Spectacle lens, antifouling agent composition, and method for manufacturing spectacle lens

Abstract

A spectacle lens including an antifouling layer which is a condensate of an antifouling agent composition containing: a compound (A) having a silyl group and a fluorinated alkyl group; a compound (B) having a silyl group at one end and a reactive group at the other end; and a chain fluorine compound (C) having no reactive group.

1 . A spectacle lens comprising an antifouling layer which is a condensate of an antifouling agent composition comprising:
 a compound (A) having a silyl group and a fluorinated alkyl group;   a compound (B) having a silyl group at one end and a reactive group at the other end; and   a chain fluorine compound (C) having no reactive group.   
     
     
         2 . The spectacle lens according to  claim 1 , wherein the antifouling agent composition comprises 30 mass % to 89 mass % of the compound (A). 
     
     
         3 . The spectacle lens according to  claim 1 , wherein the antifouling agent composition comprises 10 mass % to 70 mass % of the compound (B). 
     
     
         4 . The spectacle lens according to  claim 1 , wherein the antifouling agent composition comprises 1 mass % to 30 mass % of the compound (C). 
     
     
         5 . The spectacle lens according to  claim 1 , wherein the compound (A) has the silyl group at one end and the fluorinated alkyl group at the other end. 
     
     
         6 . The spectacle lens according to  claim 1 , wherein
 the compound (A) is represented by formula (1):   
       
         
           
           
               
               
           
         
         in which
 R 1 s each independently represent a monovalent hydrocarbon group having 1 to 6 carbon atoms, 
 R 2 s each independently represent a divalent hydrocarbon group having 1 to 6 carbon atoms, n is 0 or 1, 
 R 3 s each independently represent a divalent hydrocarbon group having 1 to 4 carbon atoms, m is 0 to 10, 
 Rf 4 s each independently represent a divalent fluorinated hydrocarbon group having 1 to 4 carbon atoms, p is 10 to 100, and 
 Rf 5  represents a fluorinated alkyl group having 1 to 20 carbon atoms. 
 
       
     
     
         7 . The spectacle lens according to  claim 6 , wherein
 (ORf 4 ) p  in formula (1) is a group represented by formula (f4-1):   
       
         
           
           
               
               
           
         
         in which a is 0 to 100, b is 0 to 100, c is 0 to 100, and a+b+c is 10 to 200. 
       
     
     
         8 . The spectacle lens according to  claim 1 , wherein
 the compound (B) is represented by formula (2):   
       
         
           
           
               
               
           
         
         in which
 R a  represents a group containing a reactive group, 
 R 10 s each independently represent a divalent hydrocarbon group having 1 to 4 carbon atoms, a is 0 to 10, 
 R 11 s each independently represent a monovalent hydrocarbon group having 1 to 4 carbon atoms or an alkoxy group having 1 to 4 carbon atoms, b is 0 to 10, c is 0 to 10, 
 R 1 s each independently represent a monovalent hydrocarbon group having 1 to 6 carbon atoms, 
 R 2 s each independently represent a divalent hydrocarbon group having 1 to 6 carbon atoms, n is 0 or 1, 
 R 3 s each independently represent a divalent hydrocarbon group having 1 to 4 carbon atoms, m is 0 to 10, 
 Rf 4 s each independently represent a divalent fluorinated hydrocarbon group having 1 to 4 carbon atoms, and p is 10 to 100. 
 
       
     
     
         9 . The spectacle lens according to  claim 1 , wherein the reactive group is at least one selected from the group consisting of a hydroxy group, a vinyl group, a silyl group, an epoxy group, and an alkoxy group. 
     
     
         10 . The spectacle lens according to  claim 7 , wherein
 the R a  is a group represented by formula (a1):   
       
         
           
           
               
               
           
         
         
           in which R a1 , R a2 , R a3 , and R a4  each independently represent a hydrogen atom or an alkyl group having 1 to 3 carbon atoms. 
         
       
     
     
         11 . The spectacle lens according to  claim 8 , wherein
 (ORf 4 ) p  in formula (2) is a group represented by formula (f4-1):   
       
         
           
           
               
               
           
         
         
           in which a is 0 to 100, b is 0 to 100, c is 0 to 100, and a+b+c is 10 to 200. 
         
       
     
     
         12 . The spectacle lens according to  claim 1 , wherein
 the compound (C) is represented by formula (3):   
       
         
           
           
               
               
           
         
         in which
 R 20  represents a monovalent hydrocarbon group having 1 to 20 carbon atoms or a fluorinated alkyl group having 1 to 20 carbon atoms, 
 R 2 s each independently represent a divalent hydrocarbon group having 1 to 6 carbon atoms, n is 0 or 1, 
 R 3 s each independently represent a divalent hydrocarbon group having 1 to 4 carbon atoms, m is 0 to 10, 
 Rf 4 s each independently represent a divalent fluorinated hydrocarbon group having 1 to 4 carbon atoms, p is 10 to 100, and 
 Rf 5  represents a fluorinated alkyl group having 1 to 20 carbon atoms. 
 
       
     
     
         13 . The spectacle lens according to  claim 12 , wherein
 (ORf 4 ), in formula (3) is a group represented by formula (f4-1):   
       
         
           
           
               
               
           
         
         in which a is 0 to 100, b is 0 to 100, c is 0 to 100, and a+b+c is 10 to 100. 
       
     
     
         14 . The spectacle lens according to  claim 1 , wherein a total value of surface free energy of the antifouling layer is more than 10.0 mJ/m 2 . 
     
     
         15 . The spectacle lens according to  claim 1 , wherein a base component of surface free energy of the antifouling layer is more than 0.95 mJ/m 2 . 
     
     
         16 . An antifouling agent composition comprising:
 a compound (A) having a silyl group and a fluorinated alkyl group;   a compound (B) having a silyl group at one end and a reactive group at the other end; and   a chain fluorine compound (C) having no reactive group.   
     
     
         17 . A method for manufacturing a spectacle lens, the method comprising:
 forming an antifouling layer on a spectacle lens with an antifouling agent composition comprising:   a compound (A) having a silyl group and a fluorinated alkyl group;   a compound (B) having a silyl group at one end and a reactive group at the other end; and   a chain fluorine compound (C) having no reactive group.