US4956404AExpiredUtility

Plastic composition for toys, novelty items and arts and crafts

Assignee: PELZIG JOSEFPriority: Jan 10, 1989Filed: Jan 10, 1989Granted: Sep 11, 1990
Est. expiryJan 10, 2009(expired)· nominal 20-yr term from priority
Inventors:Josef Pelzig
C08L 31/04C08L 91/00C08K 3/36C08L 3/02C08K 5/103
81
PatentIndex Score
65
Cited by
7
References
23
Claims

Abstract

A composition comprising a polyvinyl acetate homopolymer emulsion, glyceryl triacetate, silicon, epoxidized oil, talc, fumed silica and dextrin exhibiting remarkable molding, coloring and printing properties for used as novelty items, activity toys and molding compounds. This composition is also for use as an artist's tool, transfer and printing medium, as an exercising device and for art therapy. The molded object, after exposure to air, becomes dry and will remain flexible and permanent, including fine detail and brilliant colors. The composition may contain suitable food dyes, which allows the color to be transferred from the compound to paper, canvas, fabric and wall. The color print dries instantly. Luster and pearlescent pigments brushed on the surface of the molded objects gives the appearance of cast precious metal.

Claims

exact text as granted — not AI-modified
It is claimed: 
     
       1. A semi-solid plastic composition that is elastic and pliable and which remains flexible and does not become brittle after exposure to air and which retains fine detail of surface impressions without flow-back, consisting essentially of: (a) A dextrin incompatible polyvinyl acetate homopolymer emulsion in an amount from about 50 to about 95 wt.%, which coagulates in the presence of dextrin with the resulting coagulum incorporating all of the water of the emulsion to form a semi-solid plastic composition;   (b) glyceryl triester in an amount from about 1 to about 6 wt.%;   (c) epoxidized oil in an amount from about 0.5 to about 3.0 wt.%;   (d) fumed silica in an amount from about 1 to about 6 wt.%;   (e) hydrogenated starch hydrolysate in an amount from about 0.5 to about 3.0 wt.%; and   (f) dextrin in an amount from about 1 about 4 wt.%.   
     
     
       2. A composition as claimed in claim 1 wherein the polyvinyl acetate homopolymer emulsion is composed of about 45% to about 55% solids and about 45% to about 55% water, the glyceryl triester is glyceryl triacetate and dextrin is a solidifier. 
     
     
       3. A composition as claimed in claim 2, including silicone fluid. 
     
     
       4. A composition as claimed in claim 3, wherein there is about 50% to about 95% polyvinyl acetate homopolymer emulsion and about 1% to about 6% glyceryl triacetate, 0.5% to about 3% epoxidized oil and about 1% to about 6% silicone fluid. 
     
     
       5. The composition of claim 2 including about 0.1% to about 1% antimicrobial and antibacterial agent. 
     
     
       6. A composition as claimed in claim 2, including a buffer to retain the pH in a range of about 6.0 to 8.0. 
     
     
       7. The composition of claim 2, including about 1% to about 6% mineral oil. 
     
     
       8. A composition as claimed in claim 7, including about 0.5% to about 3% diethylene glycol. 
     
     
       9. A composition as claimed in claim 7, including about 0.5% to about 3% sodium lauryl sulfate. 
     
     
       10. A composition as claimed in claim 7, including about 0.1% to about 1% fragrance compound. 
     
     
       11. A composition as claimed in claim 7, including about 0.5% to about 3% sodium chloride. 
     
     
       12. A composition as claimed in claim 7, including about 2% to about 12% talc. 
     
     
       13. A composition as claimed in claim 7, including about 1% to about 6% zinc. 
     
     
       14. A composition as claimed in claim 7, including the addition of food dye compositions, about to about 10%. 
     
     
       15. A composition as claimed in claim 7, including the addition of non-toxic dry pigment compositions, about 1% to about 10%. 
     
     
       16. A composition as claimed in claim 2, wherein the triacetin is selected from the group consisting of glyceryl triacetate, triacetyl glycerin, propanetriol triacetate, mixed triesters of glyceryl and mixtures and combinations thereof. 
     
     
       17. A composition as claimed in claim 2 including luster pigments. 
     
     
       18. A composition as claimed in claim 1 including whitener. 
     
     
       19. A semi-solid plastic composition which is elastic, pliable and flexible, suitable for molding, three dimensional painting and crafting, and having a pH of about 6.0 to 8.0 consisting essentially of: (a) about 50% to about 95% polyvinyl acetate homopolymer emulsion being composed of about 45% to about 55% solid and about 45% to about 55% water;   (b) about 1% to about 6% silicone fluid;   (c) about 1% to about 6% glyceryl triacate;   (d) about 0.5% to about 3% epoxidized oil;   (e) about 1% to about 6% whitener;   (f) about 2% to about 12% inert filler material;   (g) about 1% to about 6% fumed silica   (h) about 1% to about 4% dextrin;   (i) about 0.5% to about 3% hydrogenated starch hydrolysate; and   (j) about 0.5% to about 3% diethylene glycol.   
     
     
       20. A semi-solid plastic composition suitable for printing which is elastic and flexible, having a pH of about 6.0 to 8.0 and consisting essentially of: (a) about 50% to about 95% polyvinyl acetate emulsion;   (b) about 1% to about 6% silicone fluid;   (c) about 0.5% to about 3% epoxidized oil;   (d) about 1% to about 6% glyceryltriacetate;   (e) about 1% to about 4% dextrin;   (f) about 0.5% to about 3%, hydrogenated starch hydrolysate; and   (g) about 0.5% to about 3% diethylene glycol.   
     
     
       21. A semi-solid plastic composition which is elastic and pliable and remains flexible after exposure to the air consisting essentially of: (a) Polyvinyl acetate homopolymer emulsion;   (b) Glyceryl triacetate;   (c) Epoxidized oil;   (d) hydrogenated starch hydrolysate; and   (e) Dextrin.   
     
     
       22. A semi-solid plastic composition which is elastic and pliable and remains flexible after exposure to the air for hand molding at about room temperature consisting essentially of: (a) a dextrin incompatible polyvinyl acetate homopolymer emulsion in an amount from about 50 to about 95 wt.%, which coagulates in the presence of dextrin with the resulting coagulum incorporating all of the water of the emulsion to form a semi-solid plastic composition;   (b) glyceryl triester in an amount from about 1 to about 6 wt.%;   (c) epoxidized oil in an amount from about 0.5 to about 3.0 wt.%;   (d) fumed silica in an amount from about 1 to about 6 wt.%;   (e) hydrogenated starch hydrolysate in an amount from about 0.5 to about 3.0 wt.%; and   (f) dextrin in an amount from about 1 to about 4 wt.%.   
     
     
       23. A composition as claimed in claim 19 wherein the consistency permits hand molding at about room temperature.

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