Information carrying discs

Abstract

Information-carrying discs are comprised of a substrate having an information bearing layer derived from 15 to 100% by weight of at least one polyacryloyl-containing heterocyclic monomer.

I claim: 
     
       1. An information-carrying element comprising a substrate having adhered to at least one surface thereof a separate layer having a maximum thickness of from 1.0 to 100 μm and a circular or spiral pattern of grooves with or without modulations, depressions, protuberances, said separate layer comprising a polymer layer derived from 15 to 100% by weight of at least one polyacryloyl-containing heterocyclic wherein said heterocyclic is selected from the formulae:   A.sup.1 --Z--A.sup.2                                       ( 1)     wherein A 1  and A 2  independently are alkoxyalkyl groups having terminal ethylenic unsaturation and having the formula ##STR11## wherein R--O-- is a monovalent residue of an aliphatic terminally unsaturated primary alcohol, ROH, formed by the removal of the active hydrogen from the primary --OH group, R having the formula:     [E--CH.sub.2 --.sub.b --.sub.m R.sup.5 --CH.sub.2 --.sub.c     wherein E is ##STR12## .Iadd.b is zero or an integer of from 1 to 6, .Iaddend. c is an integer of from 1 to 6,   R 1  and R 4  are independently selected from hydrogen and methyl,   R 5  is an aliphatic group having from 1 to 15 carbon atoms, and no more than two catenary oxygen or carboxy groups, a valence of m+1.   m is an integer of from 1 to 5,   R 2  is selected from hydrogen and groups of the formula ##STR13## wherein R 6  is selected from alkyl and alkenyl groups   R 7  is an aliphatic or aromatic group of up to eight carbon atoms,   R 3  is an alkylene group of from 1 to 6 carbon atoms with up to one catenary oxygen atom, and   Z is a heterocyclic group of the formula ##STR14## wherein X is a divalent group which is required to complete a 5- or 6-membered heterocyclic ring, or ##STR15## wherein R 12  and R 13  independently represent hydrogen or methyl,   R 14  represents hydrogen, an alkyl group, or a phenyl group,   R 13  and R 14  together may represent trimethylene or tetramethylene group,   m represents a number of from 1 to 30,   n is 2 or 3, and   A represents a group of the formula ##STR16## wherein X 1  represents the divalent radical necessary to complete a 5- or 6-membered heterocyclic ring group.[., said process comprising exposing said composition to radiation while the composition is in the presence of an atmosphere of at least 2% by volume of oxygen to polymerize said components having formula (1) or (2).]..   
     
     
       2. The element of claim 1 wherein said polymer layer was derived from 30 to 100% by weight of at least one polyacryoyl containing heterocyclic. 
     
     
       3. The element of claim 1 wherein said heterocyclic is selected from formula (2), m is 1 to 4, and X 1  is selected from ##STR17## wherein R 15 , R 16 , R 17  and R 18  independently represent hydrogen, an alkyl group, and alkylene group, a cycloalkyl group, or a phenyl group, and R 19  represents hydrogen, an aliphatic group, or an aromatic group.   
     
     
       4. The element of claim 3 wherein R 15 , R 16 , R 17  and R 18  are selected from hydrogen, alkyl of 1 to 4 carbon atoms, alkylene or 1 to 4 carbon atoms, or phenyl, and X 1  is selected from ##STR18## 
     
     
       5. The element of claim 1 wherein said heterocyclic is selected from formula (1) and X is selected from: ##STR19## wherein R 8 , R 9 , R 10 , and R 11  are independently hydrogen, alkyl group of 1 to 4 carbon atoms, cycloalkyl group of 3 to 6 carbon atoms, and phenyl group of 6 to 12 carbon atoms, and A 3  is an alkoxyalkyl group as defined for A 1  and A 2 .   
     
     
       6. The element of claim 5 wherein ##STR20## and R 8  and R 9  are hydrogen or alkyl of 1 to 4 carbon atoms and R 2  is hydrogen. 
     
     
       7. The element of claim 6 wherein ##STR21## and R 5  is alkylene of 1 to 15 carbon atoms. 
     
     
       8. The element of claim 1 wherein said polymer layer is further derived from 70 to 10% by weight of acrylates copolymerizable with said plyacryloyl containing heterocyclic. 
     
     
       9. The element of claim 6 wherein said polymer layer is further derived from 70 to 10% by weight of acrylates copolymerizable with said polyacryloyl containing heterocyclic. 
     
     
       10. The elements of .[.claims.]. .Iadd.claim .Iaddend.3.[., 4, 5, 6, 7, 8, or 9.]. in which said information carrying element comprises a disc having a circular pattern of grooves with information-carrying deformities in the form of modulations, depressions or protuberances wherein the depth or height of the information-carrying deformities from the mean height of the surface is between 0.03 and 2 μm and said separate layer is between 1 and 25 μm in its maximum thickness. .Iadd. 11. The elements of claim 4 in which said information carrying element comprises a disc having a circular pattern of grooves with information-carrying deformities in the form of modulations, depressions or protuberances wherein the depth or height of the information-carrying deformities from the mean height of the surface is between 0.03 and 2 μm and said separate layer is between 1 and 25 μm in its maximum thickness. .Iaddend..Iadd. 12. The elements of claim 5 in which said information carrying element comprises a disc having a circular pattern of grooves with information-carrying deformities in the form of modulations, depressions or protuberances wherein the depth or height of the information-carrying deformities from the mean height of the surface is between 0.03 and 2 μm and said separate layer is between 1 and 25 μm in its maximum thickness. .Iaddend..Iadd. 13. The elements of claim 6 in which said information carrying element comprises a disc having a circular pattern of grooves with information-carrying deformities in the form of modulations, depressions or protuberances wherein the depth or height of the information-carrying deformities from the mean height of the surface is between 0.03 and 2 μm and said separate layer is between 1 and 25 μm in its maximum thickness. .Iaddend..Iadd. 14. The elements of claim 7 in which said information carrying element comprises a disc having a circular pattern of grooves with information-carrying deformities in the form of modulations, depressions or protuberances wherein the depth or height of the information-carrying deformities from the mean height of the surface is between 0.03 and 2 μm and said separate layer is between 1 and 25 μm in its maximum thickness. .Iaddend. .Iadd. 15. The elements of claim 8 in which said information carrying element comprises a disc having a circular pattern of grooves with information-carrying deformities in the form of modulations, depressions or protuberances wherein the depth or height of the surface is between 0.03 and 2 μm and said separate layer is between 1 and 25 μm in its maximum thickness. .Iaddend..Iadd. 16. The elements of claim 9 in which said information carrying element comprises a disc having a circular pattern of grooves with information-carrying deformities in the form of modulations, depressions or protuberances wherein the depth or height of the surface is between 0.03 and 2 μm and said separate layer is between 1 and 25 μm in its maximum thickness. .Iaddend.