Well cementing composition having improved flow properties containing a polyamido-sulfonic additive

Abstract

Aqueous hydraulic cement compositions containing polyamido-sulfonic compounds as flow-property-improving and turbulence-inducing additives and their use in cementing wells is disclosed.

What we claim is: .[.1. A cementing composition comprising hydraulic cement in admixture with from about 0.01 to about 5.0 percent by weight, based on weight of hydraulic cement, of a polyamido-sulfonic compound recurring units represented by the following formula: ##STR3## wherein R 1  is hydrogen or methyl; R 2 , R 3 , R 4 , and R 5  are each independently selected from the group consisting of hydrogen, phenyl, straight or branched alkyl of from one to twelve carbon atoms, and cycloalkyl of up to six carbon atoms; R 6  is straight or branched alkyl of from one to twelve carbon atoms, cycloalkyl of up to six carbon atoms, phenyl, or is absent; A is hydrogen, alkali metal ion or ammonium; and n is an integer of from 2 to about 100, such that the weight average molecular weight of the polyamido-sulfonic compound is from about 
     
        200 to about 10,000..]. 2. The composition of claim .[.1.]. .Iadd.10 .Iaddend.wherein the weight average molecular weight of the 
     
     
        polyamido-sulfonic compound is from about 200 to about 1,500. 3. The composition of claim .[.1.]. .Iadd.10 .Iaddend.wherein the said polyamido-sulfonic compound is admixed with the hydraulic cement in an amount of from about 0.1 to about 2.0 percent by weight, based on .Iadd.the .Iaddend.weight of hydraulic cement. .[.4. The composition of claim 1 wherein the polyamido-sulfonic compound is poly-(2-acrylamido-2-methylpropane-sulfonic acid) comprising recurring units of the following formula: ##STR4## 
     
     
        .[.5.  An aqueous hydraulic cement slurry composition having improved flow properties and being more readily induced to flow in turbulence, comprising dry hydraulic cement in admixture with from about 0.01 to about 5.0 percent by weight, based on weight of dry hydraulic cement, of a polyamido-sulfonic compound having recurring units represented by the following formula: ##STR5##  wherein R 1  is hydrogen or methyl; R 2 , R 3 , R 4 , and R 5  are each independently selected from the group consisting of hydrogen, phenyl, straight or branched alkyl of from one to twelve carbon atoms, and cycloalkyl of up to six carbon atoms; R 6  is straight or branched alkyl of one to twelve carbon atoms, cycloalkyl of up to six carbon atoms, phenyl, or is absent; A is hydrogen, alkali metal ion or ammonium; and n is an integer of from 2 to about 100, such that the weight average molecular weight of the polyamido-sulfonic compound is from about 200 to about 10,000; and sufficient water to make a pumpable slurry which 
     
     
        is capable of setting to form a monolithic solid..]. 6. The composition of claim .[.5.]. .Iadd.11 .Iaddend.wherein the weight average molecular weight of the polyamido-sulfonic compound is from about 200 to about 
     
     
        1,500. 7. The composition of claim .[.5.]. .Iadd.11 .Iaddend.wherein the said polyamido-sulfonic compound is admixed with the hydraulic cement in an amount of from about 0.1 to about 2.0 percent by weight, based on 
     
     
        .Iadd.the .Iaddend.weight of dry hydraulic cement. 8. The composition of claim .[.5.]. .Iadd.11 .Iaddend.wherein the water is present in an amount of from about 25 to about 60 percent by weight, based on .Iadd.the .Iaddend.weight of dry hydraulic cement. .[.9. The composition of claim 5 wherein the polyamido-sulfonic compound is poly-(2-acrylamido-2-methylpropane-1-sulfonic acid) comprising recurring units of the following formula: ##STR6## 
     
     
        .Iadd. 10.  A cementing composition comprising hydraulic cement in admixture with from about 0.01 to about 5.0 percent by weight, based on the weight of hydraulic cement, of a polyamido-sulfonic compound comprising recurring units represented by the formula: ##STR7## wherein n is an integer of from 2 to about 100, such that the weight average molecular weight of the polyamido-sulfonic compound is from about 
     
     
        200 to about 10,000. .Iaddend..Iadd. 11.  An aqueous hydraulic cement slurry composition having improved flow properties and being more readily induced to flow in turbulence, comprising dry hydraulic cement in admixture with from about 0.01 to about 5.0 percent by weight, based on the weight of dry hydraulic cement, of a polyamido-sulfonic compound having recurring units represented by the following formula: ##STR8## wherein n is an integer of from 2 to about 100, such that the weight average molecular weight of the polyamido-sulfonic compound is from about 200 to about 10,000; and sufficient water to make a pumpable slurry which is capable of setting to form a monolithic solid. .Iaddend.