Cast cemented refractory metal carbides having improved sintered density

Abstract

Cemented carbide articles produced by tape casting a slurry of ingredients including organic resins and plasticizers, forming the cast tape into a desired shape and firing the tape, are improved by eliminating carbonaceous residue-forming ingredients from the organic portion of the slurry, resulting in reduced porosity of the fired article.

What is claimed is: 
     
       1. A cemented refractory metal carbide article consisting essentially of from about 75 to 97 weight % of discrete particles of at least one refractory metal carbide distributed in a matrix of from about 3 to about 25 weight % of a lower melting binder metal, said article having a predetermined configuration including at least a portion having a thickness of from about 0.004 inch to about 0.08 inch defined by at least 2 uneroded formed surfaces, characterized in that said article exhibits A-type, B-type and C-type porosities in accordance with ASTM specification #B-276-54 of up to and including A 3 , B 3  and C 3 . 
     
     
       2. An article according to claim 1 wherein at least a portion of said refractory metal carbide is tungsten carbide. 
     
     
       3. An article according to claim 2 wherein at least a portion of said lower melting binder metal is at least one iron group metal selected from the group consisting of iron, cobalt, an nickel. 
     
     
       4. A self-supporting flexible article having a composition consisting essentially of from about 85 to about 97% by weight of an inorganic portion consisting essentially of discrete particles of a refractory metal carbide, and a lower melting binder metal suspended in from about 3 to about 15 weight % of an inorganic portion consisting essentially of an organic plasticizer, a thermoplastic resin and a deflocculant, and having a thickness from about 0.006 to about .[.0.01.]. .Iadd.0.1 .Iaddend.inch, characterized in that said organic portion upon heating to a temperature up to about 1000° C is substantially completely removed from the article. 
     
     
       5. An article according to claim 4 wherein at least a portion of said refractory metal carbide is tungsten carbide. 
     
     
       6. An article according to claim 4 wherein at least a portion of the lower melting binder metal is at least one iron group metal selected from the group consisting of iron, cobalt and nickel. 
     
     
       7. An article according to claim 4 wherein said plasticizer is a phthalate derivative, and said binder resin is a thermoplastic resin of the vinyl type. 
     
     
       8. A process for producing a flexible self-supporting article containing discrete particles of a refractory metal carbide, and a lower melting binder metal suspended in an organic portion, the process comprising: (a) forming a slurry consisting essentially of from about 60 to 94 weight % of an inorganic portion consisting essentially of the carbide particles and particles of the lower melting binder metal, from about 2 to about 10 weight % of a solid organic portion consisting essentially of at least one plasticizer, at least one thermoplastic binder resin and at least one deflocculant, and from about 4 to about 30 weight percent of an organic solvent for said solid organic portion, (b) casting said slurry in the form of a relatively thin sheet, and (c) evaporating said solvent from said mixture to thereby form a flexible self-supporting article, characterized in that said organic portion upon heating to a temperature up to about 1000° is substantially completely removed from the article.   
     
     
       9. Process according to claim 8 wherein at least a portion of said refractory metal carbide is tungsten carbide. 
     
     
       10. Process according to claim 8 wherein at least a portion of said lower melting binder metal is at least one metal selected from the iron group metals iron, cobalt, and nickel. 
     
     
       11. Process according to claim 8 wherein said plasticizer is a phthalate derivative, and said binder resin is a thermoplastic resin of the vinyl type. 
     
     
       12. A process according to claim 8 wherein said organic solvent has a boiling point below about 150° C. 
     
     
       13. Process according to claim 12 wherein said solvent comprises at least one organic solvent selected from the group consisting of methanol and toluene.