US2025263806A1PendingUtilityA1

Foundry coke products, and associated systems, devices, and methods

Assignee: SUNCOKE TECH & DEVELOPMENT LLCPriority: Nov 4, 2021Filed: May 9, 2025Published: Aug 21, 2025
Est. expiryNov 4, 2041(~15.3 yrs left)· nominal 20-yr term from priority
C21B 5/007C10B 57/06C10B 57/04C21B 5/008C10L 1/04
83
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Claims

Abstract

A coke product configured to be used in foundry cupolas to melt iron and produce cast iron products is disclosed herein. In some embodiments, the coke product has a Coke Reactivity Index (CRI) of at least 30% and an ash fusion temperature (A FT) less than 1316° C. Additionally or alternatively, the coke product can comprise a fixed carbon content of at least 80% and/or a volatile matter content of no more than 1.0%.

Claims

exact text as granted — not AI-modified
What is claimed is: 
     
         1 . A coke product, comprising:
 a Coke Reactivity Index (CRI) of at least 30%;   an ash fusion temperature (AFT) no more than 1427° C.; and   a fixed carbon content of at least 80.0%.   
     
     
         2 . The coke product of  claim 1 , wherein the ash fusion temperature is between 1149° C. and 1427° C. 
     
     
         3 . The coke product of  claim 1 , wherein the coke product has a softening temperature between 1177° C. and 1371° C. 
     
     
         4 . The coke product of  claim 1 , wherein the coke product has an initial deformation temperature between 1149° C. and 1316° C. 
     
     
         5 . The coke product of  claim 1 , wherein the coke product has a hemispherical temperature between 1204° C. and 1371° C. 
     
     
         6 . The coke product of  claim 1 , wherein the coke product has a fluid temperature between and 1232° C. and 1427° C. 
     
     
         7 . The coke product of  claim 1 , wherein the fixed carbon content of the coke product is at least 85.0%. 
     
     
         8 . The coke product of  claim 1  wherein ash of the coke product has a composition that satisfies the following equation: 
       
         
           
             
               
                 
                   Ash 
                   ⁢ 
                       
                   Fusion 
                   ⁢ 
                       
                   Temperature 
                   ⁢ 
                       
                   
                     ( 
                     AFT 
                     ) 
                   
                 
                 = 
                 
                   
                     19 
                     × 
                     
                       Al 
                       2 
                     
                     ⁢ 
                     
                       O 
                       3 
                     
                     ⁢ 
                     
                       _ 
                       ⁢ 
                       mass 
                     
                     ⁢ 
                     _fraction 
                   
                   + 
                   
                     15 
                     × 
                       
                     
                       ( 
                       
                         
                           
                             SiO 
                             2 
                           
                           ⁢ 
                           _mass 
                           ⁢ 
                           _fraction 
                         
                         + 
                         
                           
                             TiO 
                             2 
                           
                           ⁢ 
                           _mass 
                           ⁢ 
                           _fraction 
                         
                       
                       ) 
                     
                   
                   + 
                   
                     10 
                     × 
                     
                       ( 
                       
                         
                           CaO_mass 
                           ⁢ 
                           _fraction 
                         
                         + 
                         
 
                         
                           MgO_mass 
                           ⁢ 
                           _fraction 
                         
                       
                       ) 
                     
                   
                   + 
                   
                     6 
                     × 
                     
                       ( 
                       
                         
                           
                             Fe 
                             2 
                           
                           ⁢ 
                           
                             O 
                             3 
                           
                           ⁢ 
                           _mass 
                           ⁢ 
                           _fraction 
                         
                         + 
                         
 
                         
                           
                             Na 
                             2 
                           
                           ⁢ 
                           O 
                           ⁢ 
                           _mass 
                           ⁢ 
                           _fraction 
                         
                         + 
                         
                           
                             K 
                             2 
                           
                           ⁢ 
                           O 
                           ⁢ 
                           _mass 
                           ⁢ 
                           _fraction 
                         
                       
                       ) 
                     
                   
                 
               
               , 
             
           
         
         wherein:
 the AFT is a value between 982° C. and 1426° C.; 
 the SiO 2 _mass_fraction is an SiO 2 _mass_fraction of the ash; 
 the Al 2 O 3 _mass_fraction is an Al 2 O 3 _mass_fraction of the ash; 
 the Fe2O 3 _mass_fraction is an Fe 2 O 3 _mass_fraction of the ash; 
 the CaO_mass_fraction is a CaO_mass_fraction of the ash; 
 the MgO_mass_fraction is an MgO_mass_fraction of the ash; and 
 the K 2 O_mass_fraction is an K 2 O_mass_fraction of the ash. 
 
       
     
     
         9 . The coke product of  claim 8 , wherein a mass fraction of the ash of the coke product is no more than 10.0%. 
     
     
         10 . The coke product of  claim 8 , wherein a mass fraction of the ash of the coke product is at least 8.0%. 
     
     
         11 . The coke product of  claim 8 , wherein a volatile matter mass fraction of the coke product is no more than 1.0%. 
     
     
         12 . The coke product of  claim 8 , wherein a mass fraction of sulfur or sulfur oxide of the coke product is no more than 1.0%. 
     
     
         13 . The coke product of  claim 8 , wherein:
 the coke product is produced from a coal blend comprising ash including Al 2 O 3  and SiO 2 ; and   a combined mass fraction of the Al 2 O 3  and SiO 2  of the ash is no more than 65%.   
     
     
         14 . The coke product of  claim 8 , wherein:
 the coke product is produced from a coal blend comprising ash including Al 2 O 3  and SiO 2 ; and   a combined mass fraction of the Al 2 O 3  and the SiO 2  of the ash is between 65% and 80%.   
     
     
         15 . The coke product of  claim 1 , wherein:
 the coke product is made from a coal blend comprising ash including CaO; and   a mass fraction of the CaO of the ash is at least 2.0%.   
     
     
         16 . The coke product of  claim 1 , wherein the coke product has a coke reactivity index (CRI) of at least 25.0%. 
     
     
         17 . The coke product of  claim 1 , wherein the coke product has a Coke Strength After Reaction (CSR) that is no more than 40.0%. 
     
     
         18 . The coke product of  claim 1 , wherein the coke product has a  2 -inch drop shatter of at least 90%. 
     
     
         19 . A coke product, comprising:
 a Coke Reactivity Index (CRI) of at least 30%; and   an ash fusion temperature (AFT) between 982° C. and 1426° C.,   wherein the AFT=19×(Al 2 O 3 _mass_fraction)+15×(SiO 2 _mass_fraction+TiO 2 _mass_fraction)+10×(CaO_mass_fraction+MgO_mass_fraction)+6×(Fe2O 3 _mass_fraction+Na 2 O_mass_fraction+K 2 O_mass_fraction), and   wherein:   the SiO 2 _mass_fraction is an SiO 2  mass fraction of the ash;   the Al 2 O 3 _mass_fraction is an Al 2 O 3  mass fraction of the ash;   the Fe2O 3 _mass_fraction is an Fe 2 O 3  mass fraction of the ash;   the CaO_mass_fraction is a CaO mass fraction of the ash;   the MgO_mass_fraction is an MgO mass fraction of the ash; and   the K 2 O_mass_fraction is an K 2 O mass fraction of the ash.   
     
     
         20 . The coke product of  claim 19 , wherein a fixed carbon content of the coke product is at least 80.0%.

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