Quaternary ammonium compounds in pretreatment of hair before shampooing with an anionic shampoo

Abstract

This invention is concerned with the pretreatment of hair on the human head, preceding shampooing the hair with anionic type hair shampoos, and with compositions for effecting such pretreatment, to obtain highly improved manageability of the hair after shampooing and with improved fullness, combability and other desired properties of the hair. The pretreatment compositions utilize readily water-soluble quaternary ammonium compounds, particularly in combination with certain agents, notably polyethylenimines and N-ethanolacetamide, and desirably together with various supplemental ingredients.

What is claimed is: 
     
       1. A method of treating hair to improve the manageability thereof, which comprises initially contacting the hair with a dilute aqueous composition containing a water-soluble quaternary ammonium compound containing at least one long chain alkyl radical attached to the central nitrogen atom thereof, and then shampooing the hair with an anionic shampoo. 
     
     
       2. The method of claim 1, in which the quaternary ammonium compound has the formula ##STR2## wherein R 1  is C 8  -C 18  alkyl; each of R 2 , R 3  and R 4  is C 1  -C 3  alkyl, the total number of carbon atoms in R 2 , R 3  and R 4  not exceeding 6; and A is an innocuous anion. 
     
     
       3. The method of claim 1, in which the dilute aqueous composition containing the quaternary ammonium compound also contains at least one member of the group of N-ethanolacetamide and a fatty acid ethanolamide in which the fatty acid comprises predominately lauric acid. 
     
     
       4. The method of claim 1, in which the dilute aqueous composition containing the quaternary ammonium compound also contains polyethylenimine having a molecular weight between about 10,000 and about 70,000. 
     
     
       5. The method of claim 3, in which the dilute aqueous composition also contains polyethyleneimine having a molecular weight between about 10,000 and about 70,000. 
     
     
       6. A method of treating hair to improve the manageability thereof, which comprises initially contacting the hair with a dilute aqueous solution, clear to the naked eye, containing a water-soluble quaternary ammonium compound containing at least one long chain alkyl radical attached to the central nitrogen atom thereof, N-ethanolacetamide, polyethylenimine having a molecular weight between about 10,000 and about 70,000, and at least one acid selected from the group consisting of formic acid and acetic acid having a pH in the range of about 3 to below 7, and subsequently shampooing the hair with an anionic shampoo. 
     
     
       7. The method of claim 6, in which the dilute aqueous solution contains the stated ingredients in approximately the following proportions by weight of said solution:   ______________________________________                                    
Water                     70 to 90%                                       
Quatenary ammonium compound                                               
                         0.5 to 4%                                        
N-Ethanolacetamide         3 to 18%                                       
Polyethylenimine         0.5 to 5%.                                       
______________________________________                                    
 .[.8. A composition for pretreatment of hair prior to shampooing said
 pretreated hair with an anionic shampoo, said composition comprising a
 major proportion of water, and minor proportions of a readily
 water-soluble quaternary ammonium compound containing at least one long
 chain alkyl radical attached to the central nitrogen atom thereof and
 polyethylenimine having a molecular weight in the range of about 10,000 to
 about 70,000..]. .[.9. The composition according to claim 8, which also
 includes a minor proportion of at least one member of the group of
 N-ethanolacetamide and a fatty acid ethanolamide in which the fatty acid
 comprises predominately lauric acid..]. .[.10. The composition of claim 8,
 which also includes at least one water-soluble acid and has a pH in the
 range of about 3 to below 7..]. .[.11. A composition according to claim 8,
 in which the quaternary ammonium compound has the formula
 ##STR3##
 wherein R.sup.1 is C.sub.8 -C.sub.18 alkyl; each of R.sup.2, R.sup.3 and
 R.sup.4 is C.sub.1 -C.sub.3 alkyl, the total number of carbon atoms in
 R.sup.2, R.sup.3 and R.sup.4 not exceeding 6; and A is an innocuous
     
     
     
        anion..]. .[.12.  The composition according to claim 11, wherein R 1  is predominately dodecyl; each of R 2 , R 3  and R 4  is methyl; and A is chlorine or bromine..]. .[.13. The composition of claim 10, in which the acid is formic acid or acetic acid..]. .[.14. A composition for pretreatment of hair prior to shampooing said pretreated hair with an anionic shampoo, said composition containing from about 70 to about 90% of water, from about 0.5 to about 4% of a readily water-soluble quaternary ammonium compound containing at least one long chain alkyl radical attached to the central nitrogen atom thereof, from about 3 to 18% of N-ethanolacetamide, and from about 0.2 to 5% of polyethylenimine having a molecular weight in the range of about 10,000 to about 70,000, said percentages being by weight of the composition..]. .[.15. A composition for pretreatment of hair prior to shampooing said pretreated hair with an anionic shampoo, said composition comprising a clear aqueous solution containing from about 70 to about 90% of water, from about 0.5 to about 4% of a readily water-soluble quaternary ammonium compound having the formula ##STR4## where R 1  is alkyl containing predominately from 10 to 14 carbon atoms; R 2 , R 3  and R 4  are each methyl; and A is chlorine or bromine; from about 3 to 18% of N-ethanolacetamide, and from about 0.2 to 2% of polyethylenimine having a molecular weight between about 10,000 and about 70,000, said percentages being by weight of the composition..]. 
     
     
        .[.  .  A composition for pretreatment of hair prior to shampooing said pretreated hair with an anionic shampoo, said composition comprising a clear aqueous solution containing from about 70 to about 85% of water, from about 1.5 to about 2% of a readily water-soluble quaternary ammonium compound having the formula ##STR5## where R 1  is alkyl containing predominately from 10 to 14 carbon atoms; R 2 , R 3  and R 4  are each methyl; and A is chlorine or bromine; from about 12 to 15% of N-ethanolacetamide, and from bout 1 to 2% of polyethylenimine having a molecular weight between about 40,000 to about 60,000, said percentages being by weight of the composition..]. 
     
     
        .[.  .  The composition according to claim 16, which also includes at least one water-soluble acid and has a pH in the range of about 3 to below 7..]. .[.18. The composition of claim 17, in which the acid is formic acid 
     
     
        or acetic acid..]. .Iadd.19.  The method of claim 1 in which the shampooing of the hair with the anionic shampoo is effected while the hair is in a wet condition subsequently to the step of initially contacting the hair with said dilute aqueous composition containing said quaternary ammonium compound. .Iaddend. .Iadd.20. The method of claim 5, in which the shampooing of the hair with the anionic shampoo is effected while the hair is in a wet condition subsequently to the step of initially contacting the hair with said dilute aqueous composition containing said quaternary ammonium compound. .Iaddend. .Iadd.21. The method of claim 6, in which the shampooing of the hair with the anionic shampoo is effected while the hair is in a wet condition subseqently to the step of initially contacting the hair with said dilute aqueous solution containing said quaternary ammonium compound and said other stated ingredients. .Iaddend. .Iadd.22. A composition for pretreatment of hair prior to shampooing said pretreated hair with an anionic shampoo, said composition comprising a major proportion of water, and minor proportions of a readily water-soluble quaternary ammonium compound containing at least one long chain alkyl radical attached to the central nitrogen atom thereof and polyethylenimine having a molecular weight in the range of about 10,000 to about 70,000, and at least one water-soluble acid, said composition having a pH in the range of about 3 to below 7. .Iaddend. .Iadd.23. The composition of claim 
     
     
        22, in which the acid is formic acid or acetic acid. .Iaddend. .Iadd.24. A composition for pretreatment of hair prior to shampooing said pretreated hair with an anionic shampoo, said composition comprising a clear aqueous solution containing from about 70 to about 85% of water, from about 1.5 to about 2% of a readily water-soluble quaternary ammonium compound having the formula ##STR6## where R 1  is alkyl containing predominately from 10 to 14 carbon atoms; R 2 , R 3  and R 4  are each methyl; and A is chlorine or bromine; from about 12 to 15% of N-ethanolacetamide, and from about 1 to 2% of polyethylenimine having a molecular weight between about 40,000 to about 60,000, said percentages being by weight of the composition, and at least one water-soluble acid, said composition having a pH in the range of 
     
     
        about 3 to about 7. .Iaddend. .Iadd.25.  A composition for pretreatment of hair prior to shampooing said pretreated hair with an anionic shampoo, said composition being free from heavy metal salts of 2-pyridinethiol-1-oxide, and consisting essentially of a major proportion of water, and minor proportions of a readily water-soluble quaternary ammonium compound containing at least one long chain alkyl radical attached to the central nitrogen atom thereof and polyethylenimine having a molecular weight in the range of about 10,000 to about 70,000. .Iaddend. .Iadd.26. The composition according to claim 25, which also includes a minor proportion of at least one member of the group of N-ethanolacetamide and a fatty acid ethanolamide in which the fatty acid comprises 
     
     
        predominately lauric acid. .Iaddend. .Iadd.27.  The composition of claim 25, which also includes at least one water-soluble acid and has a pH in the range of about 3 to below 7. .Iaddend. .Iadd.28. The composition of claim 27, in which the acid is formic acid or acetic acid. .Iaddend. .Iadd.29. A composition for pretreatment of hair prior to shampooing said pretreated hair with an anionic shampoo, said composition being free from heavy metal salts of 2-pyridinethiol-1-oxide, and consisting essentially of from about 70 to about 90% of water, from about 0.5 to about 4% of a readily water-soluble quaternary ammonium compound containing at least one long chain alkyl radical attached to the central nitrogen atom thereof, from about 3 to 18% of N-ethanolacetamide, and from about 0.2 to 5% of polyethylenimine having a molecular weight in the range of about 10,000 to about 70,000, said percentages being by weight of the composition. .Iaddend. .Iadd.30. A composition for pretreatment of hair prior to shampooing said pretreated hair with an anionic shampoo, said composition being free from heavy metal salts of 2-pyridinethiol-1-oxide, and consisting essentially of a clear aqueous solution containing from about 70 to about 90% of water, from about 0.5 to about 4% of a readily water-soluble quaternary ammonium compound having the formula ##STR7## where R 1  is alkyl containing predominately from 10 to 14 carbon atoms; R 2 , R 3  and R 4  are each methyl; and A is chlorine or bromine; from about 3 to 18% of N-ethanolacetamide, and from about 0.2 to 2% of polyethylenimine having a molecular weight between about 10,000 and about 70,000, said percentages being by weight of the composition. 
     
     
        .Iaddend. .Iadd.31.  A composition for pretreatment of hair prior to shampooing said pretreated hair with an anionic shampoo, said composition being free from heavy metal salts of 2-pyridinethiol-1-oxide, and consisting essentially of a clear aqueous solution containing from about 70 to about 85% of water, from about 1.5 to about 2% of a readily water-soluble quaternary ammonium compound having the formula ##STR8## where R 1  is alkyl containing predominately from 10 to 14 carbon atoms; R 2 , R 3  and R 4  are each methyl; and A is chlorine or bromine; from about 12 to 15% of N-ethanolacetamide, and from about 1 to 2% of polyethylenimine having a molecular weight between about 40,000 to about 60,000, said percentages being by weight of the composition. 
     
     
        .Iaddend. .Iadd.32.  The composition according to claim 31, which also includes at least one water-soluble acid and has a pH in the range of about 3 to below 7. .Iaddend. .Iadd.33. The composition of claim 32, in which the acid is formic acid or acetic acid. .Iaddend.