Quaternary spinodal copper alloys

Abstract

Copper alloys are disclosed which contain nickel and tin and Fe, Zn, Mn, Zr, Nb, Cr, Al, or Mg in amounts within specified limits. When cold worked and aged according to a critical schedule these alloys develop a predominantly spinodal structure which renders them strong as well as ductile. The disclosed alloys are useful, for example, in the manufacture of components of electrical apparatus such as springs, connectors and relay elements.

What is claimed is: 
     
       1. Cold worked and aged spinodal copper alloys consisting essentially of nickel in an amount of from 2-20%, tin in an amount of from 2-8%, an additional element selected from the group consisting of Fe in an amount of from 2 to 15%.[., Zn in an amount of from 2 to 10%,.]. and Mn in an amount of from 2 to 15%, and remainder copper. 
     
     
       2. Copper alloys of claim 1 and containing at least 5% of an element selected from said group. 
     
     
       3. Copper alloys of claim 1 containing at least two elements selected from said group in a combined amount of at most 15%. 
     
     
       4. Cold-worked and aged spinodal copper alloys consisting essentially of nickel in an amount of from 2-20%, tin in an amount of from 2-8%, at least one additional element selected from the group consisting of Zr in an amount of from 0.05-0.2%, Nb in an amount of from 0.1-0.3%, Cr in an amount of from 0.5-1%, Al in an amount of from 0.5-1.5%, and Mg in an amount of from 0.5-1%, and remainder copper. 
     
     
       5. Copper alloys of claim 4 containing at least two elements selected from said group in a combined amount of at most 1.5%.