Electromagnetic radiation mitigation in coatings with spherical particles

Abstract

Coating compositions comprising a polymer binder and a sphere selected from porous metal oxide spheres formed from metal oxide particles and having, e.g., an average porosity of from 0.10 to 0.90; polymer spheres formed from a multimodal distribution of polymer particles; or mixtures thereof, are described herein. The sphere enhances the reflective characteristics of the coating compositions with respect to electromagnetic radiation. In particular, the coating compositions when dried, can exhibit UV reflectance, visible light reflectance, IR reflectance, or a combination thereof.

1 .- 22 . (canceled) 
     
     
         23 . A coating composition comprising:
 a polymer binder; and   a sphere selected from porous metal oxide spheres formed from metal oxide particles and having an average porosity of from 0.10 to 0.90; polymer spheres formed from a multimodal distribution of polymer particles; or mixtures thereof,   wherein the sphere has an average particle size diameter of from 1 micron to 100 microns, and   wherein the coating composition when dried exhibits a UV reflectance within a wavelength from 100 nm to 400 nm; a visible light reflectance within a wavelength of from 400 to 800 nm;   an IR reflectance within a wavelength from 800 nm to 10 μm; or a combination thereof.   
     
     
         24 . The coating composition of  claim 23 , wherein the polymer binder comprises a polymer selected from acrylic homopolymers, styrene-acrylic-based copolymers, styrene-butadiene-based copolymers, styrene-butadiene-styrene block copolymers, vinyl acrylic-based copolymers, ethylene vinyl acetate-based copolymers, polychloroprene, alkyd resin, polyester resins, polyurethane resins, silicone resins, petroleum resins, epoxy resins, or blends thereof. 
     
     
         25 . The coating composition of  claim 23 , wherein the coating composition is an aqueous composition. 
     
     
         26 . The coating composition of  claim 23 , wherein the sphere comprises the porous metal oxide spheres. 
     
     
         27 . The coating composition of  claim 26 , wherein the porous metal oxide spheres have a multimodal distribution of pore sizes, or a bimodal distribution of pore sizes. 
     
     
         28 . The coating composition of  claim 26 , wherein the composition is a UV reflective composition, and the porous metal oxide spheres have an average diameter from 1 micron to 3 microns; an average porosity from 0.45 to 0.55; and an average pore diameter from 50 nm to 400 nm. 
     
     
         29 . The coating composition of  claim 26 , wherein the coating composition is an IR reflective composition, and the porous metal oxide spheres have an average diameter of from greater than 5 microns to 100 microns; an average porosity from 0.45 to 0.55; and an average pore diameter from 400 nm to 1 micron. 
     
     
         30 . The coating composition of  claim 26 , wherein the porous metal oxide spheres comprise from 60% to 99.9% by weight metal oxide, based on a total weight of the porous metal oxide spheres. 
     
     
         31 . The coating composition of  claim 30 , wherein the metal oxide is selected from the group consisting of silica, titania, alumina, zirconia, ceria, iron oxides, zinc oxide, and combinations thereof. 
     
     
         32 . The coating composition of  claim 23 , wherein the sphere comprises the polymer spheres. 
     
     
         33 . A film derived from a composition of  claim 23 , wherein the film exhibits a UV reflectance at a wavelength from 100 nm to 400 nm of at least 20%. 
     
     
         34 . The film of  claim 33 , wherein the film having a thickness of 75 microns, exhibits a contrast ratio of at least 90% and the film exhibits an IR reflectance at a wavelength from 800 nm to 1 μm, at least 20%. 
     
     
         35 . A clear coating composition comprising:
 a polymer selected from acrylic homopolymers, styrene-acrylic-based copolymers, styrene-butadiene-based copolymers, styrene-butadiene-styrene copolymers, vinyl acrylic copolymers, ethylene vinyl acetate copolymers, polychloroprene, blends thereof, thereof; and   a sphere comprising porous metal oxide spheres formed from metal oxide particles,   wherein the sphere has an average particle size diameter from 1 micron to 3 microns, and   wherein the clear coating composition when dried exhibits a UV reflectance at a wavelength range from 100 nm to 400 nm.   
     
     
         36 . The clear coating composition of  claim 35 , further comprising one or more UV absorbers, selected from a hydroxy-phenyl-benzotriaziole, a hydroxy-phenyl-triazine, a hydroxyl-benzophenone, an oxanilide, a cyanoacrylate, a malonate, or a mixture thereof. 
     
     
         37 . A method for protecting a substrate against UV-radiation, the method comprising applying the clear coating composition according to  claim 35  to the substrate. 
     
     
         38 . A paint composition comprising:
 a polymer selected from acrylic homopolymers, styrene-acrylic-based copolymers, styrene-butadiene-based copolymers, styrene-butadiene-styrene copolymers, vinyl acrylic copolymers, ethylene vinyl acetate copolymers, polychloroprene, blends thereof; and   a sphere selected from porous metal oxide spheres formed from metal oxide particles, polymer spheres formed from a multimodal distribution of polymer particles, or a mixture thereof,   wherein the sphere has an average particle size diameter from 1 micron to 10 microns, and an average porosity of from 0.40 to 0.65.   
     
     
         39 . The paint composition of  claim 38 , wherein a wet film formed from the paint composition having a thickness of 75 μm, exhibits a light scattering coefficient of greater than 3 S/mil, and an absorption coefficient of less than 0.02 K, as determined according to BS EN ISO 6504-1. 
     
     
         40 . An infrared reflecting coating composition comprising:
 a polymer selected from acrylic homopolymers, styrene-acrylic-based copolymers, styrene-butadiene-based copolymers, styrene-butadiene-styrene copolymers, vinyl acrylic copolymers, ethylene vinyl acetate copolymers, polychloroprene, alkyd resin, polyester resins, polyurethane resins, silicone resins, petroleum resins, epoxy resins, blends thereof; and   a sphere selected from porous metal oxide spheres formed from metal oxide particles, polymer spheres formed from a multimodal distribution of polymer particles, or a mixture thereof,   wherein the sphere has an average particle size diameter from 5 microns to 100 microns and an average porosity of from or from 0.40 to 0.65, and   wherein the coating composition when dried exhibits an IR reflectance at a wavelength range from 800 nm to 1 micron.   
     
     
         41 . The infrared reflecting coating composition of  claim 40 , wherein the porous metal oxide spheres have an average pore diameter from 400 nm to 1 micron. 
     
     
         42 . The coating composition of  claim 23 , comprising:
 a polymer binder; and   porous metal oxide spheres formed from metal oxide particles,   wherein the coating composition when dried exhibits a UV reflectance within a wavelength from 100 nm to 400 nm; a visible light reflectance within a wavelength of from 400 to 800 nm; an IR reflectance within a wavelength from 800 nm to 10 μm; or a combination thereof,   wherein the composition is a UV reflective composition, and the porous metal oxide spheres have an average diameter from 1 micron to 100 microns; an average porosity from 0.45 to 0.55; and an average pore diameter from 50 nm to 400 nm, and   wherein the coating composition is an aqueous composition.   
     
     
         43 . The coating composition of  claim 23 , comprising:
 a polymer binder; and   porous metal oxide spheres formed from metal oxide particles,   wherein the coating composition when dried exhibits a UV reflectance within a wavelength from 100 nm to 400 nm; a visible light reflectance within a wavelength of from 400 to 800 nm; an IR reflectance within a wavelength from 800 nm to 10 μm; or a combination thereof,   wherein the composition is a UV reflective composition, and the porous metal oxide spheres have an average diameter from 1 micron to 10 microns; an average porosity from 0.45 to 0.55; and an average pore diameter from 50 nm to 400 nm, and   wherein the coating composition is an aqueous composition.   
     
     
         44 . The coating composition of  claim 23 , comprising:
 a polymer binder; and   porous metal oxide spheres formed from metal oxide particles,   wherein the coating composition when dried exhibits a UV reflectance within a wavelength from 100 nm to 400 nm; a visible light reflectance within a wavelength of from 400 to 800 nm; an IR reflectance within a wavelength from 800 nm to 10 μm; or a combination thereof,   wherein the composition is a UV reflective composition, and the porous metal oxide spheres have an average diameter from 1 micron to 3 microns; an average porosity from 0.10 to 0.90; and an average pore diameter from 50 nm to 400 nm, and   wherein the coating composition is an aqueous composition.   
     
     
         45 . The coating composition of  claim 23 , comprising:
 a polymer binder; and   a sphere selected from porous metal oxide spheres formed from metal oxide particles and having an average porosity of from 0.45 to 0.55; polymer spheres formed from a multimodal distribution of polymer particles; or mixtures thereof,   wherein the coating composition when dried exhibits a UV reflectance within a wavelength from 100 nm to 400 nm; a visible light reflectance within a wavelength of from 400 to 800 nm; an IR reflectance within a wavelength from 800 nm to 10 μm; or a combination thereof,   wherein the composition is a UV reflective composition, and the porous metal oxide spheres have an average diameter from 1 micron to 3 microns; an average porosity from 0.45 to 0.55; and an average pore diameter from 50 nm to 400 nm, and   wherein the coating composition is an aqueous composition.   
     
     
         46 . The coating composition of  claim 23 , comprising:
 a polymer binder; and   a sphere selected from porous metal oxide spheres formed from metal oxide particles and having an average porosity of from 0.10 to 0.90; polymer spheres formed from a multimodal distribution of polymer particles; or mixtures thereof,   wherein the sphere has an average particle size diameter of from 1 micron to 100 microns, and   wherein the coating composition when dried exhibits a UV reflectance within a wavelength from 100 nm to 400 nm; a visible light reflectance within a wavelength of from 400 to 800 nm; an IR reflectance within a wavelength from 800 nm to 10 μm; or a combination thereof. and   wherein the coating composition is an aqueous composition.