Method and system for producing refined hydrocarbons from waste plastic pyrolysis oil

Abstract

The methods and system for producing refined hydrocarbons from waste plastic pyrolysis oil according to the embodiments of the present disclosure may minimize formation of an ammonium chloride salt (NH4Cl) and may prevent an adhesion phenomenon of impurity particles in a reactor in a refining process of waste plastic pyrolysis oil containing impurities including chlorine and nitrogen. In addition, the methods and system for producing refined hydrocarbons from waste plastic pyrolysis oil according to the embodiments of the present disclosure may prevent deactivation of a catalyst used in a process, such that the refining efficiency may be excellent, and the process may be operated for a long period of time. In addition, it is possible to produce, from waste plastic pyrolysis oil, refined hydrocarbons including aromatic hydrocarbons that may implement high-value-addition, which have a low content of impurities and a low content of olefins.

What is claimed is: 
     
         1 . A method for producing refined hydrocarbons from waste plastic pyrolysis oil, the method comprising:
 a dehydration operation of applying a voltage to a first mixed solution obtained by mixing waste plastic pyrolysis oil, washing water, and a demulsifier to dehydrate the first mixed solution;   a hydrotreating operation of hydrotreating a second mixed solution obtained by mixing the first mixed solution dehydrated in the dehydration operation and a sulfur source to produce refined oil from which impurities are removed; and   a reforming operation of reforming the refined oil from which impurities are removed.   
     
     
         2 . The method of  claim 1 , wherein in the dehydration operation, the waste plastic pyrolysis oil is mixed in a greater volume than the washing water. 
     
     
         3 . The method of  claim 2 , wherein in the dehydration operation, the waste plastic pyrolysis oil and the washing water are mixed in the first mixed solution at a volume ratio of 1:0.001 to 1:0.5. 
     
     
         4 . The method of  claim 1 , wherein in the dehydration operation, the waste plastic pyrolysis oil and the demulsifier are mixed in the first mixed solution at a volume ratio of 1:0.000001 to 1:0.001. 
     
     
         5 . The method of  claim 1 , wherein the voltage is applied as an alternating current or a combination of an alternating current and a direct current. 
     
     
         6 . The method of  claim 1 , wherein the voltage is applied through at least one pair of vertical electrodes. 
     
     
         7 . The method of  claim 1 , further comprising, after the application of the voltage in the dehydration operation, removing a rag layer from the first mixed solution. 
     
     
         8 . The method of  claim 1 , wherein the dehydration operation is performed under a temperature condition of 20° C. to 300° C. 
     
     
         9 . The method of  claim 1 , wherein a ratio of a content of moisture in the waste plastic pyrolysis oil to a content of moisture in the first mixed solution dehydrated in the dehydration operation is 1:0.0001 to 1:0.9. 
     
     
         10 . The method of  claim 1 , wherein in the dehydration operation, the dehydrated first mixed solution is additionally dehydrated by condensation of moisture. 
     
     
         11 . The method of  claim 1 , wherein a weight ratio of nitrogen to chlorine in the second mixed solution is 1:1 to 1:10. 
     
     
         12 . The method of  claim 1 , wherein the sulfur source includes sulfur-containing oil. 
     
     
         13 . The method of  claim 12 , wherein the sulfur-containing oil is included in an amount of less than 0.5 parts by weight with respect to 100 parts by weight of the first mixed solution dehydrated in the dehydration operation. 
     
     
         14 . The method of  claim 1 , wherein the sulfur source includes one or two or more sulfur-containing organic compounds selected from a disulfide-based compound, a sulfide-based compound, a sulfonate-based compound, and a sulfate-based compound. 
     
     
         15 . The method of  claim 1 , wherein the hydrotreating is performed in the presence of a molybdenum-based hydrotreating catalyst. 
     
     
         16 . The method of  claim 15 , wherein the molybdenum-based hydrotreating catalyst is a catalyst in which a molybdenum-based metal, or a metal including one or two or more selected from nickel, cobalt, and tungsten, and a molybdenum-based metal are supported on a support. 
     
     
         17 . The method of  claim 1 , wherein the hydrotreating is performed under a pressure condition of 50 bar to 150 bar. 
     
     
         18 . The method of  claim 1 , further comprising, after the hydrotreating operation, subjecting a stream including the refined oil from which impurities are removed to gas-liquid separation and then washing the gas-liquid separated stream with water. 
     
     
         19 . The method of  claim 1 , wherein in the reforming the refined oil operation, a refined fraction separated by distilling the refined oil from which impurities are removed in the hydrotreating operation is reformed. 
     
     
         20 . The method of  claim 1 , wherein in the reforming the refined oil operation, mixed oil obtained by mixing the refined oil from which impurities are removed in the hydrotreating operation and petroleum hydrocarbons is reformed.