Method for syngas separation at hydrogen producing facilities for carbon capture and storage

Abstract

Methods and systems for gas separation of syngas applying differences in water solubilities of syngas components, the method including producing a product gas comprising hydrogen and carbon dioxide from a hydrocarbon fuel source; separating hydrogen from the product gas to create a hydrogen product stream and a byproduct stream by solubilizing components in water that are more soluble in water than hydrogen; injecting the byproduct stream into a reservoir containing mafic rock; and allowing components of the byproduct stream to react in situ with components of the mafic rock to precipitate and store components of the byproduct stream in the reservoir.

That claimed is: 
     
         1 . A system for gas separation of syngas applying differences in water solubilities of syngas components, the system comprising:
 a hydrogen production unit with a hydrocarbon fuel inlet operable to produce a product gas comprising hydrogen and carbon dioxide from hydrocarbon fuel;   a hydrogen separation unit operable to separate hydrogen from the product gas to create a hydrogen product stream and a byproduct stream by solubilizing components in water that are more soluble in water than hydrogen; and   an injection well operable to inject the byproduct stream into a reservoir containing mafic rock to allow components of the byproduct stream to react in situ with components of the mafic rock to precipitate and store components of the byproduct stream in the reservoir.   
     
     
         2 . The system according to  claim 1 , where the hydrogen separation unit includes at least one vertical scrubbing tower with countercurrent flow of the product gas and water, the product gas flowing at about 20° C. 
     
     
         3 . The system according to  claim 2 , where at least about 50% of CO 2  and about 95% of H 2 S are removed from the product gas and separated from the hydrogen product stream by being solubilized in the countercurrent flow of water in a single pass through one scrubbing tower. 
     
     
         4 . The system according to  claim 1 , where the hydrogen separation unit includes at least two vertical scrubbing towers in series with countercurrent flow of the product gas and water. 
     
     
         5 . The system according to  claim 1 , where the mafic rock comprises basaltic rock. 
     
     
         6 . The system according to  claim 1 , further comprising a byproduct treatment unit to treat the byproduct stream to separate and purify CO 2  from other components and to increase CO 2  concentration of the byproduct stream for injection into the reservoir. 
     
     
         7 . The system according to  claim 1 , further comprising a compressor to liquefy CO 2  in the byproduct stream for injection into the reservoir. 
     
     
         8 . The system according to  claim 1 , further comprising a reaction unit to react the separated hydrogen with nitrogen to form compressed liquid ammonia. 
     
     
         9 . The system according to  claim 8 , further comprising a transportation unit to transport the compressed liquid ammonia and return the compressed liquid ammonia to hydrogen and nitrogen via electrolysis for use of hydrogen as a hydrogen fuel source. 
     
     
         10 . The system according to  claim 1 , where the hydrogen production unit includes a steam reformer or partial oxidation reactor. 
     
     
         11 . The system according to  claim 1 , where components of the produced byproduct stream react in situ with components of the mafic rock to precipitate products selected from the group consisting of: calcium carbonates, magnesium carbonates, iron carbonates, and combinations thereof. 
     
     
         12 . The system according to  claim 1 , where the reservoir is between about 250 m and about 2,200 m below the surface and is between about 30° C. and about 325° C. 
     
     
         13 . The system according to  claim 1 , where the reservoir is between about 350 m and about 1,500 m below the surface and is less than about 325° C.