Wood fly ash reduction method

Abstract

A method is disclosed for substantially reducing the potassium oxide context of wood fly ash contained in the combustion products generated during the burning of wood particles. The method disclosed involves mixing an alkali metal silicate, a secondary alkali metal compound and silica with the wood particles, burning the mixture, and withdrawing a stable, potassium oxide containing silicate product from the flue gases.

I claim: 
     
       1. A method for reducing the potassium oxide content of the wood fly ash contained in the combustion products generated by the burning of wood particles, which comprises: mixing with the wood particles, an alkali metal silicate having a melting point below 1200° C., a secondary alkali metal compound having a melting point below 1200° C., and silica;   burning the mixture; and   withdrawing a stable potassium oxide containing silicate product having a melting point below 1200° C. from the combustion products as a molten slag;   wherein the alkali metal silicate, the secondary alkali metal compound, and the silica are present in amounts effective to form the stable silica product in the presence of wood particles containing potassium oxide;   wherein the secondary alkali compound has a melting point not greater than the melting point of the stable silicate product; and wherein the mixture is kept deficient in alkali metal silicate .Iadd.product .Iaddend.in order to withdraw the potassium oxide from the wood fly ash.   
     
     
       2. The method of claim 1, wherein the alkali metal silicate, the secondary alkali metal compound, and the silica are mixed with the wood particles as they are being burned. 
     
     
       3. The method of claim 1, wherein the alkali metal silicate, the secondary alkali metal compound, and the silica are mixed with the wood particles prior to burning. 
     
     
       4. The method of claim 1, wherein the alkali metal silicate is selected from the group consisting of potassium tetrasilicate, potassium metasilicate, potassium disilicate, sodium lithium metasilicate, and sodium disilicate. 
     
     
       5. The method of claim 1, wherein the secondary alkali metal compound is selected from the group consisting of alkali metal carbonates, alkali metal hydroxides, and a second alkali metal silicate. 
     
     
       6. The method of claim 1, wherein the secondary alkali metal compound is selected from the group consisting of lithium carbonate, sodium carbonate, and potassium carbonate. 
     
     
       7. The method of claim 1, wherein the stable potassium oxide containing silicate product is a potassium lithium silicate or a sodium potassium lithium silicate. 
     
     
       8. The method of claim 7, wherein the stable potassium oxide containing silicate product is selected from the group consisting of 2K 2  O.Li 2  O.6SiO 2 , 5K 2  O.Li 2  O. 4SiO 2 , K 2  O.Li 2  O.4SiO 2 , and Na 2  O.K 2  O.Li 2  O.6SiO 2 . 
     
     
       9. The method of claim 1, wherein from 0.5 to 3 moles of the alkali metal silicate, from 0.5 to 1.5 moles of the secondary alkali metal compound, and from 2 to 6 moles of the silica are mixed with the wood particles per mole of potassium oxide present in the wood fly ash. .Iadd. 
     
     
       10.  A method for reducing the potassium oxide content of the wood fly ash contained in the combustion products generated by the burning of wood particles, which comprises: mixing with the wood particles, an alkali metal silicate having a melting point below 1200° C. selected from the group consisting of potassium tetrasilicate, potassium metasilicate, potassium disilicate, sodium lithium metasilicate, and sodium disilicate, a secondary alkali metal compound having a melting point below 1200° C. selected from the group consisting of alkali metal carbonates, alkali metal hydroxides, and a second alkali metal silicate, and silica;   burning the mixture; and   withdrawing a stable potassium oxide containing silicate product having a melting point below 1200° C. from the combustion products as a molten slag, said silicate product being a potassium lithium silicate or a sodium potassium lithium silicate;   wherein the alkali metal silicate, the secondary alkali metal compound, and the silica are present in amounts effective to form the stable silica product in the presence of wood particles containing potassium oxide;   wherein the secondary alkali compound has a melting point not greater than the melting point of the stable silicate product; and   wherein the mixture is kept deficient in the silicate product in order to withdraw the potassium oxide from the wood fly ash. .Iaddend. .Iadd.   
     
     
       11.  The method of claim 10, wherein the secondary alkali metal compound is selected from the group consisting of lithium carbonate, sodium carbonate, and potassium carbonate. .Iaddend. .Iadd.12. The method of claim 10, wherein the stable potassium oxide containing silicate product is selected from the group consisting of 2 K 2  O.Li 2  O.6SiO 2 , 5K 2O .Li 2  O.4SiO 2 , K 2O .Li 2  O.4SiO 2 , and Na 2  O.K 2  O.Li 2  O.6 SiO 2 . .Iaddend.