Solutions for stabilizing thermoplastic polycarbonates

Abstract

Certain solutions of phosphines in oxetane compounds impart oxidative stability to aromatic thermoplastic polycarbonates in which such solutions are admixed.

What is claimed is: 
     
       1. A solution comprising at least one phosphine of the general formula   (R).sub.2 P-R.sub.1                                        I     wherein   R and R 1  independently denote an unsubstituted or substituted C 6  to C 14  aryl radical and   R 1  may additionally denote an unsubstituted or substituted C 1  to C 18  alkyl radical in at least one oxetane compound of the general formula ##STR3## wherein R 2  denotes a C 1  to C 16  alkyl radical and     R 3  is either an n-valent radical of a C 2  to C 8  alkane, which may be substituted by at least one OH group and   n is 1, 2, 3, 4, 5, or 6 or   R 3  is a divalent radical of a cycloalkane and n is 2, or in at least one oxetane compound of the general formula ##STR4## wherein R 2  denotes a C 1  to C 16  alkyl radical,   R 4  denotes a C 1  to C 4  alkyl radical which may be substituted by cyano, carboxyl or acetoxy, an allyl radical, a C 6  to C 14  aryl radical which may be substituted by alkyl, or a C 7  to C 14  aralkyl or C 1  to C 4  alkoxy radical which may be substituted by C 1  to C 4  alkoxy or allyloxy,   m is 1, 2, 3, or 4 and   r is 0, 1, 2 or 3 with the proviso that m+r equal 4, in which the mixing ratio of dissolved phosphine of the formula I to solvent, containing oxetane groups, of the formula II or III is between 3 and 10 oxetane group equivalents of the solvent containing oxetane groups per atom equivalent of phosphorus of the phosphine.     
     
     
       2. The solution of claim 1, wherein said mixing ratio is between 4 and 8 oxetane group equivalents of the solvent containing oxetane groups per atom equivalent of phosphorus of the phosphine. 
     
     
       3. The solution of claim 1 wherein said R is a C 6  to C 14  aryl, substituted by a member selected from the group consisting of alkyl, halogen and OH radicals. 
     
     
       4. The solution of claim 1 wherein said R 1  is a straight chain C 1  to C 18  alkyl. 
     
     
       5. The solution of claim 1 wherein said R 1  is a branched C 3  to C 18  alkyl. 
     
     
       6. The solution of claim 1 wherein said R 1  is substituted by a member selected from the group consisting of OH, alkyl carboxy, cyano or phenyl radicals. 
     
     
       7. A process for stabilizing a thermoplastic polycarbonate comprising adding thereto a stabilizer solution comprising at least one phosphine of the general formula   (R).sub.2 P--R.sub.1                                       I     wherein   R and R 1  independently denote an unsubstituted or substituted C 6  to C 14  aryl radical and   R 1  may additionally denote an unsubstituted or substituted C 1  to C 18  alkyl radical in at least one oxetane compound of the general formula ##STR5## wherein R 2  denotes a C 1  to C 16  alkyl radical and     R 3  is either an n-valent radical of a C 2  to C 8  alkane, which may be substituted by at least one OH group and   n is 1, 2, 3, 4, 5, or 6 or   R 3  is a divalent radical of a cycloalkane and   n is 2, or in at least one oxetane compound of the general formula ##STR6## wherein R 2  denotes a C 1  to C 16  alkyl radical,     R 4  denotes a C 1  to C 4  alkyl radical which may be substituted by cyano, carboxyl or acetoxy, an allyl radical, a C 6  to C 14  aryl radical which may be substituted by alkyl, or a C 7  to C 14  aralkyl or C 1  to C 4  alkoxy radical which may be substituted by C 1  to C 4  alkoxy or allyloxy,   m is 1, 2, 3, or 4 and   r is 0, 1, 2 or 3 with the proviso that m+r equal 4, in which the mixing ratio of dissolved phosphine of the formula I to solvent, containing oxetane groups, of the formula II or III is between 3 and 10 oxetane group equivalents of the solvent containing oxetane groups per atom equivalent of phosphorus of the phosphine said solution being added to said polycarbonate either during or after its preparation.     
     
     
       8. The process of claim 7 wherein said mixing ratio is between 4 and 8 oxetane group equivalents of the solvent containing oxetane groups per atom equivalent of phosphorus of the phosphine. 
     
     
       9. The process of claim 7 wherein said R 1  is a C 6  to C 14  aryl, substituted by a member selected from the group consisting of alkyl, halogen and OH radicals. 
     
     
       10. The process of claim 7 wherein said R 1  is a straight chain C 1  to C 18  alkyl. 
     
     
       11. The process of claim 7 wherein said R 1  is a branched C 3  to C 18  alkyl. 
     
     
       12. The process of claim 7 wherein said R 1  is substituted by a member selected from the group consisting of OH, alkyl carboxy, cyano or phenyl radicals. 
     
     
       13. The process of claim 11 wherein said stabilizer solution is added in an amount of 0.01 to 1% by weight, relative to the total weight of thermoplastic polycarbonate and stabilizer solution. 
     
     
       14. The process of claim 11 wherein said stabilizer solution is added in an amount of 0.05 to 0.2% by weight, relative to the total weight of thermoplastic polycarbonate and stabilizer solution. 
     
     
       15. A stabilized thermoplastic polycarbonate obtained by the process of claim 11. .Iadd. 
     
     
       16.  A stabilized thermoplastic polycarbonate obtained by the process of claim 7. .Iaddend.