Sunscreen or daily care composition comprising micronized methylene bis-benzotriazolyl tetramethylbutylphenol

Abstract

The present invention relates to sunscreen or daily care compositions comprising (i) an ultraviolet absorber water-dispersed composition comprising (a) micronized methylene bis-benzotriazolyl tetramethylbutylphenol, and (b) at least one polyglycerol monoalkyl ester; and (ii) at least one oil soluble UVA filter.

1 .- 14 . (canceled) 
     
     
         15 . A sunscreen or daily care composition comprising
 (i) an ultraviolet absorber water-dispersed composition comprising
 (a) micronized 2,2′-Methylenebis[4-(1,1,3,3-Tetramethylbutyl)-6-(2H-Benzotriazol-2-yl)Phenol] (INCI methylene bis-benzotriazolyl tetramethylbutylphenol), and 
 (b) at least one polyglycerol monoalkyl ester; and 
   (ii) at least one oil soluble UVA filter,   wherein the at least one oil soluble UVA filter is a combination of hexyl 2-[4-(diethylamino)-2-hydroxybenzoyl]benzoate (INCI diethylamino hydroxybenzoyl hexyl benzoate) and 1-(4-(1,1-dimethylethyl)phenyl)-3-(4-methoxyphenyl)propane-1,3-dione (INCI butyl methoxydibenzoylmethane).   
     
     
         16 . The sunscreen or daily care composition according to  claim 15 , wherein the at least one polyglycerol monoalkyl ester is selected from the group consisting of decaglyceryl caprate, decaglyceryl monolaurate, decaglyceryl myristate, decaglyceryl oleate, decaglyceryl stearate, decaglyceryl isostearate, hexaglyceryl cap rate, hexaglyceryl laurate, hexaglyceryl myristate, hexaglyceryl oleate, hexaglyceryl stearate, hexaglyceryl isostearate, pentaglyceryl caprate, pentaglyceryl laurate, pentaglyceryl myristate, pentaglyceryl oleate, pentaglyceryl stearate, pentaglyceryl isostearate, and combinations thereof. 
     
     
         17 . The sunscreen or daily care composition according to  claim 15 , further comprising at least one additional UV filter. 
     
     
         18 . The sunscreen or daily care composition according to  claim 15 , further comprising at least one additional UV filter selected from the group consisting of water soluble UVA filters, UVB filters and/or broadband filters,
 a UVB filter selected from the group consisting of 4,4′,4″-(1,3,5-triazine-2,4,6-triyltriimino)tris-benzoic acid-tris(2-ethylhexyl)ester (INCI ethylhexyl triazone), 4,4′-[[6-[[4-[[(1,1-dimethylethyl)amino]carbonyl]phenyl]amino]-1,3,5-triazin-2,4-diyl]diimino]bis-benzoic acid-bis(2-ethylhexyl)ester (INCI Diethylhexyl Butamido Triazone), phenylbenzimidazole sulfonic acid, and combinations thereof and/or a broadband filter selected from the group consisting of bis-ethylhexyloxyphenol methoxyphenyl triazine, 2-(2H-benzotriazol-2-yl)-6-[(2-ethylhexyloxy)methyl]-4-methylphenol, 2-(2H-benzotriazol-2-yl)-4-methyl-6-[2-methyl-3-[1,3,3,3-tetramethyl-1-[(trimethyl silyl)oxy]siloxanyl]propyl]phenol (INCI drometrizole trisiloxane), and combinations thereof.   
     
     
         19 . The sunscreen or daily care composition according to  claim 15 , comprising
 (i) from 0.01 to 10 wt.-% of micronized 2,2′-Methylenebis[4-(1,1,3,3-Tetramethylbutyl)-6-(2H-Benzotriazol-2-yl)Phenol] (INCI methylene bis-benzotriazolyl tetramethylbutylphenol), based on the total weight of the sunscreen or daily care composition, and
 wherein the weight ratio of the at least one polyglycerol monoalkyl ester to micronized methylene bis-benzotriazolyl tetramethylbutylphenol is from 0.05 to 0.5, and 
   (ii) from 0.01 to 20 wt.-% of the at least one oil soluble UVA filter, based on the total weight of the sunscreen or daily care composition.   
     
     
         20 . The sunscreen or daily care composition according to  claim 15 , comprising
 (i) from 0.01 to 10 wt.-% of micronized 2,2′-Methylenebis[4-(1,1,3,3-Tetramethylbutyl)-6-(2H-Benzotriazol-2-yl)Phenol] (INCI methylene bis-benzotriazolyl tetramethylbutylphenol), based on the total weight of the sunscreen or daily care composition, and
 wherein the weight ratio of the at least one polyglycerol monoalkyl ester to micronized 2,2′-Methylenebis[4-(1,1,3,3-Tetramethylbutyl)-6-(2H-Benzotriazol-2-yl)Phenol] (INCI methylene bis-benzotriazolyl tetramethylbutylphenol) is from 0.05 to 0.5, and 
   (ii) from 0.01 to 10 wt.-% of diethylamino hydroxybenzoyl hexyl benzoate, based on the total weight of the sunscreen or daily care composition, and from 0.01 to 5 wt.-% of butyl methoxydibenzoylmethane, based on the total weight of the sunscreen or daily care composition.   
     
     
         21 . The sunscreen or daily care composition according to  claim 15 , wherein the sunscreen or daily care composition does not comprise Decyl b-D-glucoside (INCI decyl glucoside), 2-hydroxy-4-methoxybenzophenone (INCI oxybenzone), ethylhexyl-2-cyano-3,3-diphenyl-acrylate (INCI octocrylene), 2-ethylhexyl-(2E)-3-(4-methoxyphenyl)acrylate (INCI ethylhexyl methoxy cinnamate), and/or isoamyl-4-methoxycinnamate (INCI isoamyl-p-methoxy cinnamate). 
     
     
         22 . A method for improving water resistance and/or the sun protection factor a sunscreen composition or daily care composition comprising at least one oil soluble UVA filter, wherein the at least one oil soluble UVA filter is a combination of hexyl 2-[4-(diethylamino)-2-hydroxybenzoyl]benzoate (INCI diethylamino hydroxybenzoyl hexyl benzoate) and 1-(4-(1,1-dimethylethyl)phenyl)-3-(4-methoxyphenyl)propane-1,3-dione (INCI butyl methoxydibenzoylmethane) comprising
 (i) an ultraviolet absorber water-dispersed composition comprising
 i. micronized 2,2′-Methylenebis[4-(1,1,3,3-Tetramethylbutyl)-6-(2H-Benzotriazol-2-yl)Phenol] (INCI methylene bis-benzotriazolyl tetramethylbutylphenol); and 
 ii. at least one polyglycerol monoalkyl ester. 
   
     
     
         23 . The method according to  claim 22 , wherein the at least one polyglycerol monoalkyl ester is selected from the group consisting of decaglyceryl caprate, decaglyceryl monolaurate, decaglyceryl myristate, decaglyceryl oleate, decaglyceryl stearate, decaglyceryl isostearate, hexaglyceryl cap rate, hexaglyceryl laurate, hexaglyceryl myristate, hexaglyceryl oleate, hexaglyceryl stearate, hexaglyceryl isostearate, pentaglyceryl caprate, pentaglyceryl laurate, pentaglyceryl myristate, pentaglyceryl oleate, pentaglyceryl stearate, pentaglyceryl isostearate, and combinations thereof. 
     
     
         24 . The method according to  claim 22 , wherein the ultraviolet absorber water-dispersed composition comprises
 from 10 to 70 wt.-% of micronized 2,2′-Methylenebis[4-(1,1,3,3-Tetramethylbutyl)-6-(2H-Benzotriazol-2-yl)Phenol] (INCI methylene bis-benzotriazolyl tetramethylbutylphenol), based on the total weight of the ultraviolet absorber water-dispersed composition and/or   wherein the weight ratio of the at least one polyglycerol monoalkyl ester to micronized 2,2′-Methylenebis[4-(1,1,3,3-Tetramethylbutyl)-6-(2H-Benzotriazol-2-yl)Phenol] (INCI methylene bis-benzotriazolyl tetramethylbutylphenol) is from 0.05 to 0.5.   
     
     
         25 . The method according to  claim 22 , wherein the sunscreen or daily care composition comprises
 from 0.01 to 20 wt.-% of the at least one oil soluble UVA filter, based on the total weight of the sunscreen or daily care composition.   
     
     
         26 . The method according to  claim 22 , wherein the sunscreen or daily care composition does not comprise Decyl b-D-glucoside (INCI decyl glucoside), 2-hydroxy-4-methoxybenzophenone (INCI oxybenzone), ethylhexyl-2-cyano-3,3-diphenyl-acrylate (INCI octocrylene), 2-ethylhexyl-(2E)-3-(4-methoxyphenyl)acrylate (INCI ethylhexyl methoxy cinnamate), and/or isoamyl-4-methoxycinnamate (INCI isoamyl-p-methoxy cinnamate). 
     
     
         27 . The method according to  claim 22 , wherein the sunscreen or daily care composition further comprises at least one additional UV filter. 
     
     
         28 . A method for administering a composition to sensitive skin comprising the sunscreen or daily care composition as defined in  claim 15 .