US2024044237A1PendingUtilityA1

Method of shale gas reservoir stimulation by oxidation-induced rock burst

Assignee: SOUTHWESTERN PETROLEUM UNIVPriority: Sep 8, 2021Filed: Nov 24, 2021Published: Feb 8, 2024
Est. expirySep 8, 2041(~15.1 yrs left)· nominal 20-yr term from priority
E21B 43/27E21B 49/00E21B 43/263E21B 43/26
37
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Claims

Abstract

A method of a shale gas reservoir stimulation by oxidation-induced rock burst includes performing a hydraulic fracturing stimulation on a shale gas well to be fractured; during the hydraulic fracturing, successively pumping slick water A, oxidizing fluid, glue liquid-containing slick water, catalytic decomposition fluid, and slick water B in a form of liquid slug. In the present invention, methane released by fracturing by the slick water A is mixed with oxygen generated by decomposition of hydrogen peroxide in the oxidizing fluid to induce oxidation-induced rock burst. Based on the physical properties and chemical thermodynamic properties of shale, a calculation method for the amount of fracturing fluid used and the radius of oxidation-induced rock burst is proposed, thereby realizing safe, efficient, and non-destructive multi-scale stimulation of hydraulic fractures-burst fractures-dissolution pores and fractures.

Claims

exact text as granted — not AI-modified
What is claimed is: 
     
         1 . A method of a shale gas reservoir stimulation by an oxidation-induced rock burst, comprising:
 performing a hydraulic fracturing stimulation on a shale gas well to be fractured;   during the hydraulic fracturing stimulation, successively pumping a first slick water, an oxidizing fluid, a glue liquid-containing slick water, a catalytic decomposition fluid, and a second slick water in a form of a liquid slug;   wherein an amount of the first slick water injected is calculated according to formula (1):   
       
         
           
             
               
                 
                   
                     
                       V 
                       1 
                     
                     = 
                     
                       α 
                       ( 
                       
                         
                           2 
                           ⁢ 
                           LHW 
                         
                         + 
                         
                           
                             
                               
                                 ( 
                                 
                                   D 
                                   - 
                                   
                                     2 
                                     ⁢ 
                                     δ 
                                   
                                 
                                 ) 
                               
                               2 
                             
                             4 
                           
                           ⁢ 
                           π 
                           ⁢ 
                           h 
                         
                       
                       ) 
                     
                   
                 
                 
                   
                     formula 
                     ⁢ 
                         
                     
                       ( 
                       1 
                       ) 
                     
                   
                 
               
             
           
         
         in the formula (1), V 1  represents a volume of the first slick water; α represents a leakage coefficient, set as 1.0-1.5; D represents an outer diameter of a casing; δ represents a wall thickness of the casing; h represents a well depth; L represents a burst point depth; H represents a height of a major fracture of the hydraulic fracturing stimulation; and W represents a width of the major fracture of the hydraulic fracturing stimulation. 
       
     
     
         2 . (canceled) 
     
     
         3 . The method of the shale gas reservoir stimulation by the oxidation-induced rock burst according to  claim 1 , wherein the oxidizing fluid is a mixture of hydrogen peroxide and dilute hydrochloric acid. 
     
     
         4 . The method of the shale gas reservoir stimulation by the oxidation-induced rock burst according to  claim 3 , wherein a mass of the hydrogen peroxide injected and a radius of the oxidation-induced rock burst are calculated according to formula (2): 
       
         
           
             
               
                 
                   
                     
                       2 
                       ⁢ 
                       ϕ 
                       ⁢ 
                       π 
                       ⁢ 
                       
                         
                           r 
                           3 
                         
                         ( 
                         
                           
                             P 
                             O 
                           
                           + 
                           σ 
                         
                         ) 
                       
                     
                     = 
                     
                       
                         Z 
                         m 
                       
                       ⁢ 
                       
                         R 
                         ⁡ 
                         ( 
                         
                           
                             
                               2 
                               ⁢ 
                               
                                 P 
                                 o 
                               
                               ⁢ 
                               ϕ 
                               ⁢ 
                               π 
                               ⁢ 
                               
                                 r 
                                 3 
                               
                             
                             
                               
                                 Z 
                                 o 
                               
                               ⁢ 
                               
                                 RT 
                                 o 
                               
                             
                           
                           + 
                           
                             m 
                             
                               2 
                               ⁢ 
                                   
                               
                                 M 
                                 
                                   H 
                                   ⁢ 
                                   2 
                                   ⁢ 
                                   O 
                                   ⁢ 
                                   2 
                                 
                               
                             
                           
                         
                         ) 
                       
                       ⁢ 
                       
                         ( 
                         
                           
                             
                               16 
                               ⁢ 
                                   
                               qm 
                             
                             
                               136 
                               ⁢ 
                                 
                               
                                 
                                   CM 
                                   
                                     CH 
                                     ⁢ 
                                     4 
                                   
                                 
                                 ( 
                                 
                                   
                                     
                                       2 
                                       ⁢ 
                                       
                                         P 
                                         o 
                                       
                                       ⁢ 
                                       ϕ 
                                       ⁢ 
                                       π 
                                       ⁢ 
                                       
                                         r 
                                         3 
                                       
                                     
                                     
                                       
                                         Z 
                                         o 
                                       
                                       ⁢ 
                                       
                                         RT 
                                         o 
                                       
                                     
                                   
                                   + 
                                   
                                     m 
                                     
                                       2 
                                       ⁢ 
                                           
                                       
                                         M 
                                         
                                           H 
                                           ⁢ 
                                           2 
                                           ⁢ 
                                           O 
                                           ⁢ 
                                           2 
                                         
                                       
                                     
                                   
                                 
                                 ) 
                               
                             
                           
                           + 
                           
                             T 
                             o 
                           
                         
                         ) 
                       
                     
                   
                 
                 
                   
                     formula 
                     ⁢ 
                         
                     
                       ( 
                       2 
                       ) 
                     
                   
                 
               
             
           
         
         in the formula (2), P o  represents an original formation pressure; σ represents a tensile strength of a rock; ϕ represents a porosity of a tight gas layer; r represents the radius of the oxidation-induced rock burst; R represents an ideal gas constant; Z o  represents a gas compression factor before the oxidation-induced rock burst; Z m  represents a gas compression factor after the oxidation-induced rock burst; T o  represents an original formation temperature, K; m represents the mass of the hydrogen peroxide injected; M H2O2  represents a molar mass of the hydrogen peroxide; M CH4  represents a molar mass of methane; C represents a specific heat capacity of methane; and q represents a calorific value of methane when a product is a gaseous water. 
       
     
     
         5 . The method of the shale gas reservoir stimulation by the oxidation-induced rock burst according to  claim 4 , wherein according to the formula (2) of the mass of the hydrogen peroxide injected and the radius of the oxidation-induced rock burst, the mass m of the hydrogen peroxide injected is given to yield a one-dimensional higher-order equation of the radius r of the oxidation-induced rock burst, the one-dimensional higher-order equation of the radius r of the oxidation-induced rock burst is solved to obtain the radius r of the oxidation-induced rock burst;
 alternatively, according to the formula (2) of the mass of the hydrogen peroxide injected and the radius of the oxidation-induced rock burst, the radius r of the oxidation-induced rock burst is given to yield a one-dimensional higher-order equation of the mass m of the hydrogen peroxide injected, the one-dimensional higher-order equation of the mass m of the hydrogen peroxide injected is solved to obtain the mass m of hydrogen peroxide injected.   
     
     
         6 . The method of the shale gas reservoir stimulation by the oxidation-induced rock burst according to  claim 1 , wherein an amount of the glue liquid-containing slick water injected is greater than an effective volume of a wellbore. 
     
     
         7 . The method of the shale gas reservoir stimulation by the oxidation-induced rock burst according to  claim 1 , wherein an amount of the glue liquid-containing slick water injected is calculated according to formula (3): 
       
         
           
             
               
                 
                   
                     
                       V 
                       2 
                     
                     = 
                     
                       β 
                       ⁢ 
                       
                         
                           
                             ( 
                             
                               D 
                               - 
                               
                                 2 
                                 ⁢ 
                                 δ 
                               
                             
                             ) 
                           
                           2 
                         
                         4 
                       
                       ⁢ 
                       π 
                       ⁢ 
                       h 
                     
                   
                 
                 
                   
                     formula 
                     ⁢ 
                         
                     
                       ( 
                       3 
                       ) 
                     
                   
                 
               
             
           
         
         in the formula (3), V 2  represents a volume of the glue liquid-containing slick water; β represents a safety factor, set as 1.0-1.5. D represents the outer diameter of the casing; δ represents the wall thickness of the casing; and h represents the well depth. 
       
     
     
         8 . The method of the shale gas reservoir stimulation by the oxidation-induced rock burst according to  claim 1 , wherein the catalytic decomposition fluid is prepared by adding a catalytic decomposition agent into a third slick water, the catalytic decomposition agent comprises sodium hydroxide and manganese dioxide. 
     
     
         9 . The method of the shale gas reservoir stimulation by the oxidation-induced rock burst according to  claim 4 , wherein an amount of the catalytic decomposition fluid injected is calculated according to formula (4): 
       
         
           
             
               
                 
                   
                     
                       V 
                       4 
                     
                     = 
                     
                       m 
                       
                         0.2 
                         ρ 
                       
                     
                   
                 
                 
                   
                     formula 
                     ⁢ 
                         
                     
                       ( 
                       4 
                       ) 
                     
                   
                 
               
             
           
         
         in the formula (4), V 4  represents a volume of the catalytic decomposition fluid; ρ represents a density of a third slick water; and m represents the mass of the hydrogen peroxide injected. 
       
     
     
         10 . The method of the shale gas reservoir stimulation by the oxidation-induced rock burst according to  claim 1 , wherein the second slick water is used to seal and isolate the oxidizing fluid to make a local burst in shale hydraulic fractures occur away from an end of a wellbore and protect an integrity of the wellbore;
 an amount of the second slick water injected is calculated according to formula (5):   
       
         
           
             
               
                 
                   
                     
                       V 
                       5 
                     
                     = 
                     
                       
                         2 
                         ⁢ 
                         LHW 
                       
                       + 
                       
                         
                           
                             
                               ( 
                               
                                 D 
                                 - 
                                 
                                   2 
                                   ⁢ 
                                   δ 
                                 
                               
                               ) 
                             
                             2 
                           
                           4 
                         
                         ⁢ 
                         π 
                         ⁢ 
                         h 
                       
                     
                   
                 
                 
                   
                     formula 
                     ⁢ 
                         
                     
                       ( 
                       5 
                       ) 
                     
                   
                 
               
             
           
         
         in the formula (5), V 5  represents a volume of the second slick water; D represents the outer diameter of the casing; δ represents the wall thickness of the casing; h represents the well depth; L represents the burst point depth; H represents the height of the major fracture of the hydraulic fracturing stimulation; and W represents the width of the major fracture of the hydraulic fracturing stimulation. 
       
     
     
         11 . The method of the shale gas reservoir stimulation by the oxidation-induced rock burst according to  claim 6 , wherein the amount of the glue liquid-containing slick water injected is calculated according to formula (3): 
       
         
           
             
               
                 
                   
                     
                       V 
                       2 
                     
                     = 
                     
                       β 
                       ⁢ 
                       
                         
                           
                             ( 
                             
                               D 
                               - 
                               
                                 2 
                                 ⁢ 
                                 δ 
                               
                             
                             ) 
                           
                           2 
                         
                         4 
                       
                       ⁢ 
                       π 
                       ⁢ 
                       h 
                     
                   
                 
                 
                   
                     formula 
                     ⁢ 
                         
                     
                       ( 
                       3 
                       ) 
                     
                   
                 
               
             
           
         
         in the formula (3), V 2  represents a volume of the glue liquid-containing slick water; β represents a safety factor, set as 1.0-1.5. D represents the outer diameter of the casing; δ represents the wall thickness of the casing; and h represents the well depth.

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