Self-emulsifying anaerobic composition

Abstract

A self-emulsifying anaerobic-curing composition is disclosed. The composition is rendered self-emulsifying by incorporating certain anionic and/or nonionic surfactants in a concentration range of about 0.25 to about 10.0 percent. The preferred anionics comprise the petroleum sulfonates and the sodium alkyl or alkylaryl sulfonates. The preferred nonionics comprise the ethoxylated alkyl alcohols, the ethoxylated alkyl phenols, and the polyoxyethylene/polyoxypropylene glycols. Any anaerobic monomer or monomer mixture in which the surfactant is soluble and compatible with the cure system may be used. These self-emulsifiable compositions have the advantage of being readily removed from surfaces by washing with water, which makes them especially useful in impregnation processes where uncured resin must be removed from areas which are difficult to wash, such as small, blind holes.

I claim: .[.1. An anaerobic curing composition which is self-emulsifiable upon mixing with water comprising: 
     
        water..]. 2. A composition of claim .[.1.]. .Iadd.15 .Iaddend.wherein the concentration of the surfactant is about 0.5 to 5.0 percent by weight of 
     
     
        the total composition. 3. A composition of claim .[.1.]. .Iadd.15 .Iaddend.wherein the concentration of the surfactant is about 1.0 to 2.5 
     
     
        percent by weight of the total composition. 4. A composition of claim 
     
     
        .[.1.]. .Iadd.15 .Iaddend.wherein the surfactant is anionic. 5. A composition of claim .[.1.]. .Iadd.15 .Iaddend.wherein the surfactant is 
     
     
        nonionic. 6. A composition of claim .[.1.]. .Iadd.15 .Iaddend.wherein the 
     
     
        surfactant is a mixture of anionic and nonionic surfactants. 7. A composition of claim 4 wherein the surfactant is a petroleum sulfonate. 
     
     
           A composition of claim 4 wherein the surfactant is an alkali alkyl 
     
     
        sulfonate or alkylaryl sulfonate. 9. A composition of claim 5 wherein the surfactant is an ethoxylated linear or branched primary or secondary 
     
     
        alcohol. 10. A composition of claim 5 wherein the surfactant is an 
     
     
        ethoxylated linear or branched alkyl phenol. 11. A composition of claim 5 
     
     
        wherein the surfactant is a polyoxyethylene/polyoxypropylene glycol. 12. A composition of claim .[.1.]. .Iadd.15 .Iaddend.wherein at least a portion of the polymerizable anaerobic sealant has the formula ##STR9## wherein R 4  represents a radical selected from the group consisting of hydrogen, lower alkyl of from 1 to about 4 carbon atoms, hydroxy alkyl of from 1 to about 4 carbon atoms, and ##STR10## R 3  is a radical selected from the group consisting of hydrogen, halogen and lower alkyl of from 1 to about 4 carbon atoms; R 5  is a radical selected from the group consisting of hydrogen, hydroxyl and ##STR11## 
     
     
        m is 0 to about 12, n is at least 1, and p is 0 or 1. .[.13.  A composition of claim 1 containing in addition an accelerator of anaerobic 
     
     
        polymerization..]. 14. A composition of claim .[.13.]. .Iadd.15 
     
     
        .Iaddend.wherein the accelerator is a sulfimide. .Iadd.15.  An anaerobic curing composition which is self-emulsifiable upon mixing with water comprising: a. an anaerobically curing acrylate monomer;   b. a peroxy initiator in sufficient concentration to initiate cure of the monomer upon exclusion of oxygen, said peroxy initiator being selected from the group consisting of hydroperoxides and peresters which decompose to form free radicals;   c. about 0.25 to 10.0 percent by weight of the total composition of an anionic or nonionic surfactant which is dissolved in the composition and which renders the composition self-emulsifying upon mixing with water; and   d. an accelerator of anaerobic polymerization..Iaddend.