US2025333812A1PendingUtilityA1

Austenite stainless steel and manufacturing method therefor

Assignee: POSCO CO LTDPriority: May 31, 2022Filed: Mar 10, 2023Published: Oct 30, 2025
Est. expiryMay 31, 2042(~15.8 yrs left)· nominal 20-yr term from priority
C21D 8/02C22C 38/42C22C 38/58C22C 38/04C22C 38/02C21D 8/0263C21D 8/0236C21D 8/0226C21D 6/008C21D 6/005C21D 6/004C21D 2211/001C21D 8/0273C22C 38/001C21D 9/46C21D 8/0205
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Claims

Abstract

Provided are an austenite stainless steel having high strength, high ductility, and improved corrosion resistance by realizing ultrafine grain characteristics and a manufacturing method therefor. The austenite stainless steel according to an embodiment of the present disclosure includes, in weight %, at least 0.05% but not more than 0.1% of C, at least 0.2% but not more than 0.7% of Si, at least 2.0% but not more than 4.0% of Mn, more than 0% but less than 0.1% of P, more than 0% but less than 0.01% of S, at least 17% but not more than 19% of Cr, at least 2.0% but not more than 4.0% of Ni, at least 1.0% but not more than 2.5% of Cu, at least 0.15% but not more than 0.25% of N, and the balance being iron (Fe) and inevitable impurities and is 5 μm or less in average grain diameter of the thickness center.

Claims

exact text as granted — not AI-modified
1 . An austenite stainless steel comprising, in weight %, at least 0.05% but not more than 0.1% of C, at least 0.2% but not more than 0.7% of Si, at least 2.0% but not more than 4.0% of Mn, more than 0% but less than 0.1% of P, more than 0% but less than 0.01% of S, at least 17% but not more than 19% of Cr, at least 2.0% but not more than 4.0% of Ni, at least 1.0% but not more than 2.5% of Cu, at least 0.15% but not more than 0.25% of N, and the balance being iron (Fe) and inevitable impurities,
 wherein an average grain diameter of the thickness center is 5 μm or less.   
     
     
         2 . The austenite stainless steel according to  claim 1 , wherein an austenite stability parameter (ASP) represented by Expression (1) below is −30 to 30: 
       
         
           
             
               
                 
                   
                     551 
                     - 
                     
                       462 
                       × 
                       
                         ( 
                         
                           
                             [ 
                             C 
                             ] 
                           
                           + 
                           
                             [ 
                             N 
                             ] 
                           
                         
                         ) 
                       
                     
                     - 
                     
                       9.2 
                       × 
                       
                         [ 
                         Si 
                         ] 
                       
                     
                     - 
                     
                       8.1 
                       × 
                       
                         [ 
                         Mn 
                         ] 
                       
                     
                     - 
                     
                       13. 
                       7 
                       × 
                       
                         [ 
                         Cr 
                         ] 
                       
                     
                     - 
                     
                       29 
                       × 
                       
                         ( 
                         
                           
                             [ 
                             Ni 
                             ] 
                           
                           + 
                           
                             [ 
                             Cu 
                               
                             ] 
                           
                         
                         ) 
                       
                     
                   
                 
                 
                   
                     Expression 
                     ⁢ 
                         
                     
                       ( 
                       1 
                       ) 
                     
                   
                 
               
             
           
         
         (in Expression (1), [C], [N], [Si], [Mn], [Cr], [Ni], and [Cu] represent weight percentages (wt %) of respective elements). 
       
     
     
         3 . The austenite stainless steel according to  claim 1 , wherein a strength stability parameter (SSP) represented by Expression (2) below is 0 or more: 
       
         
           
             
               
                 
                   
                     
                       5 
                       ⁢ 
                       8 
                     
                     + 
                     
                       1 
                       ⁢ 
                       3 
                       ⁢ 
                       2 
                       × 
                       
                         [ 
                         C 
                         ] 
                       
                     
                     - 
                     
                       
                         7 
                         . 
                         9 
                       
                       × 
                       
                         [ 
                         Si 
                         ] 
                       
                     
                     + 
                     
                       1. 
                       × 
                       
                         [ 
                         Mn 
                         ] 
                       
                     
                     - 
                     
                       
                         5 
                         . 
                         6 
                       
                       × 
                       
                         [ 
                         Cr 
                         ] 
                       
                     
                     + 
                     
                       7. 
                       × 
                       
                         [ 
                         Ni 
                         ] 
                       
                     
                     + 
                     
                       3.9 
                       × 
                       
                         [ 
                         Cu 
                         ] 
                       
                     
                     + 
                     
                       1.7 
                       × 
                       
                         [ 
                         N 
                         ] 
                       
                     
                   
                 
                 
                   
                     Expression 
                     ⁢ 
                         
                     
                       ( 
                       2 
                       ) 
                     
                   
                 
               
             
           
         
         (in Expression (2), [C], [Si], [Mn], [Cr], [Ni], [Cu], and [N] represent weight percentages (wt %) of respective elements). 
       
     
     
         4 . The austenite stainless steel according to  claim 1 , wherein a pitting resistance equivalent number (PREN) represented by Expression (3) below is 17 or more: 
       
         
           
             
               
                 
                   
                     
                       [ 
                       Cr 
                       ] 
                     
                     - 
                     
                       
                         0 
                         . 
                         5 
                       
                       × 
                       
                         [ 
                         Mn 
                         ] 
                       
                     
                     + 
                     
                       1 
                       ⁢ 
                       6 
                       × 
                       
                         [ 
                         N 
                         ] 
                       
                     
                   
                 
                 
                   
                     Expression 
                     ⁢ 
                         
                     
                       ( 
                       3 
                       ) 
                     
                   
                 
               
             
           
         
         (in Expression (3), [Cr], [Mn], and [N] represent weight percentages (wt %) of respective elements). 
       
     
     
         5 . The austenite stainless steel according to  claim 1 , wherein a yield strength is 600 MPa or more. 
     
     
         6 . The austenite stainless steel according to  claim 1 , wherein an elongation is 30% or more. 
     
     
         7 . The austenite stainless steel according to  claim 1 , wherein a pitting potential value is 200 mV or more. 
     
     
         8 . The austenite stainless steel according to  claim 1 , wherein a thickness is 0.4 mm to 2.0 mm. 
     
     
         9 . A method for manufacturing an austenite stainless steel, the method comprising:
 manufacturing an ingot including, in weight %, at least 0.05% but not more than 0.1% of C, at least 0.2% but not more than 0.7% of Si, at least 2.0% but not more than 4.0% of Mn, more than 0% but less than 0.1% of P, more than 0% but less than 0.01% of S, at least 17% but not more than 19% of Cr, at least 2.0% but not more than 4.0% of Ni, at least 1.0% but not more than 2.5% of Cu, at least 0.15% but not more than 0.25% of N, and the balance being iron (Fe) and inevitable impurities;   hot rolling the ingot into a hot-rolled steel sheet;   cold rolling the hot-rolled steel sheet into a cold-rolled steel sheet; and   final annealing the cold-rolled steel sheet.   
     
     
         10 . The method according to  claim 9 , wherein the ingot has an austenite stability parameter (ASP), represented by Expression (1) below, of −30 to 30: 
       
         
           
             
               
                 
                   
                     551 
                     - 
                     
                       462 
                       × 
                       
                         ( 
                         
                           
                             [ 
                             C 
                             ] 
                           
                           + 
                           
                             [ 
                             N 
                             ] 
                           
                         
                         ) 
                       
                     
                     - 
                     
                       9.2 
                       × 
                       
                         [ 
                         Si 
                         ] 
                       
                     
                     - 
                     
                       8.1 
                       × 
                       
                         [ 
                         Mn 
                         ] 
                       
                     
                     - 
                     
                       13. 
                       7 
                       × 
                       
                         [ 
                         Cr 
                         ] 
                       
                     
                     - 
                     
                       29 
                       × 
                       
                         ( 
                         
                           
                             [ 
                             Ni 
                             ] 
                           
                           + 
                           
                             [ 
                             Cu 
                             ] 
                           
                         
                         ) 
                       
                     
                   
                 
                 
                   
                     Expression 
                     ⁢ 
                         
                     
                       ( 
                       1 
                       ) 
                     
                   
                 
               
             
           
         
         (in Expression (1), [C], [N], [Si], [Mn], [Cr], [Ni], and [Cu] represent weight percentages (wt %) of respective elements). 
       
     
     
         11 . The method according to  claim 9 , wherein the ingot has a strength stability parameter (SSP), represented by Expression (2) below, of 0 or more: 
       
         
           
             
               
                 
                   
                     
                       5 
                       ⁢ 
                       8 
                     
                     + 
                     
                       1 
                       ⁢ 
                       3 
                       ⁢ 
                       2 
                       × 
                       
                         [ 
                         C 
                         ] 
                       
                     
                     - 
                     
                       
                         7 
                         . 
                         9 
                       
                       × 
                       
                         [ 
                         Si 
                         ] 
                       
                     
                     + 
                     
                       1. 
                       × 
                       
                         [ 
                         Mn 
                         ] 
                       
                     
                     - 
                     
                       
                         5 
                         . 
                         6 
                       
                       × 
                       
                         [ 
                         Cr 
                         ] 
                       
                     
                     + 
                     
                       7. 
                       × 
                       
                         [ 
                         Ni 
                         ] 
                       
                     
                     + 
                     
                       3.9 
                       × 
                       
                         [ 
                         Cu 
                         ] 
                       
                     
                     + 
                     
                       1.7 
                       × 
                       
                         [ 
                         N 
                         ] 
                       
                     
                   
                 
                 
                   
                     Expression 
                     ⁢ 
                         
                     
                       ( 
                       2 
                       ) 
                     
                   
                 
               
             
           
         
         (in Expression (2), [C], [Si], [Mn], [Cr], [Ni], [Cu], and [N] represent weight percentages (wt %) of respective elements). 
       
     
     
         12 . The method according to  claim 9 , wherein the ingot has a pitting resistance equivalent number (PREN), represented by Expression (3) below, of 17 or more: 
       
         
           
             
               
                 
                   
                     
                       [ 
                       Cr 
                       ] 
                     
                     - 
                     
                       
                         0 
                         . 
                         5 
                       
                       × 
                       
                         [ 
                         Mn 
                         ] 
                       
                     
                     + 
                     
                       1 
                       ⁢ 
                       6 
                       × 
                       
                         [ 
                         N 
                         ] 
                       
                     
                   
                 
                 
                   
                     Expression 
                     ⁢ 
                         
                     
                       ( 
                       3 
                       ) 
                     
                   
                 
               
             
           
         
         (in Expression (3), [Cr], [Mn], and [N] represent weight percentages (wt %) of respective elements). 
       
     
     
         13 . The method according to  claim 9 , further comprising intermediate annealing the hot-rolled steel sheet before the cold rolling. 
     
     
         14 . The method according to  claim 13 , wherein the intermediate annealing is performed at a temperature of 1050° C. to 1150° C. 
     
     
         15 . The method according to  claim 9 , wherein the final annealing is performed at a temperature of 800° C. to 850° C. 
     
     
         16 . The method according to  claim 9 , wherein the cold rolling is performed to adjust a thickness reduction ratio of the hot rolled steel sheet to 50% or more.

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