Chemical milling of high tungsten content superalloys

Abstract

Chemical milling of cast superalloys having high tungsten contents is advantageously accomplished with an etchant which consists by volume percent of 40-60 concentrated HNO 3 , 0.6-0.8 concentrated HF, .[.30.]..Iadd.40.Iaddend.-70 H 2 O, with which is included at least 0.008 moles/liter CuSO 4 and 0.0016-0.025 moles/liter FeCl 3 . Preferably the molar ratio of CuSO 4 to FeCl 3 is 2:1 and etching is accomplished in the range 50°-80° C.

We claim: 
     
       1. The method of chemical milling a superalloy having a base metal selected from the group consisting of nickel and cobalt, and a tungsten content of greater than 6 weight percent, which comprises the use of the etchant consisting essentially by volume percent of 40-60 concentrated HNO 3 , .[.0.3-0.8.]. .Iadd.0.6-0.8 .Iaddend.concentrated HF, and .[.30.]. .Iadd.40.Iaddend.-70 H 2  O, together with at least 0.008 moles/liter CuSO 4  and 0.0016-0.025 moles/liter FeCl 3 . 
     
     
       2. The method of claim 1 wherein CuSO 4  is less than .[.0.083.]. .Iadd.0.08 .Iaddend.moles/liter. 
     
     
       3. The method of claim 1 wherein the etchant has the composition consisting essentially by volume of about 50 percent HNO 3 , 0.3 percent HF, and 50 percent H 2  O, with 0.008 moles/liter CuSO 4  and 0.004 moles/liter FeCl 3 . 
     
     
       4. The method of claims 1 or 2 wherein the molar proportion of CuSO 4  .[.and.]. .Iadd.to .Iaddend.FeCl 3  is about 2:1. 
     
     
       5. The method of claim 1 wherein the superalloy composition consists essentially by weight percent of 10Co, 9Cr, 2Ti, 5Al, 12W, 1Cb, 0.15C, .[.0.01B.]. .Iadd.0.015B,.Iaddend.0.05Zr.