comprising a.]. .Iadd.consisting essentially of an aliphatic, cycloaliphatic or aromatic .Iaddend.carboxylic acid .[., a sulfonic acid, a pentavalent phosphorus acid, or an ester or alkali metal or alkaline earth metal salt of any of these.]. .Iadd.containing at least eight carbon atoms or an ester or alkali metal or alkaline earth metal salt thereof .Iaddend.;   (C) Water; and   (D) At least one organic solubilizing agent for component B; the ratio of equivalents of magnesium to component B, calculated as the free carboxylic .[.or sulfonic acid or as the phosphoric.]. acid .[.ester.]., being at least about .[.5:1 .Iadd.25:1 to about 60:1.Iaddend., and the amount of water present being at least sufficient to hydrate a substantial proportion of component A calculated as magnesium oxide .Iadd.to obtain a gelled product.Iaddend..   
     
     
       2. A method according to claim 1 wherein component D is at least one substantially inert, normally liquid organic diluent. .[.3. A method according to claim 2 wherein component B is at least one sulfonic acid or 
     
     
        salt thereof..]. 4. A method according to claim .[.3.]. .Iadd.2 .Iaddend.wherein the molar ratio of component C to component A is at least about 0.7:1. .[.5. A method according to claim 4 wherein component B is at 
     
     
        least one alkylaromatic sulfonic acid..]. .[.6.  A method according to claim 5 wherein component B is at least one alkylbenzenesulfonic acid..]. 
     
     
         . A method according to claim .[.6.]. .Iadd.4 .Iaddend.wherein component A is magnesium oxide. .[.8. A method according to claim 2 wherein component B is a mixture of at least one alkylbenzenesulfonic acid and at least one hydrogenated fatty acid or carboxylic acid formed by oxidation of petrolatum..]. .[.9. A method according to claim 8 wherein the mole ratio of component C to component A is at least about 0.7:1..]. .[.10. A method according to claim 9 wherein component A is magnesium oxide..]. 
     
     
            A method according to claim 1 wherein component D is at least one substantially inert organic material which is solid at ambient temperature. .[.12. A method according to claim 11 wherein component B is 
     
     
        at least one sulfonic acid or salt thereof..]. 13. A method according to claim .[.12.]. .Iadd.11 .Iaddend.wherein the molar ratio of component C to component A is at least about 0.7:1. .[.14. A method according to claim 13 wherein component B is at least one alkylaromatic sulfonic acid..]. .[.15. A method according to claim 14 wherein component B is at least one 
     
     
        alkylbenzenesulfonic acid..]. 16. A method according to claim .[.15.]. 
     
     
        .Iadd.13 .Iaddend.wherein component A is magnesium oxide. 17. A method according to claim 1 wherein component D is a mixture of at least one substantially inert material which is solid at ambient temperature with at least one substantially inert, normally liquid organic diluent. .[.18. A method according to claim 17 wherein component B is at least one sulfonic 
     
     
        acid or a magnesium salt thereof..]. 19. A method according to claim .[.18.]. .Iadd.17 .Iaddend.wherein the molar ratio of component C to component A is at least about 0.7:1. .[.20. A method according to claim 19 wherein component B is at least one alkylaromatic sulfonic acid..]. .[.21. A method according to claim 20 wherein component B is at least one 
     
     
        alkylbenzenesulfonic acid..]. 22. A method according to claim .[.21.]. .Iadd.19 .Iaddend.wherein component A is magnesium oxide. .[.23. A method according to claim 17 wherein component B is a mixture of at least one alkylbenzenesulfonic acid and at least one carboxylic acid formed by oxidation of petrolatum..]. .[.24. A method according to claim 23 wherein the mole ratio of component C to component A is at least about 0.7:1..]. .[.25. A method according to claim 24 wherein component A is magnesium 
     
     
        oxide..]. 26. A complex prepared by the method of claim 1. 27. A complex prepared by the method of claim .[.3.]. .Iadd.4..Iaddend. .[.28. A complex prepared by the method of claim 5..]. .[.29. A complex prepared by the method of claim 6..]. .[.30. A complex prepared by the method of claim 
     
     
        8..]. 31. A complex which is solid at ambient temperature, prepared by the 
     
     
        method of claim 11. 32. A complex which is solid at ambient temperature, prepared by the method of claim .[.12.]. .Iadd.13..Iaddend. .[.33. A complex which is solid at ambient temperature, prepared by the method of claim 14..]. .[.34. A complex which is solid at ambient temperature, 
     
     
        prepared by the method of claim 15..]. 35. A thickened complex according 
     
     
        to claim 26. 36. A thickened complex according to claim 27. .[.37. A thickened complex according to claim 28..]. .[.38. A thickened complex according to claim 29..]. .[.39. A thickened complex according to claim 
     
     
        30..]. 40. A thickened complex prepared by the method of claim 17. 41. A thickened complex prepared by the method of claim .[.18.]. .Iadd.19..Iaddend. .[.42. A thickened complex prepared by the method of claim 20..]. .[.43. A thickened complex prepared by the method of claim 21..]. .[.44. A thickened complex prepared by the method of claim 23..]. .[.45. A complex of magnesium oxide or hydroxide and a magnesium sulfonate prepared by heating, at a temperature within the range of about 40°-90° C., a mixture comprising: (A) Magnesium oxide;   (B) An alkylbenzenesulfonic acid having an equivalent weight within the range of about 300-500;   (C) Water; and   (D) At least one of mineral oil, Stoddard solvent, toluene and the alkylbenzene whose sulfonation product is component B;   the ratio of equivalents of component A to component B being at least about 5:1 and the molar ratio of component C to component A being between about 0.7:1 and 3.0:1..]. .[.46. A thickened complex according to claim 45..]. .[.47. A complex of magnesium oxide or hydroxide and a magnesium sulfonate which is solid at ambient temperature and which is prepared by heating, at a temperature within the range of about 95°-150° C., a mixture comprising:   (A) Magnesium oxide;   (B) An alkylbenzenesulfonic acid having an equivalent weight within the range of about 300-500;   (C) Water; and   (D) A mixture comprising hydrocarbon waxes, C 20-40  waxy aliphatic alcohols and the alkylbenzene whose sulfonation product is component B;   the ratio of equivalents of component A to component B being at least about 5:1 and the molar ratio of component C to component A being between about   
     
     
        0.7:1 and 3.0:1..]. 48. An additive concentrate comprising a substantially inert, normally liquid organic diluent and about 20-90% by weight of the complex of claim 26. .[.49. An additive concentrate comprising a substantially inert, normally liquid organic diluent and about 20-90% by 
     
     
        weight of the complex of claim 45..]. 50. A composition comprising a major amount of a lubricating oil and a minor amount sufficient to impart detergency thereto of the complex of claim 26. .[.51. A composition comprising a major amount of a lubricating oil and a minor amount, sufficient to impart detergency thereto and comprising about 0.5-10.0% by 
     
     
        weight, of the complex of claim 45..]. 52. A composition comprising a major amount of a normally liquid fuel and a minor amount, sufficient to impart corrosion resistance thereto, suppress smoke or serve as a vanadium scavenger, of the complex of claim 26. .[.53. A composition comprising a major amount of a normally liquid fuel and a minor amount, sufficient to impart corrosion resistance thereto, suppress smoke or serve as a vanadium scavenger and comprising about 4-1000 parts by weight per million parts of 
     
     
        fuel, of the complex of claim 45..]. .Iadd.54.  The method of claim 1 additionally containing a sulfonic acid or salt thereof..Iaddend. .Iadd.55. The method of claim 54 wherein the sulfonic acid is at least one alkylaromatic sulfonic acid..Iaddend. .Iadd.56. The method according to claim 55 wherein the alkylaromatic sulfonic acid is an alkylbenzene sulfonic acid..Iaddend. .Iadd.57. The method of claim 1 wherein component D is not substantially removed from the gelled product..Iaddend. .Iadd.58. The method of claim 1 wherein the carboxylic acid contains at least 12 carbon atoms..Iaddend.