Water-soluble thermosetting resins and use thereof

Abstract

Disclosed is a novel water-soluble thermosetting resin which has the property of providing paper with a nearly constant wet and dry strength over a wide pH range according to methods of wet-end additions or surface applications.

What is claim is: 
     
       1. A thermosetting resin of the formula ##STR15## wherein: R 1 , R 2 , .[.and.]. R 3  and R 6  are independently selected from the group consisting of hydrogen and a methyl group, R 4  and R 5  are each an alkyl group having .Badd.1 to 3 carbon atoms,   A is an alkylene group having 2 to 6 carbon atoms,   X is selected from the group consisting of chlorine, bromine and iodine,   Y is an anion selected from the group consisting of nitrate ion, .[.chlorine.]. .Iadd.chloride .Iaddend.ion, sulfate ion and phosphate ion,   p, q, r and s are molar ratios of the recurring units arranged linearly and irregularly, and are the whole numbers .[.which are.]. .Iadd.having the relation of .Iaddend.q/(p+q)=0.1-1.0, r/(p+q+r+s)=0.001-0.05 and s/r=0.5-1.5; or s=0, q/(p+q)=0.1-1.0, r/(p+q+r)=0.001-0.05, and n is .Iadd.a number of .Iaddend.about 100 to about 1000.   
     
     
       2. The resin of claim 1 wherein p, q, r and s are molar ratios of the recurring units arranged linearly and irregularly, and are the whole numbers .[.which are.]. .Iadd.having the relation of .Iaddend.q/(p+q)=0.01-1.0, r/(p+q+r+s)=0.001-0.05, s/r=0.5-1.5. 
     
     
       3. The resin of claim 2 wherein R 1 , R 2  and R 6  are each hydrogen, and R 3 , R 4  and R 5  are each a methyl group and X is chlorine. 
     
     
       4. The resin of claim 2 wherein R 1  and R 2  are each hydrogen, and R 3 , R 4 , R 5  and R 6  are each a methyl group and X is chlorine. 
     
     
       5. The resin of claim 3 wherein Y is a nitrate ion. 
     
     
       6. The resin of claim 4 wherein Y is a nitrate ion. 
     
     
       7. The resin of claim 3 wherein Y is a .[.chlorine.]. .Iadd.chloride .Iaddend.ion. 
     
     
       8. The resin of claim 4 wherein Y is a .[.chlorine.]. .Iadd.chloride .Iaddend.ion. 
     
     
       9. The resin of claim 1 wherein s=0; p, q and r are molar ratios of the recurring units arranged linearly and irregularly, and are the whole numbers .[.which are.]. .Iadd.having the relation of .Iaddend.q/(p+q)=0.1-1.0, r/(p+q+r)=0.001-0.05. 
     
     
       10. The resin of claim 9 wherein R 1  and R 2  are each hydrogen, and R 3 , R 4  and R 5  are each a methyl group and X is chlorine. 
     
     
       11. The resin of claim 10 wherein Y is a nitrate ion. 
     
     
       12. The resin of claim 10 wherein Y is a .[.chlorine.]. .Iadd.chloride .Iaddend.ion.