Light and heat stabilizers for polyolefins

Abstract

Compounds of the formula: ##STR1## wherein R is hydrogen or alkyl (C 1 -C 8 ), R' is hydrogen, hydroxyl or lower alkoxy (C 1 -C 8 ); R" is alkyl (C 1 -C 20 ), alkylene (C 2 -C 12 ), cycloalkyl, wherein the alicyclic ring contains 5- or 6-carbon atoms, cycloalkylene, wherein the alicyclic ring may contain lower alkyl substituents, alkenyl (C 3 -C 20 ), arylene or aralkylene; n is an integer from 1 to 4, are useful for stabilizing polyolefin polymer against photo and thermal degradation.

We claim: 
     
       1. A compound represented by the formula: ##STR10## wherein R is hydrogen or alkyl (C 1  -C 8 ), R' is hydrogen, or lower alkoxy (C 1  -C 8 ); R" is alkylene (C 2  -C 12 ), cycloalkylene, wherein the alicyclic ring may contain lower alkyl substituents, arylene or aralkylene, n is 2. 
     
     
       2. A compound as defined in claim 1 wherein R' is hydrogen. 
     
     
       3. A compound as defined in claim 1 wherein R' is lower (C 1  -C 8 ) alkoxy. 
     
     
       4. A synthetic polyolefin polymer composition stabilized against photo- and thermal degradation comprising an effective stabilizing amount of a compound of claim 1. 
     
     
       5. A composition as defined in claim 4 wherein said polyolefin is polypropylene. 
     
     
       6. A composition as defined in claim 4 wherein said compound is incorporated in an amount of about 0.01 to 5% by weight. 
     
     
       7. A composition as defined in claim 5 wherein said compound is incorporated in an amount of about 0.01 to 2% by weight. 
     
     
       8. A compound as defined in claim 1 wherein R is hydrogen. 
     
     
       9. A compound as defined in claim 1 wherein R" is alkylene (C 2  -C 12 ). .Iadd.10. A compound represented by the formula ##STR11##.Iaddend. wherein R is hydrogen or alkyl (C 1  -C 8 ), R' is hydrogen or lower alkoxy (C 1  -C 8 ); R" is ##STR12## 
     
     
        and n is 2.  .Iadd.11.  A compound represented by the formula ##STR13## wherein R is hydrogen or alkyl (C 1  -C 8 ) R' is hydrogen or lower alkoxy (C 1  -C 8 ); R" is ##STR14## and n is 2. .Iaddend.