Gas sensor

Abstract

A gas sensor includes a sensor element and a control device, and configured to measure a carbon dioxide concentration in a measurement gas, wherein the control device performs, a first pump cell control processing in which oxygen is pumped out from around a first inner electrode, a second pump cell control processing in which oxygen is pumped to around a second inner electrode by controlling the second pump cell, a third pump cell control processing in which oxygen is pumped to around a third inner electrode by controlling the third pump cell, and the control device derives the carbon dioxide concentration in the measurement gas based on the third pump current flowing through the third pump cell by the third pump cell control processing, while taking into account the second pump current flowing through the second pump cell by the second pump cell control processing.

What is claimed is: 
     
         1 . A gas sensor comprising a sensor element and a control device, and configured to measure a carbon dioxide concentration in a measurement gas,
 wherein:   the sensor element includes:   an element body having an oxygen-ion-conductive solid electrolyte layer and a measurement gas flow path formed therein for introducing and allowing flow of the measurement gas;   a first pump cell including a first inner electrode disposed in a first chamber of the measurement gas flow path, and a first outer electrode disposed on the outside of the element body;   a second pump cell including a second inner electrode disposed in a second chamber located downstream of the first chamber of the measurement gas flow path, and a second outer electrode disposed on the outside of the element body;   a third pump cell including a third inner electrode disposed in a third chamber located downstream of the second chamber of the measurement gas flow path, and a third outer electrode disposed on the outside of the element body;   the control device performs:   a first pump cell control processing in which oxygen is pumped out from around the first inner electrode to around the first outer electrode by controlling the first pump cell, thereby reducing water and carbon dioxide in the measurement gas in the first chamber;   a second pump cell control processing in which oxygen is pumped from around the second outer electrode to around the second inner electrode by controlling the second pump cell, thereby oxidizing hydrogen generated by the reduction of water in the first chamber in the second chamber;   a third pump cell control processing in which oxygen is pumped from around the third outer electrode to around the third inner electrode by controlling the third pump cell, thereby oxidizing carbon monoxide generated by the reduction of carbon dioxide in the first chamber in the third chamber; and   the control device derives the carbon dioxide concentration in the measurement gas based on the third pump current flowing through the third pump cell by the third pump cell control processing, while taking into account the second pump current flowing through the second pump cell by the second pump cell control processing.   
     
     
         2 . The gas sensor according to  claim 1 ,
 wherein the control device derives the carbon dioxide concentration based on a corrected third pump current obtained by correcting the third pump current taking into account the second pump current, or derives the carbon dioxide concentration by correcting a provisional carbon dioxide concentration based on the third pump current taking into account the second pump current.   
     
     
         3 . The gas sensor according to  claim 2 ,
 wherein the control device derives the corrected third pump current or the carbon dioxide concentration by applying a correction in such a manner that the greater the absolute value of the second pump current, the more the absolute value of the third pump current or the provisional carbon dioxide concentration tends to increase.   
     
     
         4 . The gas sensor according to  claim 2 ,
 wherein the control device derives the corrected third pump current or the carbon dioxide concentration by applying a correction in such a manner that the greater the absolute value of the second pump current, the more the absolute value of the third pump current or the provisional carbon dioxide concentration tends to decrease.   
     
     
         5 . The gas sensor according to  claim 2 ,
 wherein the control device derives a correction value based on the absolute value of the second pump current, and corrects the third pump current or the provisional carbon dioxide concentration using the correction value.   
     
     
         6 . The gas sensor according to  claim 5 ,
 wherein the correction value is a multiplication coefficient for the absolute value of the third pump current or the provisional carbon dioxide concentration, and   the control device corrects the third pump current or the provisional carbon dioxide concentration by multiplying the absolute value of the third pump current or the provisional carbon dioxide concentration by the correction value.   
     
     
         7 . The gas sensor according to  claim 6 ,
 wherein the control device corrects the third pump current or the provisional carbon dioxide concentration using the same correction value derived based on the absolute value of the second pump current, regardless of the magnitude of the absolute value of the third pump current or the provisional carbon dioxide concentration.   
     
     
         8 . The gas sensor according to  claim 1 ,
 wherein the control device derives a water concentration in the measurement gas based on the second pump current.   
     
     
         9 . The gas sensor according to  claim 1 ,
 wherein at least two of the first outer electrode, the second outer electrode, and the third outer electrode are shared electrodes.   
     
     
         10 . The gas sensor according to  claim 1 ,
 wherein the sensor element includes a reference electrode disposed inside the element body to contact a reference gas, and   the control device controls:   the first pump cell such that a first voltage between the reference electrode and the first inner electrode reaches a first voltage target value in the first pump cell control processing;   the second pump cell such that a second voltage between the reference electrode and the second inner electrode reaches a second voltage target value in the second pump cell control processing; and   the third pump cell such that a third voltage between the reference electrode and the third inner electrode reaches a third voltage target value in the third pump cell control processing.