Continuous electrolytical treatment of aluminum or its alloys

Abstract

A process for electrolytically treating aluminum or its alloys in the form of a strip, wire or foil material in a continuous manner which comprises continuously passing the material through an anodic oxidation treatment cell through which a direct current, alternating current or AC-superimposed direct current is caused to flow and an electrolytic coloring cell through which an alternating current or AC-superimposed direct current is caused to flow and carrying out electrolysis in both said cells to anodize and color the material in a continuous manner.

We claim: .[.1. A process for electrolytically treating aluminum or its alloy in the form of a strip, wire or foil material in a continuous manner which comprises continuously passing the material through an anodic oxidation treatment cell and an electrolytic coloring cell to carry out electrolysis in said cells to anodize and color the material in a continuous manner, characterized in that just prior to the anodizing stage, a circuit is formed by commonly connecting to the aluminum material a power source for anodizing and a power source for electrolytically coloring, said power source for anodizing being further connected to the anodizing cell and said power source for electrolytically coloring being further connected to the electrolytic coloring cell; said power source for anodizing being DC and the power source for electrolytically coloring being AC, or the power source for both of them being a single AC-superimposed direct current, whereby a current having an alternating wave form rich in positive component is supplied to the electrode of the electrolytic coloring cell..]. .[.2. The process according to claim 1 wherein the electrolytic coloring is carried out in a solution containing a tin salt..]. .[.3. The process according to claim 1 wherein the electrolytic coloring is effected in a solution containing a tin salt and at least one member selected from the group consisting of nickel salts, 
     
        cobalt salts, iron salts, magnesium salts, and zinc salts..]. .[.4.  The process according to claim 1 wherein the electrolytic coloring is carried out in a solution containing at least one member selected from the group consisting of copper salts, selenium salts, manganese salts, and zirconium salts..]. .[.5. The process according to claim 1 wherein a direct current voltage is applied between an electric power supply element outside the anodic oxidation treatment cell and an electrode plate within said cell and an alternating current voltage is applied between said element and an electrode plate within the electrolytic coloring cell..]. .[.6. The process according to claim 1 wherein two anodic oxidation treatment cells are used, a direct current voltage being applied between electrode plates contained respectively in said two cells, an alternating current voltage being applied between one of said plates and an electrode plate in the electrolytic coloring cell..]. .[.7. The process according to claim 1 wherein the anodic oxidation treatment cell is divided into two compartments by a diaphragm with a slit, a direct current voltage being applied between electrode plates contained in said compartments, an alternating current voltage being applied between one of said plates and an electrode plate in the coloring cell..]. .[.8. The process according to claim 1 wherein the anodic oxidation treatment cell is divided into two compartments by a diaphragm with a slit, an AC-superimposed direct current voltage being applied between electrode plates respectively in said compartments and an electrode plate in the coloring cell..]. .[.9. A process according to claim 1, wherein the aluminum material is charged with a current having an alternating wave form rich in cathodic component in the electrolytic coloring cell..]. .Iadd.10. A process for electrolytically treating aluminum or its alloy in the form of a strip, wire or foil material in a continuous manner which comprises continuously passing the material first through a negatively charging cell, then through an anodic oxidation treatment cell and finally through an electrolytic coloring cell, each cell containing therein an electrolytic solution and comprising an electrode immersed in the electrolytic solution; wherein a circuit is formed by commonly connecting to the electrode in the negatively charging cell a power source for anodizing and a power source for electrolytically coloring, said power source for anodizing being further connected to the electrode in the anodic oxidation treatment cell and said power source for electrolytically coloring being further connected to the electrode of the electrolytic coloring cell, said power source for anodizing being DC and the power source for electrolytically coloring being AC, or the power source for both of them being a single AC-superimposed DC, whereby a current having an alternative wave form rich in positive component is supplied to the electrode of the electrolytic coloring cell, and the aluminum material is negatively charged through the electrolytic solution in the negatively charging cell, anodized in the anodic oxidation treatment cell and colored in the electrolytic coloring cell..Iaddend. .Iadd.11. The process according to claim 10, wherein the electrolytic solution in the electrolytic coloring cell contains a tin salt..Iaddend. .Iadd.12. The process according to claim 10, wherein the electrolytic solution in the electrolytic coloring cell contains a tin salt and at least one member selected from the group consisting of nickel salts, cobalt salts, iron salts, magnesium salts, and zinc salts..Iaddend. .Iadd.13. The process according to claim 10, wherein the electrolytic solution in the electrolytic coloring cell contains at least one member selected from the group consisting of copper salts, selenium salts, manganese salts and zirconium salts..Iaddend. .Iadd.14. The process according to claim 10, wherein the aluminum material is charged with a current having an alternative wave form rich in cathodic component in the electrolytic coloring cell..Iaddend. .Iadd.15. A process for electrolytically treating aluminum or its alloy in the form of a strip, wire or foil material in a continuous manner which comprises continuously passing the material through an anodic oxidation treatment cell comprising a negatively charging compartment and an anodizing compartment separated from each other by a diaphragm with a slit for passing the aluminum material and then through an electrolytic coloring cell, each of said negatively charging compartment, anodizing compartment and electrolytic coloring cell containing an electrolytic solution and comprising an electrode immersed in the electrolytic solution; wherein a circuit is formed by commonly connecting to the electrode in the negatively charging compartment a power source for anodizing and a power source for electrolytically coloring, said power source for anodizing being further connected to the electrode in the anodizing compartment, said power source for electrolytically coloring being further connected to the electrode in the electrolytic coloring cell, said power source for anodizing being DC and the power source for electrolytically coloring being AC, or the power source for both of them being a single AC-superimposed DC, whereby a current having an alternative wave form rich in positive component is supplied to the electrode of the electrolytic coloring cell, and the aluminim material is negatively charged through the electrolytic solution in the negatively charging compartment, anodized in the anodizing compartment and colored in the electrolytic coloring cell..Iaddend. .Iadd.16. The process according to claim 15, wherein the electrolytic solution in the electrolytic coloring cell contains a tin salt..Iaddend. .Iadd.17. The process according to claim 15, wherein the electrolytic solution in the electrolytic coloring cell contains a tin salt and at least one member selected from the group consisting of nickel salts, cobalt salts, iron salts, magnesium salts, and zinc salts..Iaddend. .Iadd.18. The process according to claim 15, wherein the electrolytic solution in the electrolytic coloring cell contains at least one member selected from the group consisting of copper salts, selenium salts, manganese salts and zirconium salts..Iaddend. .Iadd.19. The process according to claim 15, wherein the aluminum material is charged with a current having an alternative wave form rich in cathodic component in the electrolytic coloring cell..Iaddend.