Salt of a polyamide and functional fluid containing same

Abstract

Polyoxyalkylene polyamide lubricants having a terminal carboxylic acid group and a terminal amine group in the same molecule and a degree of polymerization of from 2 to 10 and salts thereof are provided. Stable aqueous based compositions are prepared from the polyamide or its salt, that are useful metal working and hydraulic fluids.

What is claimed is: 
     
       1. A .Iadd.salt of a .Iaddend.polyamide derivative of a polyoxalkylene diamine wherein said polyamide has (a) a single terminal carboxylic acid group and a single terminal amine group in the same molecule, and (b) a degree of polymerization of from 2 to 10 .[.or the.]. salt of the polyamide .[.which.]. is the salt of (c) the terminal carboxylic acid group, (d) the terminal amine group, or (e) both the terminal carboxylic acid and terminal amine groups, wherein the polyamide has the following formula ##STR4## where R is a divalent aliphatic, aromatic, arylaliphatic, alkylaromatic, cycloaliphatic, heteroaliphatic having oxygen or sulfur heterochain atoms, heterocyclic having one to two oxygen, sulfur or nitrogen hetero ring atoms and from 5 to 6 ring atoms or bicyclic radical or the halogenated derivatives of said divalent radical, R' is a divalent polyoxyaliylene homopolymer or copolymer radical and   n is 2 to 10, said .[.polyamide and its salts.]. .Iadd.salt .Iaddend.having an average molecular weight not greater than about 50,000.     
     
     
       2. A .[.polyamide.]. .Iadd.salt .Iaddend.according to claim 1 .[.the salt of the polyamide.]. which is the salt of the terminal carboxylic acid group. 
     
     
       3. A .[.polyamide or.]. salt .[.thereof.]. according to claim 1 wherein R is a divalent aliphatic hydrocarbon radical having from 2 to 12 carbon atoms. 
     
     
       4. A .[.polyamide or.]. salt .[.thereof.]. according to claim 1 wherein R is a phenylene or naphthylene radical. 
     
     
       5. A .[.polyamide or.]. salt .[.thereof.]. according to claim 1 wherein R is a divalent C 4  to C 6  cycloaliphatic radical. 
     
     
       6. A .[.polyamide or.]. salt .[.thereof.]. according to claim 1 wherein R is a divalent heteroaliphatic radical having one to two oxygen or sulfur heterochain atoms and from 2 to 6 carbon atoms. 
     
     
       7. A .[.polyamide or.]. salt .[.thereof.]. according to claim 1 wherein R is a divalent heterocyclic radical having one to two oxygen, sulfur or nitrogen hetero ring atoms and from 5 to 6 ring atoms. 
     
     
       8. A .[.polyamide or.]. salt .[.thereof.]. according to claim 1 wherein R is a divalent radical residue obtained by the removal of both carboxylic acid groups from a dimerized ethylenically unsaturated C 8  to C 26  fatty acid. 
     
     
       9. A .[.polyamide or.]. salt .[.thereof.]. according to claim 3,4, 5,6,7 or 8 wherein R' is a divalent polyoxyalkylene homopolymer radical having an average molecular weight in the range from 72 to 4000. 
     
     
       10. A .[.polyamide or.]. salt .[.thereof.]. according to claim 3,4, 5,6,7 or 8 wherein R' is a divalent polyoxyalkylene copolymer radical having an average molecular weight in the range from 86 to 4000. 
     
     
       11. The alkali metal, ammonium or organic amine salt of the carboxylic acid group of the polyamide according to claim 8. 
     
     
       12. The organic amine salt according to claim 11 wherein the organic amine is an alkanol amine. 
     
     
       13. The salt according to claim 12 wherein the alkanolamine is a mono, di or ti (C 2  to C 4  alkanol) amine. 
     
     
       14. The salt formed by the terminal amine group of the polyamide according to claim 1. 
     
     
       15. An aqueous functional fluid composition comprising (a) water, and (b) a lubricant compound selected from the group consisting of .[.a water soluble or dispersible polyamide derivative of a polyoxyalkylene diamine wherein the polyamide has a single terminal carboxylic acid group and a single terminal amine group in the same molecule and a degree of polymerization from 2 to 10,.]. a water soluble or dispersible salt of a water soluble or dispersible polyamide derivative of a polyoxyalkylene diamine wherein the polyamide has a single terminal carboxylic acid group and a single terminal amine group in the same molecule and a degree of polymerization of from 2 to 10 or a water soluble or dispersible salt of a water insoluble polyamide derivative of a polyoxyalkylene diamine wherein the polyamide has a single terminal carboxylic acid group and a single terminal amine group in the same molecule and a degree of polymerization of from 2 to 10, wherein the polyamide derivative has the formula ##STR5## where R is a divalent aliphatic, aromatic, arylaliphatic, alkylaromatic, cycloaliphatic, heteroaliphatic having oxygen or sulfur heterochain atoms, heterocyclic having one to two oxygen, sulfur or nitrogen hetero ring atoms and 5 to 6 ring atoms or bicyclic radical or the halogenated derivative of said radical, R' is a divalent polyoxyalkylene homopolymer or copolymer radical and   n is 2 to 10, said .[.polyamide and.]. water soluble or dispersible .[.salts thereof.]. .Iadd.salt .Iaddend.having an average molecular weight of not greater than 50,000, the water soluble or dispersible salt being formed by the terminal carboxylic acid group, terminal amine group or both the terminal carboxylic acid and terminal amine groups of the polyamide.     
     
     
       16. An aqueous functional fluid composition according to claim 15 wherein the water soluble or dispersible salt of the water soluble or dispersible polyamide is a salt of the terminal carboxylic acid group of the polyamide and the water soluble or dispersible salt of the water insoluble polyamide is the salt of the terminal carboxylic acid group of the polyamide. 
     
     
       17. An aqueous functional fluid composition according to claim 15 wherein R is a C 2  to C 12  alkylene, C 2  to C 10  alkenylene, phenylene, C 4  to C 6  cycloaliphatic, mono to di(C 1  to C 4  alkyl) substituted phenylene, phenyl substituted C 2  to C 10  alkylene, phenylene di(C 1  to C 3  alkylene), heteroaliphatic having one to two oxygen or sulfur heterochain atoms and 2 to 10 carbon atoms, heterocyclic having one to two oxygen, sulfur or nitrogen hetero ring atoms and from 5 to 6 atoms in the ring divalent radical or a divalent radical residue obtained by removal of both carboxylic acid groups from a dimerized ethylenically unsaturated C 8  to C 26  fatty acid. .[.18. An aqueous functional fluid composition according to claim 17 wherein the lubricant compound is the water soluble 
     
     
        or dispersible polyamide..]. 19. An aqueous functional fluid composition according to claim 17 wherein the lubricant compound is the water soluble 
     
     
        or dispersible salt of the water soluble or dispersible polyamide. 20. An aqueous functional fluid composition according to claim 17 wherein the lubricant compound is the water soluble or dispersible salt of the water 
     
     
        insoluble polyamide. 21. An aqueous functional fluid composition according to claim 19 or 20 wherein the .[.lubricant is the salt of the polyamide and said.]. salt is a salt of the terminal carboxylic acid group of the 
     
     
        polyamide. 22. An aqueous functional fluid composition according to claim 21 wherein the salt is an alkali metal, ammonium or organic amine salt. 
     
     
            An aqueous functional fluid composition according to claim 22 wherein the organic amine is a mono, di or tri(alkanol) amine having 2 to 4 carbon 
     
     
        atoms in the alkanol group. 24. An aqueous functional fluid composition according to claim 23 wherein the organic amine is the trialkanolamine. 
     
     
            An aqueous functional fluid composition in accordance with claim .[.18,.]. 19 or 20 wherein R' is a divalent polyoxyalkylene homopolymer radical having an average molecular weight in the range of from 72 to 
     
     
        4000. 26. An aqueous functional fluid composition according to claim .[.18,.]. 19 or 20 wherein R' is a divalent polyoxyalkylene copolymer 
     
     
        radical having an average molecular weight of from 86 to 4000. 27. An aqueous functional fluid composition according to claim 23 wherein R is a C 2  to C 10  alkylene or C 2  to C 10  alkenylene radical. 
     
     
            An aqueous functional fluid composition according to claim 23 wherein 
     
     
        R is a phenylene radical. 29. An aqueous functional fluid composition according to claim 23 wherein R is a divalent radical residue obtained by removal of both carboxylic acid groups from a dimerized ethylenically 
     
     
        unsaturated C 8  to C 26  fatty acid. 30. An aqueous functional fluid composition according to claim 19 or 20 wherein the salt is a salt 
     
     
        of the terminal amine group of the polyamide. 31. An aqueous functional fluid composition according to claim 17 wherein the lubricant compound is present in an amount in the range of from 0.01% to 99% by weight based on 
     
     
        the total weight of the composition. 32. An aqueous functional fluid composition according to claim 31 wherein the amount of lubricant compound 
     
     
        is in the range of from 0.01% to 20% by weight. 33. A metal working process comprising the step of working metal in the presence of the aqueous functional fluid composition according to claim 15.