Method and system for producing refined hydrocarbons from waste plastics

Abstract

A method and associated system for producing refined hydrocarbons from waste plastics. The method and system provide for pretreating waste plastics; producing a pyrolysis gas by introducing the waste plastics pretreated in the pretreatment process into a pyrolysis reactor; producing a pyrolysis oil by introducing the pyrolysis gas into a hot filter; dehydrating a first mixed solution, obtained by mixing the produced pyrolysis oil with washing water and a demulsifier, by applying a voltage to the first mixed solution; hydrotreating a second mixed solution obtained by mixing the dehydrated first mixed solution with a sulfur source to produce a refined pyrolysis oil from which impurities are removed; and isomerizing the refined pyrolysis oil, wherein a liquid condensed in the hot filter is re-introduced into the pyrolysis reactor. The system produces refined hydrocarbons from waste plastics.

What is claimed is: 
     
         1 . A method for producing refined hydrocarbons from waste plastics, the method comprising:
 pretreating waste plastics;   producing a pyrolysis gas by introducing the waste plastics pretreated in the pretreatment process into a pyrolysis reactor;   producing in a lightening process a pyrolysis oil by introducing the pyrolysis gas into a hot filter;   dehydrating a first mixed solution, obtained by mixing the produced pyrolysis oil with washing water and a demulsifier, by applying a voltage to the first mixed solution;   hydrotreating a second mixed solution obtained by mixing the dehydrated first mixed solution with a sulfur source to produce a refined pyrolysis oil from which impurities are removed; and   isomerizing the refined pyrolysis oil,   wherein a liquid condensed in the hot filter is re-introduced into the pyrolysis reactor.   
     
     
         2 . The method of  claim 1 , wherein the hot filter is filled with beads. 
     
     
         3 . The method of  claim 2 , wherein the beads include at least one selected from the group consisting of silica sand (SiO 2 ) and aluminum oxide (Al 2 O 3 ). 
     
     
         4 . The method of  claim 1 , wherein a temperature gradient is formed in the hot filter. 
     
     
         5 . The method of  claim 4 , wherein the temperature gradient is formed by providing at least two heaters outside the hot filter. 
     
     
         6 . The method of  claim 1 , wherein the pyrolysis reactor includes at least two batch reactors. 
     
     
         7 . The method of  claim 6 , wherein the pyrolysis process is performed by switching operations between the at least two batch reactors. 
     
     
         8 . The method of  claim 1 , wherein the refined pyrolysis oil is mixed with petroleum hydrocarbons and isomerized as a mixed oil. 
     
     
         9 . The method of  claim 8 , wherein the refined pyrolysis oil is included in an amount of 90 wt % or less with respect to the total weight of the mixed oil. 
     
     
         10 . The method of  claim 1 , wherein the waste plastics include at least one selected from the group consisting of polyethylene (PE), polypropylene (PP), polyethylene terephthalate (PET), polyvinyl chloride (PVC), and polystyrene (PS). 
     
     
         11 . The method of  claim 1 , wherein in the dehydration process, the pyrolysis oil is mixed in a greater volume than the washing water. 
     
     
         12 . The method of  claim 1 , wherein in the dehydration process, the pyrolysis oil and the washing water are mixed in the first mixed solution at a volume ratio ranging from 1:0.001 to 0.5. 
     
     
         13 . The method of  claim 1 , wherein in the dehydration process, the pyrolysis oil and the demulsifier are mixed in the first mixed solution at a volume ratio ranging from 1:0.000001 to 0.001. 
     
     
         14 . The method of  claim 1 , wherein the demulsifier is one or a mixture of two or more selected from the group consisting of polyethylene glycol, tert-butanol, acetone, alkylnaphthalene sulfonate, alkylbenzene sulfonate, a nonionic alkoxylated alkyl phenol resin, polyalkylene oxide, and polyoxyethylene sorbitan ester. 
     
     
         15 . The method of  claim 1 , further comprising, after the hydrotreating process, distilling the refined pyrolysis oil. 
     
     
         16 . The method of  claim 15 , wherein hydrocarbons derived from the refined pyrolysis oil separated in the distillation process and petroleum hydrocarbons are mixed and isomerized as a mixed oil. 
     
     
         17 . A system for producing refined hydrocarbons from waste plastics, the system comprising:
 a pretreatment device for pretreating waste plastics;   a pyrolysis reactor for producing a pyrolysis gas by introducing the waste plastics pretreated in the pretreatment device;   a hot filter for producing a pyrolysis oil by introducing the pyrolysis gas;   a connection pipe connecting the hot filter and the pyrolysis reactor so that a liquid condensed in the hot filter is re-introducible into the pyrolysis reactor;   a dehydration device for dehydrating a first mixed solution, obtained by mixing the produced pyrolysis oil with washing water and a demulsifier, by applying a voltage to the first mixed solution;   a hydrotreating device for hydrotreating a second mixed solution obtained by mixing the dehydrated first mixed solution with a sulfur source to produce a refined pyrolysis oil from which impurities are removed; and   an isomerization device for isomerizing the refined pyrolysis oil.   
     
     
         18 . The system of  claim 17 , wherein the hot filter is filled with beads. 
     
     
         19 . The system of  claim 18 , wherein the beads include at least one selected from the group consisting of silica sand (SiO 2 ) and aluminum oxide (Al 2 O 3 ). 
     
     
         20 . The system of  claim 17 , further comprising at least two heaters provided outside the hot filter.