Room temperature stable organopolysiloxane compositions

Abstract

Room temperature stable organopolysiloxane compositions containing organosilicon compounds having Si-bonded hydrogen atoms and aliphatic multiple bonds, a platinum catalyst which promotes the addition of Si-bonded hydrogen atoms to the aliphatic multiple bonds and an inhibitor which prevents premature crosslinking at room temperature selected from the group consisting of a maleinimide and a maleic acid derivative of the formula ##STR1## where R 1 is a hydroxyl group or a trimethylsiloxy group and R 2 is a monovalent hydrocarbonoxy radical having from 1 to 20 carbon atoms per radical, which is bonded to the carbon atom of the ##STR2## group or a monovalent hydrocarbonoxy radical having from 1 to 20 carbon atoms per radical, which is bonded to the carbon atom of the ##STR3## group and which is substituted with at least one triorganosilyl group.

What is claimed is: 
     
       1. A crosslinkable organopolysiloxane composition comprising an organosilicon compound having Si-bonded hydrogen atoms, in organosilicon compound having aliphatic multiple bonds, a platinum catalyst capable of promoting the addition of the Si-bonded hydrogen atoms to the aliphatic multiple bonds and an inhibitor which delays or prevents crosslinking at room temperature which is selected from the group consisting of maleinimide and a maleic acid derivative selected from the group consisting of ##STR27## and R 6  (SiR 2   7  O) x  (SiR 7  R 6  O) y  SiR 2   7  R 6 , where R 1  is .[.selected from the group consisting of a hydroxyl group and.]. a trimethylsiloxy group, R 2  is a radical selected from the group consisting of a hydrocarbonoxy radical which is bonded to the carbon atom of the ##STR28## group and a hydrocarbonoxy radical which is bonded to the carbon atom of the ##STR29## group and is substituted with at least one triorganosilyl group, at least one R 6  is a radical of the formula ##STR30## and the other R 6  radicals are selected from the group consisting of the formula   --O(CR.sub.2.sup.4).sub.n OH     and R 7 , where R 1  is the same as above, R 4  is selected from the group consisting of hydrogen and an alkyl radical having from 1 to 6 carbon atoms per radical, R 7  is selected from the group consisting of phenyl and alkyl radicals having 2 or 3 carbon atoms per radical and halogenated phenyl and alkyl radicals having 2 or 3 carbon atoms per radical, n is an integer having a value of from 3 to 19, x is 0 or an integer having a value of from 1 to 200 and y is an integer having a value of from 1 to 10.   
     
     
       2. The composition of claim 1, wherein the maleic acid derivative has the formula ##STR31## where R 1  is .[.selected from the group consisting of a hydroxyl group and.]. a trimethylsiloxy group and R 2  is a hydrocarbonoxy radical which is bonded to the carbon atom of the ##STR32## group. 
     
     
       3. The composition of claim 1, wherein R 1  is .[.selected from the group consisting of a hydroxyl group and.]. a trimethylsiloxy group and R 2  represents a hydrocarbonoxy radical which is substituted with a triorganosilyl group. 
     
     
       4. The composition of claim 1, wherein R 2  is a radical of the formula, --O(CR 2   4 ) n  SiR 3   5 ,   where R 4  is selected from the group consisting of hydrogen and an alkyl radical having from 1 to 3 carbon atoms per radical, R 5  is an alkyl radical having from 1 to 3 carbon atoms per radical, and n is an integer having a value of from 3 to 19.   
     
     
       5. The composition of claim 1, wherein the maleic acid derivative has the formula   R.sup.6 (SiR.sub.2.sup.7 O).sub.x (SiR.sup.7 R.sup.6 O).sub.y SiR.sup.7 R.sup.6     and at least one of the R 6  radicals has the formula ##STR33## where R 1  is .[.selected from the group consisting of a hydroxyl group and.]. a trimethylsiloxy group, and the other R 6  radicals are selected from the group consisting of a radical of the formula     --O(CR.sub.2.sup.4).sub.n OH     and R 7 , where R 7  is selected from the group consisting of phenyl and alkyl radicals having 2 or 3 carbon atoms per radical and halogenated phenyl and alkyl radicals having 2 or 3 carbon atoms per radical, R 4  is selected from the group consisting of hydrogen and an alkyl radical having from 1 to 6 carbon atoms per radical, n is an integer having a value of from 3 to 19, x represents 0 or an integer having a value of from 1 to 200 and y is an integer having a value of from 1 to 10.   
     
     
       6. The composition of claim 1, wherein the maleic acid derivative is present in an amount of from 0.001 to 1 percent by weight, based on the total weight of the organosilicon compounds. 
     
     
       7. A method for inhibiting premature crosslinking of organopolysiloxane compositions at room temperature, which comprises mixing an organosilicon compound having Si-bonded hydrogen atoms with an organosilicon compound containing aliphatic multiple bonds, a platinum catalyst capable of promoting the addition of the Si-bonded hydrogen to the aliphatic multiple bonds and an inhibitor selected from the group consisting of maleinimide and a maleic acid derivative selected from the group consisting of ##STR34## and R 6  (SiR 2   7  O) x  (SiR 7  R 6  O) y  SiR 2   7  R 6 , where R 1  is .[.selected from the group consisting of a hydroxyl group and.]. a trimethylsiloxy group, R 2  is a radical selected from the group consisting of a hydrocarbonoxy radical which is bonded to the carbon atom of the ##STR35## group and a hydrocarbonoxy radical which is bonded to the carbon atom of the ##STR36## group and is substituted with at least one triorganosilyl group, at least one R 6  is a radical of the formula ##STR37## and the other R 6  radicals are selected from the group consisting of a radical of the formula   --O(CR.sub.2.sup.4).sub.n OH     and R 7 , where R 1  is the same as above, R 4  is selected from the group consisting of hydrogen and an alkyl radical having from 1 to 6 carbon atoms per radical, R 7  is selected from the group consisting of phenyl and alkyl radicals having 2 or 3 carbon atoms per radical and halogenated phenyl and alkyl radicals having 2 or 3 carbon atoms per radical, n is an integer having a value of from 3 to 19, x is 0 or an integer having a value of from 1 to 200 and y is an integer having a value of from 1 to 10.   
     
     
       8. The method of claim 7, wherein the composition is crosslinked by heating to a temperature of from 60° to 180° C. .Iadd. 
     
     
       9.  A crosslinkable organopolysiloxane composition comprising an organosilicon compound having Si-bonded hydrogen atoms, an organosilicon compound having aliphatic multiple bonds, a platinum catalyst capable of promoting the addition of the Si-bonded hydrogen atoms to the aliphatic multiple bonds and an inhibitor which delays or prevents crosslinking at room temperature, which is selected from the group consisting of maleinimide and a maleic acid derivative selected from the group consisting of ##STR38## and R 6  (SiR 2   7  O) x  (SiR 7  R 6  O) y  SiR 2   7  R 6 , where R 1  is a hydroxyl group, R 2  is a hydrocarbonoxy radical which is bonded to the carbon atom of the ##STR39## group and is substituted with at least one triorganosilyl group, at least one R 6  is a radical of the formula ##STR40## and the other R 6  radicals are selected from the group consisting of the formula   --O(CR.sub.2.sup.4).sub.n OH     and R 7 , where R 1  is the same as above, R 4  is selected from the group consisting of hydrogen and an alkyl radical having from 1 to 6 carbon atoms per radical, R 7  is selected from the group consisting of phenyl and alkyl radicals having 2 or 3 carbon atoms per radical and halogenated phenyl and alkyl radicals having 2 or 3 carbon atoms per radical, n is an integer having a value of from 3 to 19, x represents 0 or an integer having a value of from 1 to 200 and y is an integer having a value of from 1 to 10. .Iaddend. .Iadd.   
     
     
       10.  The composition of claim 9, wherein R 2  is a radical of the formula   --O(CR.sub.2.sup.4).sub.n SiR.sub.3.sup.5,     where R 4  is selected from the group consisting of hydrogen and an alkyl radical having from 1 to 6 carbon atoms per radical, R 5  is an alkyl radical having from 1 to 3 carbon atoms per radical, and n is an integer having a value of from 3 to 19. .Iaddend. .Iadd.11. The composition of claim 9, wherein the maleic acid derivative has the formula     R.sup.6 (SiR.sub.2.sup.7 O).sub.x (SiR.sup.7 R.sup.6 O).sub.y SiR.sup.7 R.sup.6     and at least one of the R 6  radicals has the formula ##STR41## where R 1  is a hydroxyl group and the other R 6  radicals are selected from the group consisting of a radical of the formula     --O(CR.sub.2.sup.4).sub.n OH     and R 7 , where R 7  is selected from the group consisting of phenyl and alkyl radicals having 2 or 3 carbon atoms per radical and halogenated phenyl and alkyl radicals having 2 or 3 carbon atoms per radical, R 4  is selected from the group consisting of hydrogen and an alkyl radical having from 1 to 6 carbon atoms per radical, n is an integer having a value of from 3 to 19, x represents 0 or an integer having a value of from 1 to 200 and y is an integer having a value of from 1 to 10. .Iaddend.   
     
     
        .Iadd.12.  The composition of claim 9, wherein the maleic acid derivative is present in an amount of from 0.001 to 1 percent by weight, based on the total weight of the organosilicon compounds. .Iaddend. .Iadd.13. A method for inhibiting premature crosslinking of organopolysiloxane compositions at room temperature, which comprises mixing an organosilicon compound having Si-bonded hydrogen atoms with an organosilicon compound containing aliphatic multiple bonds, a platinum catalyst capable of promoting the addition of the Si-bonded hydrogen to the aliphatic multiple bonds and an inhibitor selected from the group consisting of maleinimide and a maleic acid derivative selected from the group consisting of ##STR42## and R 6  (SiR 2   7  O) x  (SiR 7  R 6  O) y  SiR 2   7  R 6 , where R 1  is a hydroxyl group, R 2  is a hydrocarbonoxy radical which is bonded to the carbon atom of the ##STR43## group and is substituted with at least one triorganosilyl group, at least one R 6  is a radical of the formula ##STR44## and the other R 6  radicals are selected from the group consisting of a radical of the formula   --O(CR.sub.2.sup.4).sub.n OH     and R 7 , where R 1  is the same as above, R 4  is selected from the group consisting of hydrogen and an alkyl radical having from 1 to 6 carbon atoms per radical, R 7  is selected from the group consisting of phenyl and alkyl radicals having 2 or 3 carbon atoms per radical and halogenated phenyl and alkyl radicals having 2 or 3 carbon atoms per radical, n is an integer having a value of from 3 to 19, x represents 0 or an integer having a value of from 1 to 200 and y is an integer having a   
     
     
        value of from 1 to 10. .Iaddend. .Iadd.14.  The method of claim 13, wherein the composition is crosslinked by heating to a temperature of from 60° to 180° C. .Iaddend.