US9121773B2ActiveUtilityA1

Gas sensors and methods of calibrating same

Assignee: BASCOM TURNER INSTR INCPriority: Mar 13, 2013Filed: Mar 13, 2013Granted: Sep 1, 2015
Est. expiryMar 13, 2033(~6.6 yrs left)· nominal 20-yr term from priority
G01N 25/18G01K 15/002G01K 15/005G01K 15/00
38
PatentIndex Score
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Cited by
21
References
8
Claims

Abstract

A method is provided for calibrating a thermal conductivity sensor in a first medium A from measurements in a second medium B. The method includes maintaining the sensor at a substantially fixed temperature T 1 , and measuring a heat flux I B (T 1 ) from the thermal element in the second medium B. A corresponding heat flux I A (T 1 ) in the first medium A is calculated using known thermal conductivities of the first medium A and the second medium B.

Claims

exact text as granted — not AI-modified
What is claimed is: 
     
       1. A method of calibrating a thermal conductivity sensor in a first medium A from measurements in a second medium B consisting of air free of any gaseous species of the medium A, the method comprising:
 maintaining the sensor at a substantially fixed temperature T 1 ; 
 during the maintaining step, measuring a heat flux I B (T 1 ) in the second medium B; 
 calculating a corresponding heat flux I A (T 1 ) in the first medium A, from (i) the measured heat flux in the second medium B and (ii) known thermal conductivities of the first medium A and the second medium B; and 
 based on the calculation, calibrating the sensor for measurements of a mixture of medium A and medium B by relating measurements of the heat flux I B (T 1 ) to the corresponding heat flux I A (T 1 ), thereby facilitating measurement, using the sensor, of a concentration of medium A in the mixture based on a measured heat flux of the mixture, the heat flux I A (T 1 ), and the heat flux I B (T 1 ). 
 
     
     
       2. The method of  claim 1 , wherein the first medium A comprises a member selected from the group consisting of methane, ethane, and propane. 
     
     
       3. The method of  claim 1 , wherein the fixed temperature T 1  is in a range from about 70° C. to about 300° C. 
     
     
       4. The method of  claim 1 , further comprising:
 measuring a heat flux I M (T 1 ) of the thermal conductivity sensor in a mixture of a species S A  and the second medium B, the species S A  corresponding to the first medium A; and 
 calculating a concentration C A  of the species S A  in the mixture based on the heat flux I M (T 1 ), the heat flux I A (T 1 ), and the heat flux I B (T 1 ), according to 
 
       
         
           
             
               
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       5. A thermal conductivity sensor for measuring a concentration C A  of a species S A  in a mixture of the species S A  and a medium B consisting of air, the sensor comprising:
 a thermal element; and 
 a processor configured to execute instructions stored in a non-transitory computer-readable medium to:
 maintain the thermal element at a substantially fixed temperature T 1 ; 
 with the thermal element maintained at the substantially fixed temperature, measure a heat flux I B (T 1 ) from the thermal element in the medium B free of the species S A ; and 
 calculate a heat flux I A (T 1 ) from the thermal element in the species S A , the heat flux I A (T 1 ) corresponding to the fixed temperature T 1  of the thermal element, wherein the heat flux I A (T 1 ) is calculated based on the heat flux I B (T 1 ) and thermal conductivities of the species S A  and the S A -free medium B at the fixed temperature T 1  to facilitate measurement, using the thermal element, of a concentration C A  of the species S A  in the mixture based on the heat flux I M (T 1 ), the heat flux I A (T 1 ), and the heat flux I B (T 1 ). 
 
 
     
     
       6. The sensor of  claim 5 , wherein the species S A  comprises a member selected from the group consisting of methane, ethane, and propane. 
     
     
       7. The sensor of  claim 5 , wherein the fixed temperature T 1  is in a range from about 70° C. to about 300° C. 
     
     
       8. The sensor of  claim 5 , wherein the processor is configured to execute instructions to:
 measure a heat flux I M (T 1 ) from the thermal element sensor in a mixture of the species S A  and the medium B; and 
 and calculate a concentration C A  of the species S A  in the mixture based on the heat flux I M (T 1 ), the heat flux I A (T 1 ), and the heat flux I B (T 1 ), according to 
 
       
         
           
             
               
                 C 
                 A 
               
               = 
               
                 
                   
                     
                       
                         I 
                         M 
                       
                       ⁡ 
                       
                         ( 
                         
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                           1 
                         
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                         I 
                         B 
                       
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                         I 
                         A 
                       
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                         I 
                         B 
                       
                       ⁡ 
                       
                         ( 
                         
                           T 
                           1 
                         
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                 .

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