Crystalline silicates and catalytic conversion of organic compounds therewith

Abstract

A crystalline metal organosilicate having the composition, in its anhydrous state, as follows: 0.9±0.2[xR.sub.2 O+(1-x)M.sub.2/n O]:<0.005 Al.sub.2 O.sub.3 :>1SiO 2 where M is a metal, other than a metal of Group IIIA, n is the valence of said metal, R is an alkyl ammonium radical and x is a number greater than 0 but not exceeding 1, said organosilicate being characterized by a specified X-ray diffraction pattern. Said organosilicate is prepared by digesting a reaction mixture comprising (R 4 N) 2 O, sodium oxide, an oxide of a metal other than a metal of group IIIA, an oxide of silicon and water. The crystalline organosilicates are useful as adsorbents and in their catalytically active form as catalysts for organic compound conversion.

We claim: 
     
       1. A crystal metal organosilicate having a composition, in its anhydrous state, in terms of mole ratios of oxides as follows:   0.9± 0.2[xR.sub.2 O+ (1-x)M.sub.2/n O]:<0.005 Al.sub.2 O.sub.3 :> 1 SiO.sub.2     where M is sodium or sodium in combination with tin, calcium, nickel or zinc, R is a tetraalkylammonium and x is a number greater than 0 but not exceeding 1, said organosilicate having the X-ray diffraction lines set forth in Table I of the specification.   
     
     
       2. A crystalline silicate resulting from thermal treatment of the composition of claim 1 by heating to a temperature in the range of 200° to 600° C. for between 1 and 48 hours. 
     
     
       3. The composition of claim 1 which has been exchanged with ammonium ions. 
     
     
       4. The composition of claim 1 wherein R is tetrapropylammonium. 
     
     
       5. The composition of claim 1 wherein M comprises tin. 
     
     
       6. The composition of claim 1 wherein M comprises sodium. 
     
     
       7. The composition of claim 1 wherein M comprises calcium. 
     
     
       8. The composition of claim 1 wherein M comprises nickel. 
     
     
       9. The composition of claim 1 wherein M comprises zinc. 
     
     
       10. A method of preparing a crystalline metal organosilicate as defined in claim 1 which comprises preparing a mixture containing a tetraalkylammonium compound, sodium oxide, an oxide of tin, calcium, nickel, or zinc, an oxide of silicon and water and having a composition in terms of mole ratios of oxides falling within the following ranges:   ______________________________________                                    
OH.sup.- /SiO.sub.2  .01-5                                                
R.sub.4 N.sup.- /(R.sub.4 N.sup.+ + Na.sup.+)                             
                     .05-1.0                                              
H.sub.2 O/OH.sup.-   50-1000                                              
SiO.sub.2 /M.sub.2/n O                                                    
                     >1                                                   
______________________________________                                    
     wherein R is alkyl radical and M is total metal, maintaining the mixture at a temperature at about 100° C. to about 175° C. until crystals of said metal organosilicate are formed and separated and recovering said crystals.   
     
     
       11. A method of preparing a crystalline metal organosilicate as defined in claim 1 which comprises preparing a mixture containing a tetraalkylammonium compound, sodium oxide, an oxide of tin, calcium, nickel or zinc, an oxide of silicon and water and having a composition in terms of mole ratios of oxides falling within the following ranges:   ______________________________________                                    
OH.sup.- /SiO.sub.2  .05-1.0                                              
R.sub.4 N.sup.+ /(R.sub.4 N.sup.+ + Na.sup.+)                             
                     .1-.8                                                
H.sub.2 O/OH.sup.-   50-500                                               
SiO.sub.2 /M.sub.2/n O                                                    
                     >3                                                   
______________________________________                                    
     wherein R is an alkyl radical and M is total metal, maintaining the mixture at a temperature at about 100° C. to about 175° C. until crystals of said metal organosilicate are formed and thereafter separating and recovering said crystals. .Iadd. 12. In a process for conducting in the presence of a solid porous catalyst a hydrocarbon conversion reaction, the improvement which comprises contacting charge hydrocarbons for said reaction at conversion conditions with a catalyst comprising the composition of claim 1. .Iaddend. .Iadd. 13. In a process for conducting in the presence of a solid porous catalyst an organic compound conversion reaction, the improvement which comprises contacting an organic compound charge for said reaction at conversion conditions with a catalyst comprising the composition of claim 2. .Iaddend..Iadd. 14. In a process for conducting in the presence of a solid porous catalyst a hydrocarbon conversion reaction, the improvement which comprises contacting charge hydrocarbons for said reaction at conversion conditions with a catalyst comprising the composition of claim 3. .Iaddend..Iadd. 15. The process of claim 12 wherein said catalyst comprises the composition of claim 4. .Iaddend..Iadd. 16. The process of claim 12 wherein said catalyst comprises the composition of claim 5. .Iaddend..Iadd. 17. The process of claim 12 wherein said catalyst comprises the composition of claim 6. .Iaddend..Iadd. 18. The process of claim 12 wherein said catalyst comprises the composition of claim 7. .Iaddend..Iadd. 19. The process of claim 12 wherein said catalyst comprises the composition of claim 8. .Iaddend..Iadd. 20. The process of claim 12 wherein said catalyst comprises the composition of claim 9. .Iaddend.