Hypochlorous acid process using sweep reactor

Abstract

A process for preparing hypochlorous acid in a sweep reactor is described in which gaseous chlorine is passed rapidly across the surface of an agitated aqueous solution of .[.alkali metal.]. .Iadd.sodium .Iaddend.hydroxide at a reduced temperature. The resulting gaseous product mixture of hypochlorous acid, chlorine monoxide, and unreacted chlorine is conveyed from the reactor to a suitable scrubber to produce an aqueous hypochlorous acid solution. The aqueous reaction product of the sweep reactor is a suspension of .[.alkali metal.]. .Iadd.sodium .Iaddend.chloride in .[.alkali metal.]. .Iadd.sodium .Iaddend.hypochlorite, which is withdrawn and filtered to separate the solid. The clarified aqueous solution of .[.alkali metal.]. .Iadd.sodium .Iaddend.hypochlorite is reacted with the aqueous hypochlorous acid solution from the scrubber, chlorine and lime to form an aqueous slurry of calcium hypochlorite. This slurry may be granulated by the spray graining technique, for example, to produce strong rounded granules of calcium hypochlorite.

What is desired to be secured by Letters Patent is: 
     
       1. A process for preparing hypochlorous acid in a reactor which comprises rapidly passing gaseous chlorine in contact with the surface of an agitated solution of .[.an alkali metal.]. .Iadd.sodium .Iaddend.hydroxide at a temperature below about 50° C. a. whereby a gaseous phase containing unreacted chlorine, hypochlorous acid, and chlorine monoxide is formed,   b. whereby a reaction product of suspended particles of .[.alkali metal.]. .Iadd.sodium .Iaddend.chloride in an aqueous solution of .[.alkali metal.]. .Iadd.sodium .Iaddend.hypochlorite is formed, and   c. separating said gaseous phase as it forms.   
     
     
       2. The process of claim 1 wherein said chlorine is passed in contact with said surface at a rate sufficient to provide a residence time in said reactor ranging from about 0.01 to about 5 minutes. 
     
     
       3. The process of claim 1 wherein said chlorine in passed in contact with said surface at a rate sufficient to provide a residence time in said reactor ranging from about 0.1 to about 1 minute. 
     
     
       4. The process of claim 3 wherein the .[.alkali metal.]. .Iadd.sodium .Iaddend.hydroxide concentration is in the range from about 40 to about 70 percent by weight. 
     
     
       5. The process of claim 4 wherein the conversion of said chlorine contacted with the surface of said .[.alkali metal.]. .Iadd.sodium .Iaddend.hydroxide solution ranges from about 1 to about 75 percent per pass. 
     
     
       6. The process of claim 5 wherein the conversion of said chlorine contacted with the surface of said .[.alkali metal.]. .Iadd.sodium .Iaddend.hydroxide solution ranges from about 1 to about 35 percent per pass. .[.7. The process of claim 6 wherein said alkali metal hydroxide is selected from the group consisting of sodium hydroxide, potassium 
     
     
        hydroxide, lithium hydroxide and mixtures thereof..]. .[.8.  The process 
     
     
        of claim 7 wherein said alkali metal hydroxide is sodium hydroxide..]. 9. The process of claim 5 wherein said temperature is in the range from 
     
     
        about 5° to about 20° C. 10. The process of claim 9 wherein said vaporized hypochlorous acid and chlorine monoxide containing unreacted chlorine, after separating from said surface, is contacted with an aqueous medium to produce an aqueous solution of hypochlorous acid. 
     
     
            The process of claim 10 wherein said unreacted chlorine is separated from said aqueous hypochlorous acid and recycled for reaction with additional .[.alkali metal.]. .Iadd.sodium .Iaddend.hydroxide solution. 
     
     
            The process of claim 9 wherein said .[.alkali metal.]. .Iadd.sodium .Iaddend.hydroxide solution is reacted with sufficient chlorine to effect conversion of at least about 90 percent by weight of said .[.alkali metal.]. .Iadd.sodium .Iaddend.hydroxide to form an aqueous solution of the corresponding .[.alkali metal.]. .Iadd.sodium .Iaddend.hypochlorite containing suspended therein solid particles of the corresponding .[.alkali metal .Iadd.sodium .Iaddend.chloride and separating said .[.alkali metal .Iadd.sodium .Iaddend.chloride from said aqueous solution 
     
     
        of .[.alkali metal.]. .Iadd.sodium .Iaddend.hypochlorite. 13. The process of claim 12 wherein calcium hypochlorite is prepared by reacting said aqueous .[.alkali metal.]. .Iadd.sodium .Iaddend.hypochlorite solution with said hypochlorous acid solution, lime and chlorine to produce an aqueous slurry of calcium hypochlorite, and dewatering said aqueous slurry 
     
     
        to produce granular calcium hypochlorite particles. 14. The process of claim 13 wherein said dewatering is effected by spray drying said aqueous 
     
     
        slurry of calcium hypochlorite. 15. The process of claim 13 wherein said dewatering is effected by spray graining said aqueous slurry of calcium 
     
     
        hypochlorite. 16. The process of claim 15 wherein said aqueous slurry of calcium hypochlorite is adjusted to a water concentration within the range of from about 45 to about 90 percent by weight of water prior to spray 
     
     
        graining. 17. The process of claim 16 wherein the concentration of said aqueous slurry of calcium hypochlorite is adjusted within the range of from about 50 to about 60 percent by weight of water prior to said spray graining.