Surface treatment composition

Abstract

A surface treatment composition including a perfluoropolyether group-containing silane compound and a solvent, wherein a proportion of the perfluoropolyether group-containing silane compound based on a total amount of the perfluoropolyether group-containing silane compound and the solvent is in the range from 30 to 99% by mass.

1 . A surface treatment composition comprising a perfluoropolyether group-containing silane compound and a solvent, wherein
 the perfluoropolyether group-containing silane compound is at least one perfluoropolyether group-containing silane compound represented by formula (A1), (A2), (B1), (B2), (C1), (C2), (D1) or (D2):   
       
         
           
           
               
               
           
         
       
       wherein:
 each Rf, at each occurrence, independently represents an alkyl group having 1 to 16 carbon atoms, optionally substituted with one or more fluorine atoms; 
 in the formula (A1), (A2), (B1), (B2), (C1) and (C2), a proportion of the perfluoropolyether group-containing silane compound based on 100 parts by mass of a total amount of the perfluoropolyether group-containing silane compound and the solvent is in the range from more than 50 parts by mass to 99 parts by mass; 
 in the formula (D1) and (D2), a proportion of the perfluoropolyether group-containing silane compound based on 100 parts by mass of a total amount of the perfluoropolyether group-containing silane compound and the solvent is in the range from 30 to 99 parts by mass; in the formula (A1) or (A2),
 each PFPE, at each occurrence, is independently a group represented by formula:
   —(OC 6 F 12 ) a —(OC 5 F 10 ) b —(OC 4 F 8 ) c —(OC 3 X 10   6 ) c —(OC 2 F 4 ) e —(OCF 2 ) f —
 
 
 
 wherein a, b, c, d, e and f are each independently an integer of 0 or more and 200 or less, the sum of a, b, c, d, e and f is at least 1, the occurrence order of the respective repeating units in parentheses with a, b, c, d, e or f is not limited in the formula, the repeating unit (OC 3 X 10   6 ) has linear structure, and each X 10 , at each occurrence, independently is a hydrogen atom, a fluorine atom or a chlorine atom; 
 in the formula (B1) or (B2),
 each PFPE, at each occurrence, is independently a group represented by formula:
   —(OC 6 F 12 ) a —(OC 5 F 10 ) b —(OC 4 F 8 ) c —(OC 3 X 10   6 ) d —(OC 2 F 4 ) e —(OCF 2 ) f —
 
 
 
 wherein a, b, c, d, e and f are each independently an integer of 0 or more and 200 or less, the sum of a, b, c, d, e and f is at least 1, the occurrence order of the respective repeating units in parentheses with a, b, c, d, e or f is not limited in the formula, the repeating units are linear, and each X 10 , at each occurrence, independently is a hydrogen atom, a fluorine atom or a chlorine atom; 
 in the formula (C1), (C2), (D1) or (D2),
 each PFPE, at each occurrence, is independently a group represented by formula:
   (OC 6 F 12 ) a —(OC 5 F 10 ) b —(OC 4 F 8 ) c —(OC 3 X 10   6 ) d —(OC 2 F 4 ) e —(OCF 2 ) f —
 
 
 
 wherein a, b, c, d, e and f are each independently an integer of 0 or more and 200 or less, the sum of a, b, c, d, e and f is at least 1, the occurrence order of the respective repeating units in parentheses with a, b, c, d, e or f is not limited in the formula, and each X 10 , at each occurrence, independently is a hydrogen atom, a fluorine atom or a chlorine atom; 
 each R 13 , at each occurrence, independently represents a hydroxyl group or a hydrolyzable group; 
 each R 14 , at each occurrence, independently represents a hydrogen atom or an alkyl group having 1 to 22 carbon atoms; 
 each R 11 , at each occurrence, independently represents a hydrogen atom or a halogen atom; 
 each R 12 , at each occurrence, independently represents a hydrogen atom or a lower alkyl group; 
 n1 with respect to each (—SiR 13   n1 R 14   3-n1 ) unit is independently an integer of 0 to 3; 
 provided that at least one n1 in formulae (A1), (A2), (B1) and (B2) is an integer of 1 to 3; 
 each X 1 , at each occurrence, independently represents a single bond or a di- to decavalent organic group; 
 each X 2 , at each occurrence, independently represents a single bond or a divalent organic group; 
 each t, at each occurrence, is independently an integer of 1 to 10; 
 each α1, at each occurrence, is independently an integer of 1 to 9; 
 each α1′ is independently an integer of 1 to 9; 
 each X 3 , at each occurrence, independently represents a single bond or a di- to decavalent organic group; 
 each β1, at each occurrence, is independently an integer of 1 to 9; 
 each β1, is independently an integer of 1 to 9; 
 each X 5 , at each occurrence, independently represents a single bond or a di- to decavalent organic group; 
 each γ1, at each occurrence, is independently an integer of 1 to 9; 
 each γ1′ is independently an integer of 1 to 9; 
 each R a , at each occurrence, independently represents —Z 3 —SiR 71   p1 R 72   q1 R 73   r1 ; 
 each Z 3 , at each occurrence, independently represents an oxygen atom or a divalent organic group; 
 each R 71 , at each occurrence, independently represents R a′ ; 
 R a′  has the same meaning as R a ; 
 the number of Si linearly linked via a Z 3  group in R a  is at most 5; 
 each R 72 , at each occurrence, independently represents a hydroxyl group or a hydrolyzable group; 
 each R 73 , at each occurrence, independently represents a hydrogen atom or a lower alkyl group; 
 each p1, at each occurrence, is independently an integer of 0 to 3; 
 each q1, at each occurrence, is independently an integer of 0 to 3; 
 each r1, at each occurrence, is independently an integer of 0 to 3; 
 provided that the sum of p1, q1 and r1 with respect to (—Z 3 —SiR 71   p1 R 72   q1 R 73   r1 ) is 3 and at least one q1 in formulae (C1) and (C2) is an integer of 1 to 3; 
 each R b , at each occurrence, independently represents a hydroxyl group or a hydrolyzable group; 
 each R c , at each occurrence, independently represents a hydrogen atom or a lower alkyl group; 
 each k1, at each occurrence, is independently an integer of 0 to 3; 
 each l1, at each occurrence, is independently an integer of 0 to 3; 
 each m1, at each occurrence, is independently an integer of 0 to 3; 
 provided that the sum of k1, l1 and m1 with respect to (SiR a   k1 R b   l1 R c   m1 ) is 3; 
 each X 7  independently represents a single bond or a di- to decavalent organic group; 
 each δ1 is independently an integer of 1 to 9; 
 each δ1′ is independently an integer of 1 to 9; 
 each R d , at each occurrence, independently represents —Z 4 —CR 81   p2 R 82   q2 R 83   r2 ; 
 each Z 4 , at each occurrence, independently represents an oxygen atom or a divalent organic group; 
 each R 81 , at each occurrence, independently represents R d′ ; 
 R d′  has the same meaning as R d ; 
 the number of C linearly bonded via a Z 4  group in R d  is at most 5; 
 each R 82 , at each occurrence, independently represents —Y—SiR 85   n2 R 86   3-n2 ; 
 each Y, at each occurrence, independently represents a divalent organic group; 
 each R 85 , at each occurrence, independently represents a hydroxyl group or a hydrolyzable group; 
 each R 86 , at each occurrence, independently represents a hydrogen atom or a lower alkyl group; 
 n2 with respect to a (—Y—SiR 85   n2 R 86   3-n2 ) unit independently represents an integer of 0 to 3; 
 each R 83 , at each occurrence, independently represents a hydrogen atom, a hydroxyl group or a lower alkyl group; 
 each p2, at each occurrence, is independently an integer of 0 to 3; 
 each q2, at each occurrence, is independently an integer of 0 to 3; 
 each r2, at each occurrence, is independently an integer of 0 to 3; 
 provided that the sum of p2, q2 and r2 with respect to (—Z 4 —CR 81   p2 R 82   q2 R 83   r2 ) is 3; 
 each R e , at each occurrence, independently represents —Y—SiR 85   n2 R 86   3-n2 ; 
 each R f , at each occurrence, independently represents a hydrogen atom, a hydroxyl group or a lower alkyl group; 
 each k2, at each occurrence, is independently an integer of 0 to 3; 
 each l2, at each occurrence, is independently an integer of 0 to 3; 
 each m2, at each occurrence, is independently an integer of 0 to 3; and 
 provided that the sum of k2, l2 and m2 with respect to (CR d   k2 R e   l2 R f   m2 ) is 3 and two or more groups represented by —Y—SiR 85   n2 R 86   3-n2  wherein n2 is 1 or more are present in formulae (D1) and (D2). 
 
     
     
         2 . The surface treatment composition according to  claim 1 , wherein the perfluoropolyether group-containing silane compound is at least one perfluoropolyether group-containing silane compound represented by formula (D1) or (D2), the proportion of the perfluoropolyether group-containing silane compound based on 100 parts by mass of a total amount of the perfluoropolyether group-containing silane compound and the solvent is more than 50 parts by mass. 
     
     
         3 . The surface treatment composition according to  claim 1 , wherein the solvent is a fluorine atom-containing solvent. 
     
     
         4 . The surface treatment composition according to  claim 3 , wherein a content of water contained in the solvent is 100 ppm by mass or less. 
     
     
         5 . The surface treatment composition according to  claim 1 , having a viscosity in the range from 10 to 1000 mPa·s. 
     
     
         6 . The surface treatment composition according to  claim 1 , wherein X 10  is a fluorine atom. 
     
     
         7 . The surface treatment composition according to  claim 1 , further comprising one or more other components selected from a fluorine-containing oil, a silicone oil, an alcohol, a catalyst, a transition metal, a halide ion, a silane coupling agent, and a compound containing an atom having an unshared electron pair in a molecular structure. 
     
     
         8 . The surface treatment composition according to  claim 1 , wherein the composition is used as an antifouling coating agent or a water-proof coating agent. 
     
     
         9 . The surface treatment composition according to  claim 1 , for vacuum deposition. 
     
     
         10 . A pellet comprising the surface treatment composition according to  claim 1 . 
     
     
         11 . An article comprising a base material, and a layer formed from the surface treatment composition according to  claim 1 , on a surface of the base material. 
     
     
         12 . The article according to  claim 11 , wherein the article is an optical member.