Repellent

Abstract

A water dispersible repellent containing a modified form of a polyol and at least one kind of dispersant selected from the group consisting of a nonionic dispersant, a cationic dispersant, an amphoteric dispersant, and an inorganic dispersant, wherein the volume abundance ratio of particles having a size of 100 μm or more, as measured by laser diffraction scattering, is 25% or less, the repellent being capable of imparting oil resistance to a base material (for example, fiber or paper).

1 . A water-dispersible repellent comprising a modified body of polyol and at least one dispersant selected from the group consisting of a nonionic dispersant, a cationic dispersant, an amphoteric dispersant and an inorganic dispersant,
 wherein the repellent has a volume abundance ratio of particles with a size of 100 μm or larger of 25% or less as measured by laser diffraction scattering,   wherein the modified body of polyol is a compound formed by replacing one or more hydroxy groups in the polyol with a group represented by the following formula:   
       
         
           
           
               
               
           
         
         wherein Y is 
       
       
         
           
           
               
               
           
         
         wherein, independently at each occurrence, 
         Y 11  is a direct bond, —C(═O)—, —C(═O)—NR′— or —C(═S)—NR′—, 
         Y 21  is a hydrocarbon group having 1 to 40 carbon atoms and optionally having —OR′ and 
         Y 12  is —O—, —O—C(═O)—, —O—C(═O)—O—, —O—C(═O)—NR′—, —NR′—, —NR′—C(═O)—, —NR′—C(═O)—O—, —NR′—C(═O)—NR′—, —C(═O)—, —C(═O)—O—, —C(═O)—NR′—, —SO 2 —, —SO 2 NR′—, —C(OR′)R′— or —C(OR′)(−) 2 , wherein R′ is independently at each occurrence a hydrogen atom or an organic group having 1 to 30 carbon atoms, 
         Z is a monovalent hydrocarbon group having 6 or more and 40 or less carbon atoms, and 
         n is 1 or 2. 
       
     
     
         2 . The repellent according to  claim 1 , wherein the modified body of polyol has an alkyl group having 6 or more and 40 or less carbon atoms. 
     
     
         3 . The repellent according to  claim 1 , wherein the polyol is at least one selected from the group consisting of a monosaccharide, an oligosaccharide, a polysaccharide, a sugar alcohol, a hydroxy acid, an amino acid, vitamin, flavonol, hydroxyhydrocarbon and a polymer of a hydroxy group-containing compound. 
     
     
         4 . The repellent according to  claim 1 , wherein the polyol is at least one selected from the group consisting of:
 glucose, fructose, galactose, xylose;   sucrose, cycloamylose, cyclodextrin, maltose, trehalose, lactose, sucralose;   sorbitol, maltitol, erythritol, isomalt, lactitol, mannitol, xylitol, sorbitan, lactitol;   starch, cellulose, curdlan, pullulan, alginic acid, carrageenan, guar gum, chitin, chitosan, locust bean gum, kappa-carrageenan, iota-carrageenan, isomaltodextrin, gellan gum, tamarind seed gum;   ascorbic acid, kojic acid, quinic acid, chlorogenic acid, gluconic acid;   glucosamine;   inositol;   catechin, quercetin, anthocyanin;   glycerol, ethylene glycol, propylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, neopentyl glycol, trimethylene glycol, trimethylolpropane, trimethylolethane;   polyglycerol, polyvinyl alcohol, hydroxyethyl (meth)acrylate polymer, hydroxypropyl (meth)acrylate polymer and hydroxybutyl (meth)acrylate polymer.   
     
     
         5 . The repellent according to  claim 1 , wherein the modified body of polyol has a biobased content of 20% or more. 
     
     
         6 . The repellent according to  claim 1 , wherein the modified body of polyol has a hexadecane contact angle of 30° or more. 
     
     
         7 . The repellent according to  claim 1 , wherein the dispersant comprises a dispersant other than a fatty acid ester having an HLB value of 7 or more. 
     
     
         8 . The repellent according to  claim 1 , wherein the modified body of polyol is a compound formed by replacing a hydroxy group of polyol with a group represented by the following formula: 
       
         
           
           
               
               
           
         
         wherein Y is 
       
       
         
           
           
               
               
           
         
         wherein, independently at each occurrence, 
         Y 11  is a direct bond, —C(═O)—, —C(═O)—NR′— or —C(═S)—NR′—, 
         Y 21  is a hydrocarbon group having 1 to 40 carbon atoms and optionally having a substituent, 
         Y 12  is —O—, —O—C(═O)—, —O—C(═O)—O—, —C(═O)—NR′—, —O—C(═O)—NR′—, —NR′—, —NR′—C(═O)—, —NR′—C(═O)—O—, —NR′—C(═O)—NR′—, —C(═O)—, —C(═O)—O—, —C(═O)—NR′—, —SO 2 —, —SO 2 NR′—, —C(OR′)R′— or —C(OR′)(−) 2 , 
         Z is a hydrocarbon group having 6 or more and 40 or less carbon atoms, and 
         n is an integer of 1 or more and 3 or less, and 
         the polyol is at least one selected from the group consisting of: 
         glucose, fructose, galactose, xylose; 
         sucrose, cycloamylose, cyclodextrin, maltose, trehalose, lactose, sucralose; 
         sorbitol, maltitol, erythritol, isomalt, lactitol, mannitol, xylitol, sorbitan, lactitol; 
         starch, cellulose, curdlan, pullulan, alginic acid, carrageenan, guar gum, chitin, chitosan, locust bean gum, kappa-carrageenan, iota-carrageenan, isomaltodextrin, gellan gum, tamarind seed gum; 
         ascorbic acid, kojic acid, quinic acid, chlorogenic acid, gluconic acid; 
         glucosamine; 
         inositol; 
         catechin, quercetin, anthocyanin; 
         glycerol, ethylene glycol, propylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, neopentyl glycol, trimethylene glycol, trimethylolpropane, trimethylolethane; 
         polyglycerol, polyvinyl alcohol, hydroxyethyl (meth)acrylate polymer, hydroxypropyl (meth)acrylate polymer and hydroxybutyl (meth)acrylate polymer, and 
         the modified body of polyol has a hydroxy group substitution ratio of 30% or more. 
       
     
     
         9 . The repellent according to  claim 1 , wherein the modified body of polyol is a compound formed by replacing a hydroxy group of polyglycerol having a degree of polymerization of 5 or more and 15 or less or a sugar alcohol with a group represented by the following formula: 
       
         
           
           
               
               
           
         
         wherein
 Z is an alkyl group having 14 or more and 24 or less carbon atoms, and 
 the modified body of polyol has a hydroxy group substitution ratio of 50% or more. 
 
       
     
     
         10 . The repellent according to  claim 1 , which is for a textile product or a paper product. 
     
     
         11 . A product treated with the repellent according to  claim 1 . 
     
     
         12 . The product according to  claim 11 , which is a textile product or a paper product. 
     
     
         13 . The product according to  claim 11 , which is an oil-resistant paper or a water-resistant paper. 
     
     
         14 . The product according to  claim 11 , which is a food packaging material or a food container. 
     
     
         15 . A method for producing a treated product, comprising treating a substrate with the repellent according to  claim 1 . 
     
     
         16 . The production method according to  claim 15 , wherein the treatment is internal addition treatment.