Gas-permeable lens

Abstract

This invention comprises a gas-permeable contact lens consisting essentially of a plasticized cellulose resin selected from a partially esterified or partially etherified cellulose polymer plasticized with a compatible plasticizer in an amount sufficient to increase the gas permeability of the cellulose resin.

What is claimed is: 
     
       1. A transparent optically clear gas-permeable contact lens consisting essentially of a plasticized cellulose resin selected from a partially esterified or partially etherified cellulose polymer plasticized with a compatible plasticizer in an amount sufficient to increase the oxygen permeability of the cellulose resin at least about 13% higher than that of the unplasticized cellulose resin but below that at which the optical and physical properties of the lens are substantially adversely affected. 
     
     
       2. The contact lens of claim 1 wherein the cellulose .[.polymer.]. .Iadd.resin prior to plasticization .Iaddend.is a partially esterified cellulose polymer in which from about 20% to 60% .[.of the hydroxyl groups in the polymer are esterified with.]. .Iadd.by weight thereof is esters of .Iaddend.a C 2  to C 4  fatty acid. 
     
     
       3. The contact lens of claim 1 wherein the partially esterified cellulose .[.polymer.]. .Iadd.resin prior to plasticization .Iaddend.is selected from cellulose acetate butyrate, cellulose acetate propionate, or mixtures thereof, in which 40% to 50% .[.of the hydroxyl groups in the polymer are esterified.]. .Iadd.by weight thereof is esters, .Iaddend.and in which the predominant ester group in each .[.polymer.]. .Iadd.resin prior to plasticization .Iaddend.is, respectively, butyrate and propionate. 
     
     
       4. The contact lens of claim 1 wherein the plasticizer is selected from low molecular weight organic esters, chlorinated paraffins, phosphoric acid derivatives, epoxidized vegetable oil, polymeric plasticizers, and mixtures thereof. 
     
     
       5. The contact lens of claim 1 wherein the .[.polymer.]. .Iadd.resin prior to plasticization .Iaddend.is selected from cellulose acetate butyrate, cellulose acetate propionate, or mixtures thereof, in which about 40% to 50% .[.of the hydroxyl groups in the polymer are esterified.]. .Iadd.by weight thereof is esters .Iaddend.and in which the acetate ester group comprises no more than about 25% .Iadd.by weight .Iaddend.of the ester groups in the polymer, and in which the plasticizer is a low molecular weight organic ester formed from mono or poly acids with linear or branched-chain monohydroxy alcohols or polyols; the plasticizer being used in an amount of from about 3% to 25% by weight based on the total weight of plasticizer and polymer. 
     
     
       6. The contact lens of claim 1 wherein the cellulose resin .Iadd.prior to plasticization .Iaddend.is a partially etherified cellulose polymer selected from ethyl cellulose, ethoxyethyl cellulose, or mixtures thereof, in which from about 40% to 60% .[.of the hydroxyl groups in the polymer are etherified.]. .Iadd.by weight thereof is ethers. .Iaddend. 
     
     
       7. The contact lens of claim 6 wherein the plasticizer is selected from low molecular weight organic esters, chlorinated paraffins, phosphoric acid derivatives, epoxidized vegetable oils polymeric plasticizers, and mixtures thereof. 
     
     
       8. The contact lens of claim 6 wherein .Iadd.the cellulose resin prior to plasticization is a partially etherified cellulose polymer in which .Iaddend.45% to 50% .[.of the hydroxyl groups are etherified.]. .Iadd.by weight thereof is ethers .Iaddend.and the plasticizer is a low molecular weight organic ester formed from mono or poly acids with linear or branched-chain monohydroxy alcohols or polyols; the plasticizer being used in an amount of from about 3% to 25% by weight, based on the total weight of plasticizer and polymer. 
     
     
       9. The contact lens of claim 1 wherein the cellulose polymer is cellulose acetate propionate and the plasticizer is dihexyl azelate, said plasticizer being present in an amount from about 3% to 25% by weight based on the total weight of plasticizer and polymer. 
     
     
       10. The contact lens of claim 1 wherein the cellulose polymer is cellulose acetate butyrate and the plasticizer is di(2-ethylhexyl)adipate, said plasticizer being present in an amount from about 3% to 25% by weight based on the total weight of plasticizer and polymer.