Epichlorohydrin purification process

Abstract

2,3-Butanedione impurity is removed from epichlorohydrin by contacting the impurity containing epichlorohydrin with .[.a macroreticular poly(t-butyl acrylate) resin .]. .Iadd.an acrylic ester resin .Iaddend.having a pore volume of about .[.0.5 .]. .Iadd.0.55 .Iaddend.ml/ml, an average pore diameter of about 90 angstroms and a surface area of about 450 m 2 /gm.

What is claimed is:  .[.1. The process of removing 2,3-butanedione impurity from epichlorohydrin which comprises contacting said epichlorohydrin with a macroreticular poly(t-butyl acrylate) adsorbent resin having a pore volume between about 0.48 and about 0.57, an average pore diameter between about 80 and about 100 angstroms and a surface area between about 400 to about 500 square meters per gram..]. .[.2. The process of claim 1 wherein the resin has a pore volume between about 0.50 and about 0.55, an average pore diameter between about 85 and about 95 angstroms and a surface area 
     
        between about 425 to about 475 square meters per gram..]. 3. The process of claim .[.1.]. .Iadd.4 .Iaddend.where the resin is contained in a fixed-bed and said epichlorohydrin is passed through said bed at a liquid hourly space velocity ranging between about 0.1 to about 100 hours -1 . .Iadd. 4. The process of removing 2,3-butanedione impurity from epichlorohydrin which comprises contacting said epichlorohydrin with an acryclic ester resin having a porosity of 0.55, a surface area of 450 m 2  /gm and an average pore diameter of 90 angstroms.