US2024010550A1PendingUtilityA1

Non-contact coated glass and related coating system and method

Assignee: CORNING INCPriority: Jan 26, 2016Filed: Sep 26, 2023Published: Jan 11, 2024
Est. expiryJan 26, 2036(~9.5 yrs left)· nominal 20-yr term from priority
C03C 17/002C03C 17/225C03C 17/009C03C 17/245C03C 17/3411C03C 17/10C03C 17/22C03C 17/25C03C 17/256C03C 17/3417C03C 2218/11Y02P40/57C03C 21/00C03B 27/00
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Claims

Abstract

A coated glass article and of a system and method for forming a coated glass article are provided. The process includes applying a first coating precursor material to the first surface of the glass article and supporting the glass article via a gas bearing. The process includes heating the glass article and the coating precursor material to above a glass transition temperature of the glass article while the glass article is supported by the gas bearing such that during heating, a property of the first coating precursor material changes forming a coating layer on the first surface of the glass article from the first precursor material. The high temperature and/or non-contact coating formation may form a coating layer with one or more new physical properties, such as a deep diffusion layer within the glass, and may form highly consistent coatings on multiple sides of the glass.

Claims

exact text as granted — not AI-modified
What is claimed: 
     
         1 . A method of strengthening a glass sheet, comprising:
 thermally-tempering glass of the glass sheet to impart a compressive stress therein greater than   
       
         
           
             
               
                 { 
                 
                   
                     
                       
                         
                           P 
                           2 
                         
                         ( 
                         h 
                         ) 
                       
                       * 
                       t 
                     
                     
                       ( 
                       
                         
                           
                             P 
                             0 
                           
                           ( 
                           h 
                           ) 
                         
                         + 
                         t 
                       
                       ) 
                     
                   
                   · 
                   E 
                   · 
                   
                     [ 
                     
                       
                         
                           T 
                           strain 
                         
                         · 
                         
                           a 
                           CTE 
                           S 
                         
                       
                       + 
                       
                         
                           a 
                           CTE 
                           L 
                         
                         · 
                         
                           ( 
                           
                             
                               T 
                               soft 
                             
                             - 
                             
                               T 
                               strain 
                             
                           
                           ) 
                         
                       
                     
                     ] 
                   
                 
                 } 
               
               , 
             
           
         
       
       where: 
       
         
           
             
               
                 
                   P 
                   1 
                 
                 ⁢ 
                     
                 
                   is 
                       
                   [ 
                   
                     910.2 
                     - 
                     
                       259.2 
                       · 
                       
                         exp 
                         ⁡ 
                         ( 
                         
                           - 
                           
                             h 
                             0.143 
                           
                         
                         ) 
                       
                     
                   
                   ] 
                 
               
               , 
               
 
               
                 
                   P 
                   2 
                 
                 ⁢ 
                     
                 
                   is 
                       
                   [ 
                   
                     2.53 
                     + 
                     
                       23.65 
                       
                         ( 
                         
                           1 
                           + 
                           
                             
                               ( 
                               
                                 h 
                                 0.00738 
                               
                               ) 
                             
                             1.58 
                           
                         
                         ) 
                       
                     
                   
                   ] 
                 
               
               , 
             
           
         
         
           t is a thickness of the glass sheet, and wherein the t is less than 3 mm, 
           h is a heat transfer coefficient greater than or equal to 0.020 cal/s·cm 2 ·° C., 
           a S   CTE  is a low temperature linear CTE of the glass in 1/° C., 
           a L   CTE  is a high temperature linear CTE of the glass in 1/° C., 
           E is an elastic modulus of the glass in GPa, 
           T soft  is temperature in ° C. of glass of the glass sheet at viscosity of 10 7.6  Poise, and 
           T strain  is temperature in ° C. of the glass of the glass sheet at a viscosity of 10 14.7  Poise; and 
         
         wherein, after the thermal-tempering, the glass sheet comprises a non-dimensional surface fictive temperature θ s  of the glass sheet between 0.2 and 0.9, where:
 θ s  is (T fs −T anneal )/(T soft −T anneal ), 
 T fs  is fictive temperature in ° C. of the glass of the glass sheet at a surface therof, 
 T anneal  is temperature in ° C. of the glass of the glass sheet at viscosity of 10 13.2  Poise. 
 
       
     
     
         2 . The method of  claim 1 , where h is 0.0625 cal/s·cm 2 ·° C. 
     
     
         3 . The method of  claim 2 , wherein the glass comprises soda lime silicate. 
     
     
         4 . The method of  claim 1 , further comprising ion-exchanging the glass sheet after the thermally-tempering to further strengthen the glass sheet. 
     
     
         5 . The method of  claim 4 , wherein compressive stresses of the glass sheet are further increased by at least 100 MPa from the ion-exchanging. 
     
     
         6 . The method of  claim 1 , wherein, after the thermally-tempering, the glass sheet comprises a surface comprising a 50 mm profile that is flat to 100 μm total indicator run-out. 
     
     
         7 . The method of  claim 1 , wherein, after the thermally-tempering, the glass sheet comprises a surface comprising an area of 10 μm by 10 μm having a roughness in a range of from 0.2 to 1.5 nm Ra thereover.

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