High solids pigment coating composition

Abstract

A high solids pigmented coating composition is prepared from a curing agent and an ester diol binder which is a mixture of (a) 20-80 mole % of a compound having the general formula: ##STR1## where R 1 represents the group formed by abstraction of the two carboxyl groups from a cycloaliphatic and/or aromatic dicarboxylic acid having 8 to 20 carbon atoms and R 2 and R 3 may be the same or different and represent groups formed by abstraction of the two hydroxyl groups from a divalent alcohol having 2 to .[.12.]. .Iadd.6 .Iaddend.carbon atoms, and m is a number of 1 - 3, and (b) 80-20 mole % of a compound having the general formula: ##STR2## where R 4 represents the group formed by abstraction of the two carboxyl groups from an aliphatic dicarboxylic acid having 2 to 12 carbon atoms, and R 5 and R 6 may be the same or different and represent groups formed by abstraction of the two hydroxyl groups from a divalent alcohol having 2 to .[.12.]. .Iadd.6 .Iaddend.carbon atoms, and n is a number of 1 - 3.

What is claimed is: 
     
       1. A high solids pigmented coating composition prepared from a blend of an ester diol as binder and a curing agent for the binder, characterized in that (1) the ester diol is a mixture of (a) 20-80 mole % of an ester diol having the general formula: ##STR5## where R 1  represents the group formed by abstraction of the carboxyl groups from a cycloaliphatic and/or aromatic dicarboxylic acid having 8 to 20 carbon atoms and R 2  and R 3  may be the same or different and represent groups formed by abstraction of the two hydroxyl groups from a divalent alcohol having 2 to .[.12.]. .Iadd.6 .Iaddend.carbon atoms, and m is a number of 1-3, and   (b) 80-20 mole % of an ester diol having the general formula: ##STR6## where R 4  represents the group formed by abstraction of the two carboxyl groups from an aliphatic dicarboxylic acid having 2 to 12 carbon atoms, and R 5  and R 6  may be the same or different and represent groups formed by abstraction of the two hydroxyl groups from a divalent alcohol having 2 to .[.12.]. .Iadd.6 .Iaddend.carbon atoms, and n is a number of 1-3,   (2) the curing agent for the binder is an aminoplast, and   (3) the amount of pigment in said coating composition is at least 30% by weight, based on the total solids content.   
     
     
       2. The coating composition of claim 1 characterized in that the molar ratio of the ester diols is between 3:1 and 1:3. 
     
     
       3. The coating composition of claim 1 characterized in that the molar ratio of the ester diols is between 2:1 and 1:2. 
     
     
       4. The coating composition of claim 1 characterized in that one of the ester diols is formed from a cycloaliphatic or aromatic dicarboxylic acid containing 8 to 10 carbon atoms and a diol containing 2 to .[.9.]. .Iadd.6 .Iaddend.carbon atoms. 
     
     
       5. The coating composition of claim 1 characterized in that one of the ester diols is formed from an aliphatic dicarboxylic acid containing 2 to 10 carbon atoms and a diol containing 2 to .[.9.]. .Iadd.6 .Iaddend.carbon atoms. 
     
     
       6. The coating composition of claim 1 characterized in that the molar ratio of the hydroxyl groups of the ester diol mixture to the reactive groups of the curing agent is between about 0.7 and about 1.5. 
     
     
       7. The process for the preparation of a coating composition having a high solids content characterized in that it comprises the preparation of the coating composition of claim 1. 
     
     
       8. The coating composition of claim 1 wherein said curing agent for the binder is a methylol melamine containing 4 to 6 methylol groups per molecule of melamine, at least 3 of said methylol groups being etherified with an alcohol selected from the group consisting of methanol, ethanol, and butanol. 
     
     
       9. The coating composition of claim 1 wherein said curing agent for the binder is an N-methylol group-and/or N-methylol ether group- containing amino resin formed by reacting an aldehyde with a compound containing amino groups or amido groups. .Iadd. 
     
     
       10.  A high solids pigmented coating composition prepared from a blend of an ester diol as binder and a curing agent for the binder, characterized in that (1) the ester diol is a mixture of 
     
     
       (a) 20-80 mole % of an ester diol having the general formula: ##STR7##.Iaddend. where R 1  represents the group formed by abstraction of the carboxyl groups from a cycloaliphatic and/or aromatic dicarboxylic acid having 8 to 20 carbon atoms and R 2  and R 3  represent groups formed by abstraction of the two hydroxyl groups from neopentyl glycol, and m is a number of 1-3, and 
     
     
       (b) 80-20 mole % of an ester diol having the general formula: ##STR8## where R 4  represents the group formed by abstraction of the two carboxyl groups from an aliphatic dicarboxylic acid having 2 to 12 carbon atoms, and R 5  and R 6  represent groups formed by abstraction of the two hydroxyl groups from neopentyl glycol, and n is a number of 1-3, (2) the curing agent for the binder is an aminoplast, and   (3) the amount of pigment in said coating composition is at least 30% by weight, based on the total solids content.  .Iadd.   
     
     
       11.  The coating composition of claim 10, characterized in that the molar ratio of the ester diols is between 3:1 and 1:3. .Iaddend. .Iadd.12. The coating composition of claim 10, characterized in that the molar ratio of the ester diols is between 2:1 and 1:2. .Iaddend. .Iadd.13. The coating composition of claim 10, characterized in that one of the ester diols is formed from a cycloaliphatic or aromatic dicarboxylic acid containing 8 to 10 carbon atoms and neopentyl glycol. .Iaddend. .Iadd.14. The coating composition of claim 10, characterized in that one of the ester diols is formed from an aliphatic dicarboxylic acid containing 2 to 10 carbon atoms and neopentyl glycol. .Iaddend. .Iadd.15. The coating composition of claim 10, characterized in that the molar ratio of the hydroxyl groups of the ester diol mixture to the reactive groups of the curing agent is between 0.7 and about 1.5. .Iaddend. .Iadd.16. The process for the preparation of a coating composition having a high solids content characterized in that it comprises the preparation of the coating composition of claim 10. .Iaddend. .Iadd.17. The coating composition of claim 10, wherein said curing agent for the binder is a methylol melamine containing 4 to 6 methylol groups per molecule of melamine, at least 3 of said methylol groups being etherified with an alcohol selected from the group consisting 
     
     
        of methanol, ethanol, and butanol. .Iaddend. .Iadd.18.  The coating composition of claim 10, wherein said curing agent for the binder is an N-methylol group- and/or N-methylol ether group-containing amino resin formed by reacting an aldehyde with a compound containing amino groups or amido groups.