Water soluble insulating varnish

Abstract

Water dispersible oil-modified polyesters and oil-free polyesters are formed by the reaction of aromatic dicarboxylic acids, aliphatic dicarboxylic acids and polyols to form the polyester. In oil-free polyesters, oils of the respective fatty acids are excluded but the other reactants are similar to those employed in the preparation of oil-modified polyesters.

What is claimed is: 
     
       1. A process for forming a water-dispersible polyester capable of being solubilized to become water-soluble comprising reacting (1) with (2a) to form (I), wherein (1) is isophthalic acid, terephthalic acid, benzophenone dicarboxylic acid or mixtures thereof and wherein   (2a) includes a polyol having at least three hydroxyl groups and a diol, wherein said polyol is trimethylol-propane, tris(hydroxymethyl)aminoethane, trimethylolethane, glycerine, pentaerythritol or tris(hydroxyethyl)isocyanurate and said diol is neopentyl glycol, 1,4-butylene glycol, dimethyl hydantoin, dipropylene glycol, ethylene glycol, diethylene glycol, propylene glycol, cyclohexane dimethanol, hydrogenated bisphenol A, hydroquinone di-(beta-hydroxyethyl) ether, the diether of propylene glycol and bisphenol A, or the diether of ethylene glycol and bisphenol A; wherein said triol is present in amounts up to 35 mole percent of all reactants used to form said polyester;   wherein said polyol and said diol are heated together and then said component (1) is added thereto;   and adding (II) which is (a) trimellitic anhydride; (b) an aliphatic dibasic acid which is adipic acid, succinic acid, azelaic acid, sebacic acid, dimerized fatty acids, maleic acid, fumaric acid or an anhydride of said acids or (c) a cycloaliphatic acid which is tetrahydrophthalic acid, hexahydrophthalic acid, 3,6-endomethylene, delta 4  -tetrahydrophthalic acid or an anhydride of said acid, which component (II) is 15 to 65 mole percent based on the total moles of (1) and (II), and wherein (1) comprises 35 to 85 mole percent of the total amount of (1) and (II);   wherein the mixture of (1) and (2a) is heated until a portion of the mixture containing 100 percent solids is characterized by an acid number of .[.at least.].  about 10 .Iadd.up to 20.Iaddend..   
     
     
       2. The process of claim 1, wherein said polyester further includes a mixture of a saturated or unsaturated fatty acid which is non-conjugated or conjugated linoleic acid, linolenic acid, oleic acid, palmitic acid, stearic acid, elaeostearic acid, lauric acid, myristic acid, pelargonic acid, isodecanoic acid or mixtures thereof in an amount ranging from 5 to 60 percent by weight of said polyester. .[.3. The process of claim 1, 
     
     
        wherein said acid number ranges up to 20..]. 4. The process of claim 1, wherein said heating step is followed by cooling and then by addition of 
     
     
        component .[.(B).]. .Iadd.(II). .Iaddend. 5. The process of claim 4, wherein said addition is followed by heating .Iadd.until the reaction product, when diluted to 80 percent solids, attains an acid value of from 
     
     
        25 to 90. 6. The process of claim 5, wherein said heating step following addition is maintained until the reaction product, when diluted to 80 
     
     
        percent solids, attains an acid value of about 40. 7. A water-dispersible polyester capable of being solubilized to become water-soluble, comprising the reaction product of component (I) and component (II) wherein: (I) is the reaction product of (1) isophthalic acid, terephthalic acid; benzophenone dicarboxylic acid or mixtures thereof; and   (2) 0 to 41 percent by weight, based on the total weight of reactants used to form said polyester, of a diol which is neopentyl glycol, 1,4-butylene glycol, dimethyl hydantoin, dipropylene glycol, ethylene glycol, diethylene glycol, propylene glycol, cyclohexane dimethanol, hydrogenated bisphenol A, hydroquinone di-(beta-hydroxyethyl) ether, the diether of propylene glycol and bisphenol A, or the diether of ethylene glycol bisphenol A and 10 to 27 percent by weight based on the total weight of all reactants of a polyol having at least three hydroxyl groups which is trimethylol-propane, tris(hydroxymethyl)aminoethane, trimethylolethane, glycerine, pentaerythritol or tris(hydroxyethyl) isocyanurate; and   (3) a saturated or unsaturated fatty acid which is non-conjugated or conjugated linoleic acid, linolenic acid, oleic acid, palmitic acid, stearic acid, elaeostearic acid, lauric acid, myristic acid, pelargonic acid, isodecanoic acid or mixtures thereof in an amount ranging from 5 to 60 percent by weight of said polyester, and wherein     (II) is (a) trimellitic anhydride; or (b) or aliphatic dibasic acid which is adipic acid, succinic acid, azelaic acid, sebacic acid, dimerized fatty acids, maleic acid, fumaric acid or an anhydride of said acids or (c) a cycloaliphatic acid which is tetrahydrophthalic acid, hexahydrophthalic acid, 3,6-endomethylene, delta 4  -tetrahydrophthalic acid or an anhydride of said acid, which component (II) is 15 to 65 mole percent based on the total moles of (1) and (II), wherein (1) comprises 35 to 85 mole percent of the total amount of (1) and (II);   wherein the OH:COOH ratio of said polyester ranges from 1:1 to 1.5:1 .[...]..Iadd.; .Iaddend.   .Iadd.wherein the acid number of the polyester is 25 to 90, based on a   
     
     
        sample of said polyester diluted to 80% solids. .Iaddend. 8. The polyester 
     
     
        of claim 7, wherein said OH:COOH ratio is 1:1 to 1.3:1. 9. The polyester 
     
     
        of claim 7, dispersed in water. 10. The polyester of claim 7, including 
     
     
        both a polyol having at least three hydroxyl groups and a diol. 11. The polyester of claim 10, wherein said polyol is trimethylol propane and said 
     
     
        diol is dipropylene glycol. 12. The polyester of claim 10, wherein said 
     
     
        polyester includes isophthalic acid and trimellitic anhydride. 13. The 
     
     
        polyester of claim 7, wherein said diol is neopentyl glycol. 14. The 
     
     
        polyester of claim 13, wherein said polyol is trimethylol-propane. 15. The 
     
     
        polyester of claim 14, wherein said element (1) is isophthalic acid. 
     
     
        16. The polyester of claim 15, which includes adipic acid. 17. The polyester of claim 7, wherein the diol is dipropylene glycol, diethylene 
     
     
        glycol or neopentyl glycol. 18. The polyester of claim 7, wherein the polyol is trimethylolpropane, trimethylolethane, glycerine or 
     
     
        tris(hydroxyethyl)isocyanurate. 19. The polyester of claim 7, wherein (B) 
     
     
        is maleic anhydride, or adipic acid. 20. The polyester of claim 7, wherein (B) is maleic anhydride, tetrahydrophthalic anhydride, hexahydrophthalic anhydride, 3,6-endomethylene, Δ 4  -tetrahydrophthalic anhydride 
     
     
        or trimellitic anhydride. 21. The polyester of claim 7, which is 
     
     
        water-soluble. 22. The reaction product formed by reacting the polyester 
     
     
        of claim 7 with an amino triazine-aldehyde reaction product. 23. The product of claim 22, wherein said triazine is hexamethoxymethyl melamine. 
     
     
         4. A water-dispersible polyester capable of being solubilized to become water-soluble comprising 2.8 moles of tall oil fatty acids, 3.8 moles of trimethylol propane, 0.4 mole of dipropylene glycol, 3.2 moles of 
     
     
        isophthalic acid and 0.9 mole of trimellitic anhydride. 25. The product 
     
     
        produced by the process of claim 1, admixed with water. 26. A pigmented enamel comprising the product of claim 25. .[.27. The product produced by the process of claim 3, admixed with water..]. .Iadd. 28. A water-dispersible polyester capable of being solubilized to become water-soluble, comprising the reaction product of component (I) and (II) wherein: (I) is the reaction product of (1) isophthalic acid, terephthalic acid; benzophenone dicarboxylic acid or mixtures thereof; and   (2) 0 to 41 percent by weight, based on the total weight of reactants used to form said polyester, of a diol which is neopentyl glycol, 1,4-butylene glycol, dimethyl hydantoin, dipropylene glycol, ethylene glycol, diethylene glycol, propylene glycol, cyclohexane dimethanol, hydrogenated bisphenol A, hydroquinone di-(beta-hydroxyethyl) ether, the diether of propylene glycol and bisphenol A, or the diether of ethylene glycol and bisphenol A and 10 to 27 percent by weight based on the total weight of all reactants of a polyol having at least three hydroxyl groups which is trimethylol-propane, tris(hydroxymethyl)aminoethane, trimethylolethane, glycerine, pentaerythritol or tris(hydroxyethyl)isocyanurate; and   (3) a saturated or unsaturated fatty acid which is non-conjugated or conjugated linoleic acid, linoleninc acid, oleic acid, palmitic acid, stearic acid, elaeostearic acid, lauric acid, myristic acid, pelargonic acid, isodecanoic acid or mixtures thereof in an amount ranging from 5 to 60 percent by weight of said polyester, and wherein     (II) is trimellitic anhydride wherein the trimellitic anhydride component (II) is 15 to 65 mole percent based on the total moles of (1) and (II), wherein (1) comprises 35 to 85 mole percent of the total amount of (1) and (II);   wherein the OH:COOH ratio of said polyester ranges from 1:1 to 1.5:1; and wherein the acid number of said polyester is 25 to 90, based on a sample of said polyester diluted to 80% solids.