Vinyl ester resin compositions containing dicyclopentadiene alkenoate

Abstract

Thermosetting resin compositions containing vinyl ester resins having terminal unsaturation, vinyl aromatic monomers, and dicyclopentadiene alkenoate concentrates are useful to make fibrous reinforcement laminates. The use of the dicyclopentadiene alkenoate concentrate accelerates the rate at which hardness develops during room temperature cure.

I claim: 
     
       1. A thermosetting resin composition which comprises (A) about 80 to about 30% by weight of a vinyl ester resin having terminal unsaturation,   (B) about 20 to about 70% by weight of an unsaturated monomer mixture of a vinyl aromatic monomer and dicyclopentadiene alkenoate concentrate .[.comprising   (a) about 50-100% by weight of compounds of the formula.]. ##STR5## .[.(b) about 0-30% of compounds of the formula.]. ##STR6## .[.(c) about 0-2% of compounds of the formula.]. ##STR7## .[.and (d) about 0-2% of compounds of the formula.]. ##STR8## .[.where R is a alkenyl group having 2-4 carbon atoms and R 1  is hydrogen or a methyl group.]. wherein the range of dicyclopentadiene alkenoate concentrate in said mixture ranges from about 5 to about 90 weight percent.   
     
     
       2. The resin composition of claim 1 wherein the vinyl ester resin is prepared by the reaction of about equivalent proportions of polyepoxides, with ethylenically unsaturated monocarboxylic acids, 2-hydroxyalkyl acrylate half esters of dicarboxylic acids, or mixtures of same with or without the subsequent reaction of dicarboxylic acid anhydrides with the epoxide-unsaturated monocarboxylic acid reaction product. 
     
     
       3. The resin composition of claim 1 wherein the dicyclopentadiene alkenoate concentrate is dicyclopentadiene acrylate. 
     
     
       4. A cured fibrous laminate made with the composition of claim 1. 
     
     
       5. A cured fibrous laminate made with the composition of claim 2. 
     
     
       6. A cured fibrous laminate made with the composition of claim 3. 
     
     
       7. A cured glass fiber laminate made with the composition of claim 1. 
     
     
       8. A cured glass fiber laminate made with the composition of claim 2. 
     
     
       9. A cured glass fiber laminate made with the composition of claim 3.