Cold rolled, ductile, high strength steel strip and sheet and method therefor

Abstract

Cold reduced, annealed steel strip and sheet stock having 0.2% yield strength of 45 to 65 ksi with an elongation of at least 25%, or having a yield strength of at least 90 ksi with an elongation of at least 10%. A low carbon steel (0.02-0.10% C) typical of rimmed or drawing steel analysis is preferably vacuum degassed, and 0.02% to 0.18% columbium is added. The casting is hot rolled, coiled not higher than 1300° F., cold reduced 40% to 70%, and annealed at low temperature for a time sufficient to restore desired ductility without substantially decreasing yield strength.

We claim: 
     
       1. Cold reduced and annealed low carbon steel strip and steel stock .Iadd.in substantially unrecrystallized form after annealing .Iaddend.having a 0.2% yield strength of .Badd..[.45 to 65 ksi or of.]..Baddend. at least 90 ksi, with an elongation in 2 inches of greater than 10% .[.for at least 90 ksi yield strength and greater than 25% for 45 to 65 ksi yield strength.]., consisting essentially of, by weight percent, from 0.02% to about 0.10% carbon, about 0.1% to about 0.9% manganese, 0.02% to about 0.18% columbium, residual phosphorus, sulfur, silicon, oxygen and nitrogen, about 0.01% to about 0.08% aluminum, and balance essentially iron except for incidental impurities, with the columbium being substantially completely combined. 
     
     
       2. Strip and sheet stock as claimed in claim 1, .[.in substantially unrecrystallized form after annealing.]. having a 0.2% yield strength of about 90 to about 120 ksi and an elongation in 2 inches of greater than 10%. 
     
     
       3. Strip and sheet stock as claimed in claim 2, consisting essentially of from about 0.03% to about 0.05% carbon, about 0.3% to about 0.6% manganese, about 0.04% to about 0.12% columbium, about 0.006% to about 0.01% phosphorus, about 0.01% to about 0.017% sulfur, about 0.004% maximum nitrogen, about 0.03% to about 0.05% aluminum, about 0.01% maximum oxygen, about 0.1% maximum silicon, and balance essentially iron. .[.4. Strip and sheet stock as claimed in claim 1, in substantially fully recrystallized form after annealing, having a 0.2% yield strength of 45 to 65 ksi and an 
     
     
        elongation in 2 inches of greater than 25%..]. 5. Strip and sheet stock as claimed in claim .[.4.]. .Iadd.11.Iaddend., consisting essentially of from about 0.03% to about 0.05% carbon, about 0.3% to about 0.6% manganese, about 0.04% to about 0.12% columbium, about 0.006% to about 0.01% phosphorus, about 0.01% to about 0.017% sulfur, about 0.004% maximum nitrogen, about 0.03% to about 0.05% aluminum, about 0.01% maximum oxygen, 
     
     
        about 0.1% maximum silicon, and balance essentially iron. 6. Strip and sheet stock as claimed in claim .[.1.]. .Iadd.3.Iaddend., wherein zirconium is partially substituted for columbium on a stoichiometrically 
     
     
        equivalent basis. 7. Strip and sheet stock as claimed in claim 1, wherein titanium is substituted for aluminum on a stoichiometrically equivalent 
     
     
        basis. 8. A coated product comprising an outer layer chosen from the group consisting of aluminum, zinc, alloys of aluminum, alloys of zinc, and terne, and an inner substrate of cold reduced and annealed steel strip and sheet stock .Iadd.in substantially unrecrystallized form having a 0.2% offset yield strength of at least 90 ksi and an elongation in 2 inches of greater than 10%, said sheet stock .Iaddend.consisting essentially of, by weight percent, from 0.02% to about 0.10% carbon, about 0.1% to about 0.9% manganese, 0.02% to about 0.18% columbium, residual phosphorus, sulfur, silicon, oxygen and nitrogen, about 0.01% to about 0.08% aluminum, and balance essentially iron except for incidental impurities, with the columbium being substantially completely combined, there being 
     
     
        substantially no interfacial alloy layer. 9. The product claimed in claim 8, wherein said outer layer has been applied by fluxless hot dip metallic 
     
     
        coating. 10. The product claimed in claim 8, wherein said substrate consists essentially of, by weight percent, from about 0.03% to about 0.05% carbon, about 0.3% to about 0.6% manganese, about 0.04% to about 0.12% columbium, about 0.006% to about 0.010% phosphorus, about 0.01% to about 0.017% sulfur, about 0.04% maximum nitrogen, about 0.03% to about 0.05% aluminum, about 0.01% maximum oxygen, about 0.1% maximum silicon, and balance essentially iron. .Iadd. 11. Cold reduced and annealed low carbon steel strip and sheet stock in substantially fully recrystallized form after annealing, having a 0.27%, offset yield strength of 45 to 65 ksi and an elongation in 2 inches of greater than 25%, said strip and sheet stock being produced from hot rolled steel coiled at 1000° to 1300° F., and consisting essentially of, in weight percent, from 0.02% to about 0.10% carbon, about 0.1% to about 0.9% manganese, 0.02% to about 0.18% columbium, residual phosphorus, sulfur, silicon, oxygen and nitrogen, about 0.01% to about 0.08% aluminum, and balance essentially iron except for incidental impurities, with the columbium being substantially completely combined. .Iaddend..Iadd. 12. Strip and sheet stock as claimed in claim 5, wherein zirconium is partially substituted for columbium on a stoichiometrically equivalent basis. .Iaddend..Iadd. 13. Strip and sheet stock as claimed in claim 11, wherein titanium is substituted for aluminum on a stoichiometrically equivalent basis. .Iaddend..Iadd. 14. A coated product comprising an outer layer chosen from the group consisting of aluminum, zinc, alloys of aluminum, alloys of zinc, and terne, and an inner substrate of cold reduced and annealed strip and sheet stock in substantially fully recrystallized form after annealing having a 0.2% offset yield strength of 45 to 65 ksi and an elongation in 2 inches of greater than 25%, said sheet stock being produced from hot rolled steel coiled at 1000° to 1300° F. and consisting essentially of, by weight percent, from 0.02% to about 0.10% carbon, about 0.1% to about 0.9% manganese, 0.02% to about 0.18% columbium, residual phosphorus, sulfur, silicon, oxygen and nitrogen, about 0.01% to about 0.08% aluminum, and balance essentially iron except for incidental impurities, with the comumbium being substantially completely combined, there being substantially no interfacial alloy layer. .Iaddend. .Iadd. 15. The product claimed in claim 14, wherein said substrate consists essentially of, by weight percent, from about 0.03% to about 0.05% carbon, about 0.3% to about 0.6% manganese, about 0.04% to about 0.12% columbium, about 0.006% to about 0.010% phosphorus, about 0.01% to about 0.017% sulfur, about 0.004% maximum nitrogen, about 0.03% to about 0.05% aluminum, about 0.01% maximum oxygen, about 0.15 maximum silicon, and balance essentially iron. .Iaddend.