Cathodic electrodeposition coating compositions containing diels-alder adducts

Abstract

Described herein is an organic coating composition particularly useful in cathodic electrodeposition comprising a dispersion, solution or suspension of a coating composition characterized by (a) a reaction product of a conjugated fatty acid ester and an acrylic containing monomer, preferably containing oxirane rings; and (b) Formula A within the molecule, being the reaction product of reacting an oxirane ring and an amine; wherein Formula A is: --CH.sub.2 --C(Z)--CH.sub.2 --N═ wherein Z is hydrogen, hydroxyl, alkoxy of 1 to 6 carbon atoms; acyloxy of from 1 to 6 carbon atoms; (═O, as in a ketone), --OR'].sub.n H; --OR'].sub.n OH, and --OR'(CH.sub.2 OH)].sub.n OH, wherein R' is a saturated alkylene group of from 2 to 4 carbon atoms and n is a number from 1 to 6. Also described is a method of electrodepositing coating compositions containing said adducts onto a cathode.

What is claimed is: 
     
       1. An organic coating composition comprising a dispersion, solution or suspension of a coating composition characterized by: (a) the reaction product of a conjugated fatty acid ester and an acrylic containing monomer; and   (b) Formula A within the molecule, being the reaction product of reacting an amine with an oxirane ring; wherein Formula A is: ##STR9## wherein Z is independently selected from the group consisting of hydrogen, hydroxyl, alkoxy of from one to 6 carbon atoms; acyloxy of from one to 6 carbon atoms; (═O), --OR'] n  H, --OR'] n  OH, and --OR'(CH 2  OH)] n  OH; wherein R' is a saturated alkylene of from 2 to 4 carbon atoms and n is a number from 1 to 6.     
     
     
       2. Composition of claim 1 wherein the fatty acid ester is obtained by the reaction between a fatty acid and an alkanol of from 1 to 12 carbon atoms. 
     
     
       3. The composition of claim 1 wherein the composition is substantially free of oxirane rings. 
     
     
       4. The composition of claim 1 further comprising an effective amount of a nitrogenous cross-linking composition. 
     
     
       5. The composition of claim 1 wherein the coating composition is comprised of a resin portion characterized as follows:   ______________________________________                                    
Components           Parts by Weight                                      
______________________________________                                    
(a)   total monomer portion used                                          
                         about 30 to about 60                             
      to produce polymer                                                  
(b)   fatty acid ester portion                                            
                         about 30 to about 50                             
(c)   Formula A producing amine                                           
                         balance                                          
      portion                                                             
______________________________________                                    
     wherein the total resin components equals 100 parts (on a pigment, catalyst and filler free basis).   
     
     
       6. The composition of claim 5 wherein the acrylic monomer comprises about 10 to about 40% of the total resin portion of the coating composition. 
     
     
       7. The composition of claim 1 wherein Z is hydroxyl. .Iadd. 
     
     
       8.  An organic coating composition comprising a dispersion, solution or suspension of a coating composition characterized by: (a) the reaction product of a conjugated fatty acid ester and an acrylic containing monomer; and   (b) Formula A' within the molecule, being the reaction product of reacting an amine with an oxirane ring; wherein Formula A' is: ##STR10## wherein Z is independently selected from the group consisting of hydrogen, hydroxyl, alkoxy of from 1 to 6 carbon atoms; acyloxy of from 1 to 6 carbon atoms; (═O), --OR'] n  H, --OR'] n  OH and --OR'(CH 2  OH)] n  OH; wherein R' is a saturated alkylene group of from 2 to 4 carbon atoms and n is a number from 1 to 6; and wherein X is H or --C-- provided that when X is --C--, then C-X is part of an alicyclic ring structure.